What is Perturbation theory: Definition and 263 Discussions

In mathematics, physics, and chemistry, perturbation theory comprises mathematical methods for finding an approximate solution to a problem, by starting from the exact solution of a related, simpler problem. A critical feature of the technique is a middle step that breaks the problem into "solvable" and "perturbative" parts. In perturbation theory, the solution is expressed as a power series in a small parameter



ϵ


{\displaystyle \epsilon }
. The first term is the known solution to the solvable problem. Successive terms in the series at higher powers of



ϵ


{\displaystyle \epsilon }
usually become smaller. An approximate 'perturbation solution' is obtained by truncating the series, usually by keeping only the first two terms, the solution to the known problem and the 'first order' perturbation correction.
Perturbation theory is used in a wide range of fields, and reaches its most sophisticated and advanced forms in quantum field theory. Perturbation theory (quantum mechanics) describes the use of this method in quantum mechanics. The field in general remains actively and heavily researched across multiple disciplines.

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  1. R

    How does Perturbation theory account for interactions in QED?

    Many of you stated how ad hoc is QFT as the field is supposed to be non-interacting yet how could they get an incredibly accurate value of calculated magnetic moment of the electron of value 1.0011596522 compared to measured 1.00115965219 with accuracy to better than one part in 10^10, or...
  2. P

    Hydrogen like atom, perturbation theory

    Hi all ! I need some help Homework Statement The nucleus of an hydrogen-like atom is usually treated as a point charge Ze. Using the first order perturbation theory, estimate the error due to this approximation assuming that the nucleus is a sphere of radius R with a uniform charge...
  3. V

    Perturbation theory to solve diff eq?

    Hi all, I have a tricky problem in pertubation theory. I have a function: f(\vec{r}) = P(\vec{r}) + \left( B(\vec{r}) + b(\vec{r}) \right)^2 where b(\vec{r}) is a small perturbation and is equal to 0 when P(\vec{r}) = 0 Now, to solve the equation \nabla f(\vec{r}) = 0 for b(r) is...
  4. A

    Question on time-independent perturbation theory

    Hi all. I have been thinking about a very simple question, and I am a little confused. We know from time-independent perturbation theory that if the system is perturbed by the external perturbation λV which is much smaller compared to the unperturbed hamiltonian H0, we can write the ground state...
  5. C

    Question on perturbation theory

    Hey everyone, I'm studying quantum mechanics from Griffiths (Introduction to Quantum Mechanics, 2nd edition), and I'm puzzling over his derivation of the nth order corrections to the energies and corresponding eigenstates for a perturbed Hamiltonian. The steps that are outlined in Griffiths...
  6. P

    Diagonalizing a matrix using perturbation theory.

    Homework Statement Consider the following Hamiltonian. H=\begin{pmatrix} 20 & 1 & 0 \\1 & 20 & 2 \\0 & 2 & 30 \end{pmatrix} Diagonalize this matrix using perturbation theory. Obtain eigenvectors (to first order) and eigenvalues (to second order). Ho=\begin{pmatrix} 20 & 0 & 0 \\0 & 20 & 0...
  7. E

    Perturbation theory - need a couple of articles

    I'm studying a perturbation theory (behaviour of its series) and have found two articles which might be of particular interest. Unfortunately, all my three institutions do not have subscription to these journals (articles are too old). I'm kindly asking for your help. These are the articles I'm...
  8. M

    Degenerate Perturbation Theory Wavefunction Correction

    Hi, If we have a non degenerate solution to a Hamiltonian and we perturb it with a perturbation V, we get the new solution by |\psi_{n}^{(1)}> = \sum \frac{<\psi_{m}^{(0)}|V|\psi_{n}^{(0)}>}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)} where we sum over all m such that m\neq n. When we do the same...
  9. JK423

    Time-dependent perturbation theory

    I'm studying Sakurai at the moment, time-dependent perturbation theory (TDPT). I'm having a problem in understanding a basic concept here. According to Sakurai we have the following problem: Let a system be described initially by a known hamiltonian H0, being in one of its eigenstates |i>...
  10. E

    Time-dependant perturbation theory & transitions

    Time-dependant perturbation theory & "transitions" I'm studying approximation methods, and something is really bothering me about the standard treatment of time-dependant perturbation theory. In lecture, the prof introduced time-dependant perturbation theory with the following motivation...
  11. B

    Litle help with perturbation theory

    Why when we analyse time dependant perturbation theory, we take that the diagonal elements of matrix <i|W(t)|j> are equal to zero? Why in degenerate perturbation theory we assume that perturbed wavefunctions of degenerate states can be expressed in the base of unperturbed wavefunctions of...
  12. T

    Degenerate perturbation theory help

    So in time-independent degenerate perturbation theory we say that we can construct a set of wavefunctions that diagonalize the perturbation Hamiltonian (H') from the degenerate subspaces of the unperturbed Hamiltonian (Ho). Since the original eigenstates are degenerate, combinations of them are...
  13. M

    Degenerate Perturbation Theory: Operator commuting with Ho and H'

    Homework Statement Question is: Prove the following: Let A be a Hermitian operator that commutes with H0 and perturbation H'. If two degenerate states have distinct eigenvalues for A, then the matrix element of perturbation between them is zero! The real problem is I don't understand...
  14. C

    Question about a scientific paper - Fluid Mechanics - Perturbation Theory

    My question pertains to the following article: http://tinyurl.com/4uw9h2a I have attached the relevant section to this post. My question is whether Godin's assertion is correct or not - namely the sentence "Such a development ... additional terms" and the last sentence in the attachment...
  15. A

    Time independent perturbation theory (QM)

    Homework Statement I'm trying to derive the second-order correction of energy in time independent perturbation theory. My professor did it the Landau's way so I'd rather use his notation (without bra and kets). I already derived the first-order correction: E_n^{(1)}=V_{nn}=\int...
  16. K

    A mathematical issue raised from perturbation theory

    Take the usual time-independent perturbation theory in QM for example,H'=H_0+V, a basic assumption is we can expand the new states of H' in terms of the old ones of H_0, most of the textbooks justify this assumption by reasoning that the set of eigenfunctions of Hamiltonian is complete...
  17. R

    Quick Q: First order perturbation theory derivation

    Homework Statement Going over and over the perturbation theory in various textbooks, I feel that I've NEARLY cracked it. However, in following a particular derivation I fail to understand a particular step. Could anyone enlighten me on the following? Multiply |\psi^{1)_{n}>...
  18. A

    Is this interpretation logical? (Perturbation theory)

    Hi all. Just have a quick question on perturbation theory. Let's consider a molecule in ground electronic state. If a time-independent external perturbation acts on the molecule, the average electronic energy is going to change. From time-independent perturbation theory, we know that <E> =...
  19. J

    Time dependent perturbation theory

    Hi I was wondering if someone could help me out. I have been studying TDPT and was wondering how it applies to atomic physics or if someone could give me a example that would be great.
  20. J

    Perturbation theory and asymptotics

    I need to find the roots of the transcendental function, f(x;a)=x^2-3ax-1-a+exp(-x/a)=0; I've done many problems like this before and am fairly sure this is just a regular perturbation problem. The difficulty I'm having is with the exponential term. Could anyone give me an idea of how...
  21. B

    First-order time-dependent perturbation theory on a Hydrogen atom

    Homework Statement A Hydrogen atom is initially in its ground state and then subject to a pulsed electric field E(t)=E_{0}\delta(t) along the z direction. We neglect all fine-structure and hyperfine-structure corrections. Homework Equations 1. It is important to use selection rules to avoid...
  22. F

    Perturbation Theory - Shift of Ground State

    Homework Statement Use leading order perturbation theory to calculate the ground state shift of hydrogen due to perturbation: \hat{V} Homework Equations 1. Leading terms in expansion of energy: E=mc^{2}+\frac{p^{2}}{2m}-\frac{p^{4}}{8m^{3}c^{2}}+... 2. \hat{H}=\hat{H}_{0}+\hat{V} where...
  23. C

    Energy eigenfunctions in time-independent perturbation theory

    I've been working my way through some basic quantum mechanics, and have gotten up to perturbation theory. It basically makes sense to me, but there's one thing that bothers me, and I was wondering if somebody could shed some light on it. The essential idea behind perturbation theory is that we...
  24. A

    Question on Time-independent perturbation theory: I am confused

    We all know from time-independent perturbation theory that if we have an atom in ground state [0>, and when a time-independent perturbation acts on it, the energy of the ground state gets shifted and the ground state wave function also gets modified. Using Time-independent Schroedinger eq...
  25. B

    Why do degenerate energy levels shift or split due to perturbation?

    Homework Statement Consider the first excited state of the Hydrogen atom. The principle quantum number is given by n = 2 and so it is four-fold degenerate. Consider now a weak perturbation in the form of V = λxy, where x and y are the Cartesian coordinates of the electron with respect to the...
  26. A

    Question about time limits of time-dependent perturbation theory

    I have been using time-dependent perturbation theory for quite a while. Yet, one thing is still not clear to me. I have seen in many books and papers that when they calculate the transition amplitudes, they integrate from 0 to t. While in many other papers and books, the limit is taken to be -...
  27. C

    How small for perturbation theory to be valid?

    Homework Statement A particle of mass m is in the ground state in the harmonic oscillator potential V(x) = \frac{1}{2}Kx^{2} A small perturbation \beta x^{6} is added to this potential. How small must \beta be in order for perturbation theory to be valid? Homework Equations...
  28. P

    Time dependent perturbation theory for density matrix

    Does anyone kown how to apply time dependent perturbation theory to densities matricies (I'm interested in first order)? Thanks.
  29. 1

    Understanding Perturbation Theory and Spin in Quantum Mechanics

    In my quest to learn quantum mechanics I've become a little confused and I have a question. It is "In The Feynman Lectures on Physics Volume 3, is most of the work, eg. ammonia molecule done using perturbation theory or is this method something else, not perturbation theory?" I started to...
  30. A

    Perturbation theory and total derivatives

    Hi I was just reading about that total derivatives in the Lagrangian does not give any contributions in perturbation theory but that they can play role in non perturbative regimes. But there was no statement WHY that is so? Does anyone have an idea and reading advices? I have the most...
  31. J

    Where Can I Find Feynman Rules for Chiral Perturbation Theory?

    Hello, I was wondering whether anyone knows the Feynman rules for Chiral Perturbation theory? I am trying to calculate K->PiPi and have obtained the relevant diagrams but cannot proceed without the relevant feynman rules.
  32. P

    Mastering Perturbation Theory for Nuclear Engineering Students

    Perturbation Theory Help! Hello physicsforums.com, The last two weeks of my nuclear engineering course covered a mathematical topic known as 'perturbation theory'. It was offered as a 'method to solve anything' with; the problem is, however, that nobody in my class understands it. Basic...
  33. M

    Perturbation Theory & the Ground State in a 1-D Potential Box

    A particle is in the ground state in a one-dimensional box given by the potential v(x)= 0 for 0<x<a v(x)= inifinity other wise A small perturbation V = V(0)x/a is now introduced. Show, correct to first order in perturbation theory, hat the energy change in the ground state is V(0)/2...
  34. N

    Perturbation theory / harmonic oscillator

    Homework Statement An electron is confined by the potential of a linear harmonic oscillator V(x)=1/2kx2 and subjected to a constant electric field E, parallel to the x-axis. a) Determine the variation in the electron’s energy levels caused by the electric field E. b) Show that the second order...
  35. G

    Perturbation theory question (in Quarks & Leptons)

    Hi I'm referring to the book Quarks and Leptons (Halzen, Martin). On pages 79-82 nonrelativistic perturbation theory is investigated (i.e. by using the Schroedinger equation, which is first order in time). On Page 85, however, the transition amplitude (T_fi) is used that has been derived on...
  36. C

    Energy shift using perturbation theory

    Homework Statement I am looking at the relativistic correction to the kinetic energy for a hydrogen atom. I am told that the perturbation is usually written as H = -p^4/(8 m^3 c^2) and need to find the energy shift Homework Equations I know that from the perturbation theory the energy...
  37. J

    Where can I find perturbation theory formulas up to fourth order?

    Does anybody happen to know where to find the perturbation theory formulas for the energies and states up to fourth order? I have to do a calculation up to this order and don't want to have to derive them if I don't have to (I know that Wikipedia has high order energies, but they only have the...
  38. B

    Time-dependent perturbation theory question not a hard one

    Homework Statement A hydrogen atom is placed in a uniform electric field E(t) given by E(t) = Enaught*exp(-a*t) (where a is a constant) for t >0. The atom is initially in the ground state. What is the probability that, as t→∞ , the atom makes a transition to the 2p state? I know...
  39. M

    Perturbation Theory description of Positronium

    Hi everyone, I'm trying to work on Problem 5.32 from Sakurai's Modern Quantum Mechanics. In a nutshell, we need to use Perturbation Theory to find some of the energy levels of Positronium. Here's the full problem: http://img714.imageshack.us/img714/6515/sakurai532.gif Problem 3.3 isn't much...
  40. N

    Perturbation Theory: How Does Oscillation Amplitude Vary with Length?

    Homework Statement The length of a pendulum is slowly doubled (l=l_0(1+epsilon*t), 0<=t<=1/epsilon). How does the amplitude q_max of the oscillations vary? Any hints? Homework Equations The Attempt at a Solution
  41. S

    Degenerate perturbation theory

    Homework Statement Hi, i have put the question, my attempt and actual answer in the attached picture. My answer is not quite right; firstly why is the second term a minus lambda, and where does the O(lamdba^2) come from? Homework Equations The Attempt at a Solution
  42. D

    Time dependant perturbation theory

    Hi, I am basically trying to put a wavefunction into the Time Dependant Schrodinger Eqn, as shown in my lecture notes, but i don't understand one of the steps taken... |\right \Psi (t)\rangle=\sum c_n (t) |\right u_n\rangle e^-(\frac{E_n t}{\hbar}) into i\hbar \frac{\delta}{\delta t}|\right...
  43. J

    First order perturbation theory

    The potential of an electron in the field of a nucleus is: -Ze^2/(4 Pi Epsilon0 r) r > r0 -Ze^2/(4 Pi Epsilon0 r0) r <= r0 where r0 is the fixed radius of the nucleus. What is the pertubation on the normal hydrogenic Hamiltonian? Calculate the change in energy of the 1s state to the first...
  44. MathematicalPhysicist

    Another 2 questions in perturbation theory.

    Homework Statement 1. A particle of mass M is in a square well, subject to the potential: V(x)= V0\theta(x-a/2) for x in (0,a) and diverges elsewhere, where theta is heaviside step function. In perturbation theory, find O(V0^2) correction to the energy and O(V0)to the eigenstate. 2. A...
  45. MathematicalPhysicist

    Calculating Electron Energy Shift with Perturbation Theory

    Homework Statement Regard the nucleus of charge Ze as a sphere of radius R0 with uniform density. Assume that R0<<a0 where a0 is Boher radius/ 1. Derive an expression for the electrostatic potential V(r) between the nucleus and the electrons in the atom. If V0(r)=-Ze^2/r is the potential...
  46. N

    Time-dependent perturbation theory

    Hi all Please look at this link (Search for the phrase "The quantum state at each instant can be expressed as a linear combination of the eigenbasis"): http://en.wikipedia.org/wiki/Perturbation_theory_%28quantum_mechanics%29 If we write the wavefunction for the perturbed system as a...
  47. A

    How Does Degenerate Perturbation Theory Apply to Matrix Elements?

    Homework Statement Ok, so i have this online test to be completed by tomorrow and i have NO IDEA how to go about it, my notes are useless, they don't explain anything. On the up side all the questions seem to be on a very similar topic so if i could understand some key ideas then i should be...
  48. Z

    Perturbation Theory: 2D Harmonic Oscillator & Energy Levels

    Homework Statement 1. Considered the 2D harmonic oscillator potential, V(x,y) = m\omega^{2}x^{2}/2+m\omega^{2}y^{2}/2+ \lambda xy and showed that the energy eigenvalues could be found exactly. Now, treat this as a perturbation theory problem with perturbing Hamiltonian, H^{'}=\lambda xy...
  49. J

    Perturbation theory in 3D potential

    Homework Statement Consider a quantum particle of mass m in a 3-D harnonic potential with frequency \omega and it experiences a perturbation H_{1}=az^{2} a. Determine the effect of H_{1} on the 1st exicted level of the system ( at the 1st order perturbation) b. what happen to L^{2} and...
  50. L

    Perturbation Theory: Square Well & Energy Levels

    a particle moves in one dimension in the potential V(x)=\infty \forall |x|>a, V(x)=V_0 \cos{\frac{\pi x}{2a}} \forall |x| \leq a now the unperturbed state that i use is just a standard infinite square well. anyway the solution says that perturbation theory is only valid provided that...
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