What is Boiling point: Definition and 127 Discussions

The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor.
The boiling point of a liquid varies depending upon the surrounding environmental pressure. A liquid in a partial vacuum has a lower boiling point than when that liquid is at atmospheric pressure. A liquid at high pressure has a higher boiling point than when that liquid is at atmospheric pressure. For example, water boils at 100 °C (212 °F) at sea level, but at 93.4 °C (200.1 °F) at 1,905 metres (6,250 ft) altitude. For a given pressure, different liquids will boil at different temperatures.
The normal boiling point (also called the atmospheric boiling point or the atmospheric pressure boiling point) of a liquid is the special case in which the vapor pressure of the liquid equals the defined atmospheric pressure at sea level, one atmosphere. At that temperature, the vapor pressure of the liquid becomes sufficient to overcome atmospheric pressure and allow bubbles of vapor to form inside the bulk of the liquid. The standard boiling point has been defined by IUPAC since 1982 as the temperature at which boiling occurs under a pressure of one bar.The heat of vaporization is the energy required to transform a given quantity (a mol, kg, pound, etc.) of a substance from a liquid into a gas at a given pressure (often atmospheric pressure).
Liquids may change to a vapor at temperatures below their boiling points through the process of evaporation. Evaporation is a surface phenomenon in which molecules located near the liquid's edge, not contained by enough liquid pressure on that side, escape into the surroundings as vapor. On the other hand, boiling is a process in which molecules anywhere in the liquid escape, resulting in the formation of vapor bubbles within the liquid.

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  1. teroenza

    Calculate new boiling point with change post-pressure change

    Homework Statement Liquid X boils at 127C, at a pressure of 10.6*10^5 Pa. Its enthalpy of vaporization is 5000 J/mol. At what temperature will it boil if the pressure is raised to 1.08*10^5 Pa? Homework Equations \frac{dT}{dP}=\frac{l}{T(v_{B}-v_{A})}The Attempt at a Solution It seems so...
  2. J

    Why does 2-propanethiol have a lower boiling point than 1-propanethiol

    Homework Statement Consider 2-propanethiol, shown below. Would you expect its boiling point to be higher or lower than that of 1-propanethiol? Why?Homework Equations 1-propanethiol: 2-propanethiol: The Attempt at a Solution I looked it up, and 2-propanethiol does have a lower boiling point...
  3. C

    Archived Finding a lot of answers to water boiling point.

    Homework Statement I had an issue with a professor a while ago. A question was asked, "Why does water boil at 100°C?". What I believe was the targeted answer was something around "Hydrogen bonds." Hydrogen bonds are a valid answer, I believe also correct enough. For clarity purposes, I...
  4. 1

    Vapor pressure given boiling point and heat of vaporization?

    Homework Statement What is the vapor pressure of benzene at 50.0 C? Benzene's boiling point is 80.1 C and its heat of vaporization is 31 kJ/mol Homework Equations The Attempt at a Solution I don't want to be that guy who just says "I don't know" but.. All I know is that: ln P...
  5. S

    Fluid's boiling point dependence as function of pressure

    Greetings to all, I need some help for i understand how to demonstrate fluids boiling point dependence as function of pressure (i.e for main cool agents). Which are the basic equations for to write a general formula? I know that in PHWR type reactor water is at hight pressure to prevent...
  6. F

    Calculate freezing point depression and boiling point elevation

    Homework Statement Calculate new freezing point and boiling point when 0.47 mol ethylene glycol and 0.14 mol KBr is added to 150g H2O. Express your answer using one decimal place.Homework Equations molality = moles solute/kg solvent ΔTf=i*Kf*m ΔTb=i*Kb*m New bp = ΔTb + normal bp New fp =...
  7. D

    Boiling point of Cyclohexene and 2-methylbut-1-ene

    So i just took a final and the question was Arrange the following solvents in order of boiling point. water 2-methylbut-1-ene cyclohexane So the answer was Water>cyclohexene> 2-methylbut-1-ene. I understand by the hydrogen bonding that water is definitely #1. But I can't...
  8. A

    What factors affect the boiling point of polar molecules?

    arrange the boiling point of the following compounds methoxymethane,butane,pentane and water I quickly arrange like this butane<pentane<methoxymethane<water but after checking wiki,it should be methoxymethane<butane<pentane<water In my knowledge,methoxymethane is a polar molecule,so i...
  9. A

    Pasteurization temperature adjustment for boiling point variations

    If you are at altitude and let's say water boils at 95 Celsius. Pasteurization for an X food product is 30 minutes at 82 Celsius at sea level. Now deductively, should I also reduce my pasteurization temperature to 82-5=77 Celsius to compensate?
  10. R

    Effect of air pressure on boiling point of water

    I know that the boiling point of water is lower when the atmospheric pressure is less (such as at the top of a mountain), but why is that? Once a water molecule has the energy to escape from the binding forces that keep it with the other water moelcules in the liquid, I don't understand why...
  11. Y

    Atmospheric Pressure & Boiling Point of Water: 20 C

    What does the atmospheric pressure have to be to make the boiling point of water 20 C?
  12. M

    Thermodynamics: dropping iron into thermos of nitrogen at boiling point

    Homework Statement You come into lab one day and find a well insulated 2000mL thermos bottle containing 500mL of boiling liquid nitrogen. The remainder of the thermos has nitrogen gas at a pressure of 1.0atm. The gas and liquid are in thermal equilibrium. While waiting for lab to start, you...
  13. Q

    Methanal vs Hexanone Boiling Point Comparison

    Which one has higher boiling point?Methanal or Hexanone?
  14. S

    Cracking of hydrocarbons and boiling point of salt water

    Can alkenes be cracked or only alkanes can be cracked? Then what would the products be? Like for alkanes a alkenes must always be formed but what about for alkenes cracking? Also, when we boil salt water its temperature is 101.4 degrees. But when performing fractional or simple distillation...
  15. T

    Understanding the Boiling Point: Thermodynamic Proof

    If we add a small amount of heat δq to a liquid at its boiling point Tb, it could either increase its temperature a small amount dT = δq/Cv, or suffer a phase change into vapor. Experimentally, we see that liquids remain at Tb until the phase change is complete, and only then continue...
  16. D

    Phase Change and Lowest Boiling Point

    I am studying for the MCAT and I am having a hard time understanding the rationale for the following question from my review: Q: One of the limitations of using a gas as a shock absorbing cushion is that under high pressure, the gas may liquefy and lose compressibility. Which of the...
  17. M

    Enthelpy of vapourisation vs boiling point

    Ethanol has a higher ΔHvap than water (43.5 vs 41.3 kJ/mol). But water has a higher boiling point (373 vs 352K). How do we explain this?!
  18. M

    Determing Boiling Point elevations in lab

    I am trying to get the calculations and the data to match up in lab. The boiling point elevation predicted by the equation does not match up to the one I am getting by direct measurement. What am I doing wrong?
  19. T

    Vapor pressure and the boiling point of a liquid

    I'm not totally sure this topic should be placed in this forum, since it is not specifically solid state. Anyways, my question is simply why is there a correlation between vapor pressure and the boiling point of a substance, I would have thought that the boiling point would be at any...
  20. P

    Calculating Molal Boiling point elevation constant HELP

    Calculating Molal Boiling point elevation constant! HELP! So here's how I did my problem, but the answer I arrived with is wrong. I need help with this...:cry: Carbon disulfide (CS2) boils at 46.30°C and has a density of 1.261g/mL. When 0.250 mol of a nondissociating solute is dissolved in...
  21. P

    Find True Boiling Point with Barometric Pressure

    I'm doing a lab and I was wondering how to find the true boiling point of water in a room given the barometric pressure in inches(just the equation). I looked on Google and I couldn't seem to find anything about it.
  22. Y

    Impurities on melting point and boiling point of water

    When impurities was added to the water, it tends to increase the boiling point of the water to 102 degree celcius and lower the melting point of the water to -2 degree celcius! Why this happen? Is it because the impurities tends to absorb the heat supplied to boil the water causing it to take in...
  23. S

    Boiling point and vapor pressure

    I am trying to understand the concept of boiling from a very fundamental perspective. Most textbooks say that: as a liquid is heated, it's vapor pressure increases. When the vapor pressure reaches the surrounding pressure(or atmospheric pressure at that point), then boiling occurs. I agree...
  24. S

    Boiling point and vapor pressure

    I am trying to understand the concept of boiling from a very fundamental perspective. Most textbooks say that: as a liquid is heated, it's vapor pressure increases. When the vapor pressure reaches the surrounding pressure(or atmospheric pressure at that point), then boiling occurs. I agree...
  25. jaumzaum

    Why acetaldehyde has a higher boiling point than ethylamine?

    Ethylamine has 2 hydrogen bonds, Acethaldehyde has no one, so why the second has a higher boiling point?
  26. T

    Calculate Normal Boiling Point of Ethyl Alcohol

    Homework Statement What is the normal boiling point in Celsius of ethyl alcohol if a solution prepared by dissolving 26.0g of glucose C6H12O6 in 285g of ethyl alcohol has a boiling point of 79.1 Celsius? Kb for ethyl alcohol is 1.22( Celsius x kg)/mol . Homework Equations 26g of...
  27. R

    Is the boiling point directly related to the volatility of a substance?

    I know that volatility is more or less proportionally related to vapor pressure. If they are directly related, are they any exceptions where a more volatile substance may have a higher boiling point than a less volatile substance?
  28. T

    Which substance has the highest boiling point?

    Of the following substances which has the highest boiling point? H20, CO2, CH4, Kr, NH3 I already know the answer is H20 but I would've initially chosen NH3 because of the nitrogen bond to hydrogen but that's obviously wrong. Is it H20 because oxygen is more electronegative then nitrogen??
  29. H

    Predicting missing boiling point in the following series of compounds:

    Homework Statement a) CH4 -164 C , SiH4 -112 C, GeH4, -90 C, SnH4, ? C. b) H2O ? C, H2S -61 C, H2Se -41 C, H2Te -2 C The Attempt at a Solution a)This was an assignment and the right answer was T= -75 C. I did a graph starting from CH4 to SnH4 and I know this because its going...
  30. A

    Caculating normal boiling point using an equation of a line

    Homework Statement The equation for the best fit line was y = - 5307.5x + 19.55. Using the equation of the best fit line, calculate the heat of vaporization and the normal boiling point (in C) of this volatile liquid. (Hint: What is the value of Pvap when liquid boils at its normal boiling...
  31. P

    Can a vacuum of 1.5 Bar be used to lower the boiling point of liquid?

    Now this may seem a stupid question, but as my old dad said there are no stupid questions only stupid answers! I am distilling some liquid which has a boiling point of about 190 C, I have put the liquid under vacuum of -1bar and the liquid now boils at about 160C, I would like the liquid to...
  32. Z

    Boiling Point before Melting Point?

    How can an element boil before it melts? I came across this- As - Melting Point 816 C and Boiling Point 615 C. Every other element given along with this element in my book has its melting point lower than boiling point which makes sense to me. I am curious to know what is different about As...
  33. T

    Among the six measurements of the boiling point of a silsicon compound

    Question: Among the six measurements of the boiling point of a silsicon compound, the size of the error was 0.07, 0.03,0.14,0.08 and 0.03 degree C . Assuming that these data can be looked upon as a random sample from the population given by. f(x; \theta) = 2 (\theta - x) / \theta2 for 0 < x...
  34. T

    Among six measurement of the boiling point of a silicon compound,

    Question: Among six measurement of the boiling point of a silicon compound, the size of the error was 0.07,0.03,0.14,0.08 and 0.03 degree Celsius. Assuming that these data can be looked upon as a random sample from the population given by f(x;\theta) = 2(\theta-x)/\theta for 0<x<\theta =0...
  35. K

    Boiling point at a certain pressure

    How can one calculate the boiling of a liquid at a pressure different from standard temperature? Am trying to do it using the ideal gas equation, (PV)/T=(P'V')/T' Where P is the STP, V is 22.4l, T= boiling point at STP, P'= new pressure, V' is the new volume and T' is to be found. But is...
  36. S

    What is the Boiling Point of Mineral Oil in a Vacuum?

    Boiling point in a vacuum... Gidday, I am as new here as it gets, and I have a question to post. I have been having a (heated) discussion with regards to the temperature that water boils in a vacumm. Given: @ 10in Hg water will boil at 192F. If you had a pressure reading of 29.7in of...
  37. S

    Boiling Point of Nitrogen References

    I'm writing up a report on an experiment I did involving liquid nitrogen. I need to state the boiling point of liquid nitrogen (77.36K) in the report, as I've used it in calculations, but I don't know if I should get a reference for it or not. I did use a reference (Wikipedia and Google...
  38. A

    Boiling point of water in a closed container

    Hi all, for a closed container with water under pressure in it, let's say GAUGE PRESSURE of the container is 101 kPa, what will the boiling point of water in that vessel be? Will it be 100 deg C, or will it be 120 deg C because the ABSOLUTE PRESSURE of the water in that vessel is 202kPa...
  39. A

    Why Does Water Boil at 155°C Under 600 psi Pressure?

    Boiling Point H20 @ 600 psi? According to the psychometric chart boiling point of water @ 600 psi is 252 C. I have a chamber with water inside (in forms of weight measured drops). I am purging CO2 at 600 psi in the chamber. After am heating the chamber to 155 deg C expecting the water to...
  40. C

    Question on the Boiling point of NaCl solution.

    The experimental boiling point of the NaCl solution is lower than that calculated, assuming that NaCl is completely dissociated in solution. Why is this the case? I'm thinking that this is because some of the Na+ and Cl- ions reassociate for a short time, thus causing the solution to...
  41. A

    Vapor pressure, its decrease and subsequent lowering of boiling point

    I gather the following: - A decrease in atmospheric pressure leads to a decrease in boiling point - Thermodynamics explains this using mathematics - A kinetic theory model can also be used to explain I need to know: - The science behind this occurring. Why does a lower atmospheric...
  42. S

    Understanding Boiling Point: Factors That Affect Liquid Vapor Pressure

    Hello! I often read that the boiling point of a liquid is when its vapor pressure is equal to the atmospheric pressure. What I don't understand is why they never take the pressure of the water into consideration? Doesn't water pressure increase as depth increases and wouldn't this have to be...
  43. B

    Can Small Amounts of Chemicals Lower Water's Boiling Point?

    Is there any catalyst or substance that can do this?
  44. C

    Gas that turn into liquid have a boiling point?

    I now know that gas can turn into liquid when condition are met (temperature and pressures) But I wonder, Is these liquid from gas have a boiling point? and since at normal temp (room temperature) these liquid turn back to gas state, dose that mean their boiling point are below zero? For...
  45. P

    Boiling Point & Van der Waals Force: Weight Dependency

    1.Why does boiling point depend on weight ? 2.Does the vanderwall force depend on weight ?
  46. W

    Finding normal boiling point given pressure and enthelpy.

    Homework Statement Given the following data, determine the heat of vaporization and normal boiling point of ammonia Temp (K): 200 210 220 230 235 Pressure (respectively)(torr): 65.3 134.3 255.7 456.0 597.0 Homework Equations ln(p2/p1)=-deltaH/R(1/t2-1/t1) The Attempt...
  47. S

    How does molecular shape affect boiling point in organic compounds?

    In organic chemistry, What causes a compound to be more soluble than others? What causes a compound to have a higher boiling point than others? I think the more molecular mass a compound has, the higher boiling point. However, methoxymethane and ethanol both have the same molecular mass...
  48. S

    Question on normal boiling point and enthelpy of vaporization

    Hello all I performed a lab where we put a graduated cylinder filled to 90% with water upside down in a large beaker filled with water and measured the volume of the air bubble inside the graduated cylinder at different temperatures. When I graphed Ln(PH20) vs. 1/T I got a slope of -10412...
  49. D

    Calculating Boiling Point of HF: ΔH and ΔS Equation Analysis

    find the boiling point of HF according to the following reaction HF(L) --> HF(G) ΔH=7.53 [KJ/mol] ΔSsys=0.0257[KJ/(mol*K)] i used the equation ΔH=-ΔS*T >>T=-ΔH/ΔS >>T=-0.0257/7.53 T=-292.996°K surely this is meant to be positive ? have i used the wrong equation?? which other...
  50. S

    Raising boiling point of salt water

    How much salt per quart does it take to raise the temperature of water to 325 degrees at 28 PSI? I am sorry to say I am not educated in physics but I do understand the more particles in the water the higher the boiling point. I am trying to plasticize animal horns in a pressure cooker with a...
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