Degenerate Perturbation Theory Wavefunction Correction

In summary, perturbing a non-degenerate solution to a Hamiltonian with a perturbation V will result in a new solution represented by the equation |\psi_{n}^{(1)}> = \sum \frac{<\psi_{m}^{(0)}|V|\psi_{n}^{(0)}>}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}, where m is summed over all values except for n. In degenerate perturbation theory, the same equation applies but the summation excludes m if \psi_{m} belongs to the degenerate subspace. Each "good" state, which are the eigenstates of V in the degenerate subspace,
  • #1
McLaren Rulez
292
3
Hi,

If we have a non degenerate solution to a Hamiltonian and we perturb it with a perturbation V, we get the new solution by

[tex] |\psi_{n}^{(1)}> = \sum \frac{<\psi_{m}^{(0)}|V|\psi_{n}^{(0)}>}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}[/tex]

where we sum over all [itex]m[/itex] such that [itex]m\neq n[/itex].

When we do the same for a degenerate perturbation theory, we simply exclude all the [itex]\psi_m[/itex] that belongs to the degenerate subspace. That is

[tex] |\psi_{n}^{(1)}> = \sum \frac{<\psi_{m}^{(0)}|V|\psi_{n}^{(0)}>}{E_n^{(0)} - E_m^{(0)}}\psi_m^{(0)}[/tex]

only this time the summation exculdes m if [itex]\psi_{m}[/itex] is in the degenerate subspace. Am I right so far?

If so, my question is this. Assuming we are taking the "good" states that Griffiths mentions (those which are the eigenstates of V in the degenerate subspace), then each one has a different energy correction. But the wavefunction correction for all of them is exactly the same according to the expression given above. That seems a little fishy. The first order corrections to each of the "good" states is exactly the same but the first order energy correction is different?

Thank you for your help.
 
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  • #2
The matrix elements [tex]\langle \psi_m^{(0)}|V|\psi_n^{0)}\rangle[/tex] will be different for different "good states" n from the degenerate subspace, no?
 
  • #3
Oh dear, I don't know what I was thinking! Sorry about that. It is obviously different for different n. Thank you DrDu.
 

Related to Degenerate Perturbation Theory Wavefunction Correction

1. What is degenerate perturbation theory?

Degenerate perturbation theory is a method used in quantum mechanics to calculate the energy levels and wavefunctions of a system that experiences a small perturbation or disturbance. It is typically used when the system has degenerate or closely spaced energy levels.

2. How does degenerate perturbation theory work?

Degenerate perturbation theory works by treating the perturbation as a small addition to the original Hamiltonian of the system. The perturbation is then expanded in a series and the resulting equations are solved iteratively to obtain corrections to the energy levels and wavefunctions of the system.

3. What is the difference between first-order and higher-order degenerate perturbation theory?

In first-order degenerate perturbation theory, only the first term in the expansion of the perturbation is considered, resulting in a rough approximation of the energy levels and wavefunctions. In higher-order degenerate perturbation theory, multiple terms in the expansion are considered, leading to a more accurate calculation of the energy levels and wavefunctions.

4. Why is degenerate perturbation theory important?

Degenerate perturbation theory is important because it allows for the calculation of energy levels and wavefunctions of systems that cannot be solved exactly. It is also useful in understanding the effects of small perturbations on a system, which is relevant in many areas of physics such as quantum chemistry and solid state physics.

5. What are some limitations of degenerate perturbation theory?

Degenerate perturbation theory may not work well for highly degenerate systems or in cases where the perturbation is not small. It also assumes that the perturbation is time-independent and that the energy levels do not cross. Additionally, the calculations can become very complex for higher-order perturbations, making it difficult to obtain accurate results.

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