What is Molecular: Definition and 581 Discussions

A molecule is an electrically neutral group of two or more atoms held together by chemical bonds. Molecules are distinguished from ions by their lack of electrical charge.
In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.
In the kinetic theory of gases, the term molecule is often used for any gaseous particle regardless of its composition. This violates the definition that a molecule contain two or more atoms, since the noble gases are individual atoms.A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H2O).
Atoms and complexes connected by non-covalent interactions, such as hydrogen bonds or ionic bonds, are typically not considered single molecules.Molecules as components of matter are common. They also make up most of the oceans and atmosphere. Most organic substances are molecules. The substances of life are molecules, e.g. proteins, the amino acids they are made of, the nucleic acids (DNA & RNA), sugars, carbohydrates, fats, and vitamins. The nutrient minerals ordinarily are not molecules, e.g. iron sulfate.
However, the majority of familiar solid substances on Earth are not made of molecules. These include all of the minerals that make up the substance of the Earth, soil, dirt, sand, clay, pebbles, rocks, boulders, bedrock, the molten interior, and the core of the Earth. All of these contain many chemical bonds, but are not made of identifiable molecules.
No typical molecule can be defined for salts nor for covalent crystals, although these are often composed of repeating unit cells that extend either in a plane, e.g. graphene; or three-dimensionally e.g. diamond, quartz, sodium chloride. The theme of repeated unit-cellular-structure also holds for most metals which are condensed phases with metallic bonding. Thus solid metals are not made of molecules.
In glasses, which are solids that exist in a vitreous disordered state, the atoms are held together by chemical bonds with no presence of any definable molecule, nor any of the regularity of repeating unit-cellular-structure that characterizes salts, covalent crystals, and metals.

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  1. L

    Molecular Orbital & Normal Modes

    I'd like to ask a couple of questions. As a solid object gets bigger, the molecular orbital (combinations of all single atom orbitals) has greater size too? For a one inch square object (of closely packed molecules like crystals), what is its molecular orbital size compared to a one foot square...
  2. H

    Chemistry Bonding and antibonding molecular orbitals

    Not a homework question, just curious. My book says that bonding orbitals from from constructive interference while antibonding orbitals from destructive interference. Since constructive interference increases amplitude, what increases in amplitude from the combination of bonding orbitals? It...
  3. gracy

    Difference between molecular mass and molar mass

    Molecular mass of water is constant i.e mass of one mole of water i.e 18 g Molar mass is the mass of a substance depending on how many moles of substance is taken into consideration. Ex. A mole of H2O: 18 g Two moles of H2O: 36 g Three moles of H2O: 54g and so on. Right? And molecular mass...
  4. J

    Cell physiology vs Molecular biology vs Cell Biology?

    What exactly is the concrete difference between those three?
  5. T

    Chemistry Using data (Pressure vs. density) to find molecular mass .

    Homework Statement Use the data: P/bar a: 0.1000 b: 0.5000 c: 1.000 d: 1.01325 e: 2.000 vs. density/(g/L) a: 0.1771 b: 0.8909 c: 1.796 d: 1.820 e: 3.652...for an unknown gas at 300K to determine the molecular mass of the gas...
  6. L

    Molecular speed and energy distributions

    Hi guys, If the value of v for which f(v) has its maximum value is known for a sample of a gas, is there a way of determining the corresponding maximum of f(E)/g(E)?
  7. L

    Calculating temperature from molecular speed distribution

    Homework Statement A sealed container of 0.10 m3 holds a sample of 3.0x1024 atoms of helium gas in equilibrium. The distribution of speeds of the helium atoms shows a peak at 1100 m s-1. Take the mass of a helium atom to be 4.0 amu. I, calculate the temperature and pressure of the helium gas...
  8. R

    Molecular sensing fluorescent proteins and FRET pairs

    Hope this is in the right place, apologies if not. We have studied green flourescent protein GFP and others (RFP, CFP etc) as a means of analysing an organism / sample, you need two that have unique fluorophores. We have also studied the use of FRET pairs such as florecein-florescien or...
  9. barryj

    Exploring the Molecular and Ionic Nature of HCl and Other Acids

    I have thought the HCl is an ionic compound since it disassociates in water. However I read in my chemistry book that HCl is molecular. So what is it? Are all acids molecular or just the ones like HF, HCl, HBr, etc?
  10. M

    Black Body Molecular Absorption

    I understand photon absorption/emission by electrons in atoms, that transition them between energy levels, producing sharp spectral lines. However, I am having difficulty understanding photon absorption/emission by the vibrational and rotational modes of molecules, with respect to black body...
  11. N

    Molecular Orbitals: Understanding & Rules

    My general understanding of Molecular Orbitals is as follows: N atoms come together to form N molecular orbitals. N/2 of the orbitals will be spatially asymmetric with symmetric spins.This corresponds to the antibonding orbital. N/2 will be spatially symmetric with antisymmetric spins. This...
  12. R

    Chemistry Molecular Orbital Diagram for Tetrahedral Compound

    Homework Statement I'm trying to construct a molecular orbital correlation diagram for a tetrahedral compound [NiX4]2- considering the ligand pi-orbital basis. I've already constructed a diagram wherein the only the sigma-orbital basis is considered. In that diagram, I had 12 electrons for the...
  13. T

    Chemistry Molecular Structure: Thorium & Rubidium; Thorium & Phosphour

    Homework Statement Got a homework question for what kind of molecular structure you would get by combining these to metals: Thorium and rubidium, thorium and phosphour. Got to draw the Lewis diagrams and VSEPR model for these molecular structures, and predict the geometry - bond angles - bond...
  14. P

    Chemistry Deducing a Molecular Formula from Mass Spectra

    Homework Statement When reacted with a small quantity of water, SiCl4 produces an oxychloride X, SixClyOz. The mass spectrum of X shows peaks at mass numbers 133, 149, 247, 263 and 396. You should assume that the species responsible for all these peaks contain the 16O, 35Cl and 28Si isotopes...
  15. C

    Molecular Charge Density Analysis

    How would one go about estimating the relative position of the center of charge density (with respect to oxygen) in ruthenium oxide vs. silicon oxide? (Hypothetically) My real quandary is with the relative screening experienced by oxygen core electrons in silicon dixoide vs. ruthenium dioxide...
  16. A

    Engineering Seeking Career Advise (Engineering, Physics, Molecular Biology)

    Hello, While I'm reading though various threads here on PhysicsForums, I thought I'd make a post asking for some advice/insight from those who have already gone though the process of finishing a degree and gained valuable life experience. I have a few questions which I'll post at the latter...
  17. S

    Programs What undergraduate degree to take for Molecular Biologist?

    Can someone tell me What should I take in Community College to become a Molecuar Biologist? Should I take a Associates of Applied Sciences in BioTechnology or a Associates of Biology in Science(AS) or Associates of Science?However in the future I would like to work at a Biotech company,but I...
  18. J

    Use of Trotter Theorem in Path Integral Molecular Dynamics

    I am unable to prove step 8.3 in this proof of the path integral formulation of molecular dynamics https://files.nyu.edu/mt33/public/jpc_feat/node11.html Any help would be much appreciated.
  19. S

    Molecular dynamics help - Lennard Jones potention

    Homework Statement The Lennard-Jones potential function u(r) = 4ε[(σ/r)^12 - (σ/r)^6] If intermolecular interactions are ignored in this calculation for r > rc , show that in the mean field approximation in the long range correction [itex] P*LR to the measured pressure is given by...
  20. H

    Molecular speed and temperature

    Imagine a special air filter placed in a window of a house. The tiny holes in the filter allow only air molecules moving faster than a certain speed to exit the house, and allow only air molecules moving slower than that speed to enter the house from outside. What effect would this filter have...
  21. H

    Related to Kinetic Molecular theory

    The derivation of the ideal-gas equation included the assumption that the number of molecules is very latge, so that we could compute the average force due to many collisions. However, the ideal-gas equation holds accurately only at low pressures, where the molecules are few and far between...
  22. M

    Kinetic Temperaturea and molecular velocities

    If I have ice, water and vapour at the triple point and they are in equilibrium at a temperature of 273.16. Does this mean that the average kinetic energy of the particles is the same in each state? If so how can the molecules in the water be moving with the same mean squared speed as the...
  23. W

    Non-Academic career for Molecular Biology PhD?

    Hello everyone, I will be entering my third year of university majoring in applied math and biology. I am currently looking for graduate school opportunities. My interest leans slightly towards the biology side but I am terribly worried about not getting a decent job after graduation if I do...
  24. R

    What Is the Valence Molecular Connectivity Index of a 3rd Order Cluster?

    Dear All, I would like to know about (question related to computational chemistry): what is valence molecular connectivity index of 3rd order cluster. Please provide an example? Thanks for your help. Regards, Rajini.
  25. M

    Effect of Cooling on Molecular Structure

    I am interested in knowing whether what changes would happen at the molecular and atomic level, to a material subjected to Cooling. 1. Does the minimum temperature that can be achieved has limit? 2. Is it Zero Kelvin? 3. If so, is it a global standard for minimum temperature for any material...
  26. H

    Molecular orbitals of three or more atoms

    In Molecular orbital theory, when two atoms A & B come close to each other, their atomic orbitals (say their s orbitals) combine and make two molecular orbitals, one bonding and the other anti-bonding. How about molecular orbitals of three or more atoms? For three atoms say A & B & C we would...
  27. S

    Schools What courses needed for molecular biology grad school?

    Hi, I'm an applied math major who wants to go to grad school for molecular biology. In my plan, I have included: Intro to cell biology & lab Intro to genetics Intro to microbiology molecular biology & lab advanced cell biology bioinformatics biological sequence analysis intro to...
  28. P

    Can anyone explain the mechanism of molecular vibration and heat transfer?

    Can anyone help with the following - which I have been musing about for some time. mThe general idea is that when heat is applied to a substance the molecules / atoms in that substance vibrate more and more (until the bonds in the molecule break). OK - so can anyone help with the following...
  29. M

    Molecular Orbital Theory Question about bonding/antibonding orbitals

    Hi I spotted on an MCAT book I am studying off of that the shading of the lobes(from a figure of p and sp3 orbitals) in an orbital represents the direction of spin for the electron and that in order for the electron density to overlap, the electrons must have the same spin. Firstly, I thought...
  30. E

    Problem with molecular separation calculations

    I am attempting to complete a basic question involving molecular separation from Alonso & Finn "Fundamental University Physics" Second Edition, Chapter 2, Question 9. The Problem states "Using the data in table 2-1 and A-1, estimate the average separation in molecules of hydrogen at STP (gas)...
  31. G

    Molecular vs ionics compounds, H20

    I have read previous topics, but still the difference in compounds is not clear to me. As far as I understood, molecular compounds are made of covalent bonds, while ionic compounds by ionic bonds. I understand why Mn2O3 is ionic compound, because neutral Mn and O would make only MnO IN CASE...
  32. P

    Molecular orbitals sigma and pi

    hi! i have a doubt, how can i know the total number of bonding and antibonding electrons given a diatomic molecule's electronic configuration in therms of sigma and pi orbitals? I have to add these σ and π orbitals are of the type gerade and ungerade. does anyone can help me?
  33. C

    Need a strategy for independently studying physics for molecular bio

    Hello all; I'm in an odd position. I graduated with a degree in molecular biology 2 years ago and now work in a quality control lab for a pharmaceutical manufacturer. My job involves doing things like running gene-amplification reactions for recombinant microorganisms used in drug-production...
  34. C

    Molecular nutrition- health and desease- any good books?

    Hi, I'm very interested in understanding how molecules in nutrition play a role in sustaining the human body so I'm looking for some good chemistry/molecular nutrition book describing some of the following: *The chemical and metabolic pathways taking place in the body (such as glykolysis...
  35. B

    Help understanding molecular vs atomic electron quantum states

    I am a retired electrical engineer, now able to get back to studying what I really enjoy - mathematics and physics. As a genuine old geezer, my modern physics knowledge, which was never very deep, is now way out of date. I purchased a copy of "Modern Physics", by Kenneth Krane, and have been...
  36. C

    Calculating Molar Energy Change in Molecular System Conversion?

    Homework Statement Consider a molecular system containing X type molecules and Y type molecules. X and Y can interconvert, and each has two energy levels (given below). The population in moles (n), of each energy state for X and Y, are given at equilibrium of T=300K. For X n0=0.8 and E0=0...
  37. C

    Orbital theory - Molecular vs Hybrid orbitals

    Hi I have a question regarding Molecular orbital theory: Is it correctly understood that if we combine 2 or more atoms the atomic orbitals can become 2 things: They can either become Hybrid orbitals which are the orbitals that form sigma bonds between atoms, or they can become Molecular...
  38. caters

    Totipotent Stem Cell From Molecular Components

    I am making a human stem cell from its molecular components(just pretending to do it right now but might be able to do later in life). I have extracted my DNA and formed a liposome. I have the DNA replicating in an incubator at 98.6° F, 5% CO2, and 95% humidity. The temperature is because it...
  39. Q

    Chemistry Find pH of 0.20 M Iron (III) Sulfate

    Homework Statement Find the pH of 0.20 M Iron (III) sulfate. Homework Equations The metal ion becomes hydrated (water is a ligand) and forms iron hexahydrate. The sulfate ion is a weak base. The Attempt at a Solution Now, in considering the pH of this solution, should I consider the...
  40. B

    Veracity of Simple Molecular Model

    Hello Everyone, I understand that sometimes in physics we make a model of some physical system purely for theoretical convenience, as it allows us to calculate certain properties of the system very easily; although, sometimes these models aren't actually what is going on, but it doesn't matter...
  41. M

    Solid-State and molecular physics; allowed energy states

    When two objects move under the influence of their mutual force alone, we can treat the relative motion as a one-particle system of mass μ=m1m2/(m1+m2). An object of mass m2and charge -e orbits an object of mass m1 and charge +Ze. By appropriate substitutions into formulas given in the chapter...
  42. C

    Biology DNA Sequence for Anti-Sense Strand of CCUAGGCUA mRNA Molecule

    A portion of an mRNA molecule has the sequence CCUAGGCUA. What is the sequence of the anti sense strand of the corresponding DNA molecule? The anti sense strand is the coding strand. The 3' to 5' strand from which mRNA builds. Does that mean the sequence would be backwards?
  43. R

    Molecular emission spectra database

    Hi, I am looking for online molecular emission spectra database for spectroscopic analysis of plasma. It would be great if searching in it is based on a wavelength of spectral lines/bands. For atomic spectra I found this database: http://physics.nist.gov/PhysRefData/ASD/lines_form.html But I...
  44. T

    Molecular States, Symmetry and Allowed Transitions

    I have a question about allowed transitions and molecular states. For an electric dipole transition between two states (say molecular or atomic) to have a non-zero probability of occurring, the transition dipole moment \langle \psi_{f}|\textbf{μ}\left|\psi_{i} \right \rangle must be non-zero...
  45. M

    Molecular Orbital Theory: Build MOs for Diatomic Molecules

    http://chemwiki.ucdavis.edu/Theoretical_Chemistry/Chemical_Bonding/Molecular_Orbital_Theory/How_to_Build_Molecular_Orbitals Hi, I'm currently trying to understand MO theory and how diagrams are made and interpreted. I stumbled across this website and it shows the general MO diagrams...
  46. A

    Relation between liquid water pressure and it's molecular dynamics

    Hello everyone. I'm am looking for some literature (articles or books) containing information about how is the relation between the liquid water pressure (macroscopic thermodynamic quantity) and it's quantum molecular dynamics (collisions, vibrations, etc.). Like: The pressure increase...
  47. K

    Why Are Detectors for Molecular Vibration Frequencies Less Common?

    We have common detectors for radio, microwaves, visible, ultraviolet, xray and gammy rays.. but how about the infrared frequencies from molecular vibrations. The frequencies of molecular vibrations range from less than 10^12 to approximately 10^14 Hz. These frequencies correspond to radiation...
  48. J

    Good books on practical molecular electronic structure theory?

    Does anyone know of a good code-oriented book on molecular electronic structure theory? I've been looking for a good modern book that teaches how to write SCF code to solve simple cases of the kind of problem that standard quantum chemistry packages (e.g. Gaussian, Orca) are used for without...
  49. N

    Finding Molecular Weight from Freezing Point Depression

    A compound contains boron (40.3%), nitrogen (52.2%), and hydrogen (7.5%) - by mass. If 6.32g of this compound if dissolved in 100g of benzene, the solution freezes at 1.30 celcius. If the cryoscopic constant is 5.12 and freezing pt of benzene is 5.48, what is the molecular weight of compound...
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