What is Absorption: Definition and 531 Discussions

Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.
Absorption spectroscopy is employed as an analytical chemistry tool to determine the presence of a particular substance in a sample and, in many cases, to quantify the amount of the substance present. Infrared and ultraviolet–visible spectroscopy are particularly common in analytical applications. Absorption spectroscopy is also employed in studies of molecular and atomic physics, astronomical spectroscopy and remote sensing.
There are a wide range of experimental approaches for measuring absorption spectra. The most common arrangement is to direct a generated beam of radiation at a sample and detect the intensity of the radiation that passes through it. The transmitted energy can be used to calculate the absorption. The source, sample arrangement and detection technique vary significantly depending on the frequency range and the purpose of the experiment.
Following are the major types of absorption spectroscopy:

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  1. M

    Why does silver have lower absorption than zirconium at 35 keV?

    so just about finishing a report on x ray abosprtion on different materials, generally the linear attneuation coefficent increases with atominc number Z. However silver(47) had a lower attenuation coefficent then zirconium(40) despite having the significantly higher value of Z. With some...
  2. M

    X RAY ABSORPTION edge explination

    so just about finishing a report on x ray abosprtion on different materials, generally the linear attneuation coefficent increases with atominc number Z. However silver(47) had a lower attenuation coefficent then zirconium(40) despite having the significantly higher value of Z. With some...
  3. G

    Choosing the Right Material for Shock Absorption

    Hello! I’ve recently become very interested in Sorbothane as a shock absorbing material, with the purpose of protecting sensitive equipment of mine from drops. My background on physics is limited and I would really appreciate any help, especially since Sorbothane can be costly and I’m a...
  4. M

    Effect of altering incident light intensity on absorption

    Hi all, Physics was never my strong point at school, yet here I am looking at the differences between three types of graduated light filter for a Health Sciences Masters degree. I'm in the process of writing up, and one of my sets of results is a bit bewildering. Basically, I measured the...
  5. P

    X-Ray emission and Bragg Scattering (K-Alpha and K-beta absorption)

    Homework Statement Complete this sentence. When doing Bragg scattering of x-rays off of NaCl, the first order K-Alpha peak has an energy that is ___________ the energy of the second order K-Alpha peak. Known Information It is known that the Intensity of the K-Alpha is greater than the K-Beta...
  6. L

    X-ray absorption spectroscopy - fine edge structure

    Hi, could someone tell me how the fine edge structure next the the absorbing edge in an XAS arises? from my understanding an XAS is a plot of absorption coefficient against energy of incoming xray. The absorption edge is at an energy corresponding to when the energy is just sufficient to...
  7. D

    Mass Transfer - GAS ABSORPTION help

    Homework Statement A Mixture of air and acetone is being vented from a solvent recovery plant. The air has to be scrubbed and this is done by absorbing the acetone into water in an absorption column. The acetone is present in small amounts and its concentration never rises above 4 mol % of the...
  8. Q

    MCNP - Measuring Neutron Absorption in a Moderator

    Hello all. I'm am a first time poster but a long time visitor. I am having a little trouble that I was hoping someone far wiser and more knowledgeable than myself might be able to help with. I've been using MCNP to investigate criticality in a simple geometry consisting of a central natural...
  9. N

    Understand Infrared Absorption & Vibrational Frequencies

    I'm confused about infrared spectroscopy. Wikipedia states that "when the frequency of the IR is the same as the vibrational frequency of a bond, absorption occurs." However, if I look at some vibrational transitions of HCl for the anharmonic oscillator, I see: 0-->1 \omega = 2885.7...
  10. P

    Absorption of Photon by a Free Electron - Impossible - Conservation Laws?

    Hey, It seems like this is impossible because momentum conservation is violated. I had a Q where an electron underwent an energy transition and emitted a photon, and then they asked whether it was possible for the photon to be reabsorbed by the electron to undergo the same transition as...
  11. V

    Understanding the Gap in a HCl Absorption Spectrum

    Looking at a HCl spectrum (from hyerphysics: http://hyperphysics.phy-astr.gsu.edu/hbase/molecule/vibrot.html), I don't understand why there is a gap in the middle of the spectrum that seems to act as a line of symmetry in the x-axis. Can anyone help please?
  12. O

    Energy absorption by aircraft fuselage

    Homework Statement 1. When an aircraft flies above the clouds during the daylight period it is continuously exposed to sunlight. This sunlight heats up the cabin. Although the outside air temperature at cruise altitude is – 56 degrees this is still one of the determining factors for the sizing...
  13. V

    Low absorption , high absorption

    hi, this might be the wronge place to post this but trying to find this info on the web is exceedingly dificult. I need a material that is cheap has a heat insulating effect and has high transparency and permeability for al forms of the light spec rum including uv and infared. That is part...
  14. AlexChandler

    Radiation Emission and Absorption

    Homework Statement A sphere of radius 0.500 m, temperature 27.0°C, and emissivity 0.850 is located in an environment of temperature 77.0°C. At what rate does the sphere (a) emit and (b) absorb thermal radiation? (c) What is the sphere's net rate of energy exchange?Homework Equations...
  15. R

    X-ray absorption by semiconductors

    Hi, i am doing a project course in masters. i need help regarding on X-ray Spectrum absorption by semiconductors. I am doing the simulations in XOP(X-ray oriented programs) software which is freeware at http://www.esrf.eu/UsersAndScience/Experiments/TBS/SciSoft/xop2.3 . So, my doubt is...
  16. T

    How Much Flux is Absorbed by a Silicon Wafer?

    Homework Statement A silicon wafer that is 200 um thick has no front reflection, 30% back reflection and absorption coefficient \alpha=39.9 cm^{-1}. What is the flux absorbed? Homework Equations Beer's absoorption law: \Phi(x) = \Phi_0 e^{-\alpha x} The Attempt at a Solution...
  17. A

    Absorption Spectrum of Hydrogen

    When white radiation is passed through a sample of hydrogen gas(atoms assumed actually) why are absorption lines observed in Lyman series only? The corresponding photon energy range for visible light(380-780nm) are 1.59-3.27eV which should cause transitions of electrons in the first excited...
  18. D

    Absorption of gamma rays experiment (opinions?)

    Hey I recently did an experiment on the absorption of gamma rays I calculated the thickness and the no. of counts, got a nice exponential curve. So, I used lead as the absorbent or shielding material for gamma... Any suggestions what else I can use for gamma? I thought about sausages or...
  19. E

    Light absorption and reflection

    Hi there! I have a question about the classical interaction of light with matter according the Drude-Lorentz model. Let's suppose that the light in matter has a wave-number k which in general is complex. Then the real part of k accounts for the propagation of light, while the imaginary part of...
  20. M

    Photoinduced Absorption Spetcroscopy

    I am studying on the electrical properties of organic compounds and having a problem with photoinduced absorption spectroscopy applied to these materials. Because in all the books, articles, etc , information given is on the results of applying this method. However i need to learn what PIA...
  21. G

    ZPF Absorption Rate in Magnetization of Electrons

    Homework Statement Just basically want to see if my algebra is ok. Homework Equations All are relevent. The Attempt at a Solution Calculating Rates in Magnetic Moments to Predict Period Interaction Between a Fermion and the Zero-Point Field First we must identify the net...
  22. J

    Explaining the Unexpected Spikes in a Quantum Well Absorption Spectrum

    I'm looking in a textbook at a discussion of a semiconductor quantum well which is being irradiated and an absorption spectrum produced. Electrons are being promoted across the band gap and holes are being created. There are heavy hole and light hole transitions, and the spectrum shown rises in...
  23. I

    Random Walk - Expected Time Until Absorption

    Homework Statement Consider the following random walk on the integers: \mathbb{S}=\{0, 1, 2, 3, ... , L\} Let Wn = {the state k \in\mathbb{S} you are in after the n'th transition} \mathbb{P}[W_{n+1}= k \pm 1 | W_{n} = k] = \frac{1}_{2} For \ 1\leq k\leq L-1 Otherwise...
  24. A

    Heat absorption, reflection, and radiation

    Homework Statement 1.if you were to paint a house that reflects heat during summer and radiates heat during winter nights. which color should a house be painted? green, red, black, white, or pink? 2. why do gardeners mix soot in the soil? The Attempt at a Solution 1.i say it is...
  25. A

    Does Ancestral Location Affect Vitamin C Absorption from Berries and Fruits?

    Is there difference in absorption rate between various berries and fruits due to a place where you and your ancestors have lived? What I meant, is it true that my organism will absorb vitamin C much better from black currant than from lemon or kiwi (because I live in Baltic states and black...
  26. T

    How Does a Slab Reach Thermal Equilibrium When Exposed to Blackbody Radiation?

    Consider a slab of matter contained within two infinite planes a distance of s = 1m apart. absorption coefficent =1m2kg-1 density of slab 1kgm-3 heat capacity 103^3jk-1kg-1 assume the absorption coefficient to be independent of wave length 1.Suppose one face of a slab is illuminated...
  27. P

    Calculating Laser Power Absorption: 800 nm, 20 W, 0.25 cm Layer

    Hi,I need help with this question Assume you have a laser emitting a wavelength of 800 nm with power 20 W. You irradiate a goblet filled with water whose layer is 0.25 cm thick. The absorption coefficient of water at this wavelength is 0.65 cm-1. a) What is the remaining power behind the...
  28. C

    Photoelectric absorption in x-ray imaging

    I'm sure I'm overlooking something simple here. I am trying to understand characteristic x-rays given off during photoelectric absorption of a photon. The energy from the photon is given to an inner orbital electron and the photon no longer exists. The electron uses the energy to escape, and...
  29. S

    Thermodynamics issue with absorption heat pumps

    I have been recently trying to advance my understanding of thermodynamics, but i have encountered a problem when it comes to absorption heat pumps and similar systems. The standard heat pump requires an energy input, to move heat energy from one location to another. Most would consider...
  30. D

    Light absorption through water

    Homework Statement I am currently doing a biology honours project at university and have been stumped by a fairly basic physics hurdle. I need to know the equation to calculate the amount of light absorbed by water/unit depth. I have tried to find the equation all over but cannot find...
  31. M

    Visible light Absorption Spectra vs Color of mineral

    I have been wondering how to realize the color of a mineral by having the absorption Spectra... The following case is an example; The image is the absorption spectra of a Bolivian Amethyst which looks like this; [PLAIN]http://www.tequilabay.com/amethyst300lbbolivian.jpg I have tried...
  32. C

    Passive Absorption of Quinine in Stomach vs Ileum

    Homework Statement The antimalarial drug quinine has pka = 8.4; is it likely to be absorbed by passive diffusion through lipid membranes in the stomach (ph = 0.9) or ileum (ph \approx 8)? Why? Homework Equations n/a The Attempt at a Solution If the pH of the environment is...
  33. J

    Light Absorption Mechanism: Electrons, IR, UV Heating

    This is probably a really basic question, but I realized I'm not sure what the answer is. What is the mechanism for light heating an object? Are photons always absorbed by electrons (if they are absorbed at all)? Maybe this will help explain my question: People often say that infrared light...
  34. I

    Absorption (without energy level transition).

    This thread is related to another question that I have been pondering. In most objects that we experience on a daily basis (a green shirt for example), we know that most of the frequencies of light striking the object are absorbed. I simply can't believe that the atoms in the shirt have...
  35. K

    The absorption of a linearly polarized photon.

    Linearly polarized light does not carry angular momentum. However, individual photons emitted, say, in the direction of the X-axis, carries a spin angular momentum \hbar in the direction + X or -X. And, when absorbing of the photon, target gets its energy h\nu and its angular momentum \hbar. Is...
  36. R

    Exploring the Practical Uses of Band Gaps and Free Carrier Absorption

    what is the practical use of the concept of band gap other than classification between material? can free carrier absorption be manipulated by changing band gaps?
  37. M

    Exploring Exponential Decay in Light Absorption

    Hi I'm self-teaching calculus and I'm looking at exponential growth and decay. The differential equation for relationships like these if this was related to time is dP/dt = -kP i.e. the rate of change in P with time decreases at a rate which is proportional to the amount of P present. I can...
  38. N

    What determines the absorption strength in molecular bands?

    I have a very basics question. I have a question about absorption in molecular bands. When looking at spectra in the infrared region and comparing it with simulated spectra, I can see that some lines get partially absorbed and then grows to fully absorbed in the "center" of the absorption...
  39. S

    Absorption Lines in Gas Atoms: Examining Electron Transitions

    The diagram (see attached) represents some of the energy levels for an atom of a gas. White light passes through the gas and absorption lines are observed in the spectrum. Which electron transition produces the absorption line corresponding to the lowest frequency; A. E3 to E2 B. E2 to E3 C...
  40. M

    What's the difference between emission and absorption?

    My textbook says "absorption yields color. emission yields fluorescence" - can someone explain what that means exactly. I know color is when something absorbs all wavelengths except one, which gets reflected and produces color. If it helps... the chapter is on bohr's model.
  41. M

    Black Body Net Heat Absorption Problem

    Homework Statement A naked person, whose skin area is 1.7 m2, sits in a sauna that has a wall temperature of 61oC. If the person’s skin temperature is 37oC, find the net rate at which the person absorbs heat by radiative transfer (assume an emissivity e of 1). How much liquid must the...
  42. J

    Reflection loss during absorption spectroscopy

    An isotropic solid has a refractive index of 10 at low frequencies. A 10 um thick platelet of this solid with perfectly polished planes shows two absorption bands in optical transmission. These bands, corrected for reflection, have a (negative) Gaussian shape. They occur at frequencies of 3x1012...
  43. GRB 080319B

    Photosynthesis Chlorophyll wavelength absorption

    Why do the chlorophyll in land plants absorb primarily in the blue and red wavelengths, http://en.wikipedia.org/wiki/File:Solar_Spectrum.png" ? Isn't more energy available in 500nm green light vs 700nm red light? E =\frac{hc}{\lambda}
  44. H

    What is the Interaction of Solar Neutrinos with Matter?

    Hi, I'm trying to find out the total number of solar neutrinos that interact with the human body per second or per lifetime. I know we are exposed to many, most which pass straight through us, but I'm interested to know how neutrinos interact with matter. Thanks.
  45. T

    Absorption bands on electronic spectra

    I have several electronic spectra for different cobalt complexes which I need to analyse. I am fine with finding \lambdamax and the molar absorption coefficient etc. However it also asks me to mark absorption bands on the printout and tabulate \lambdamax values and absorbance values for these...
  46. J

    Calculating the absorption coefficient from little information

    Hello, I am currently creating a program that calculates the change in observed intensity (nadir) from initial intensity within the atmosphere. As I am studying particular compounds, a first suggestion for my work is to produce a 'forward model' based on very simplistic radiative transfer...
  47. M

    Questions re: absorption spectrum

    Hi readers, I'm confused about some aspects of absorption spectroscopy, and hoping someone can de-confuse me First, just a preliminary question; am I right in thinking that when an electron absorbs a photon, the electron will then emit a photon of the same frequency and energy as the one...
  48. E

    Photon absorption via changing EM field

    Does it work like that.. that a changing EM field in-phase (actually, like.. 180 degre (spell?) out-of phase) with the incoming photon would absorb it? .. when sound waves of 180 degre.. (spell) out of phase with each other would cancel each other out. The same thing would happen with EM...
  49. A

    Absorption spectrum in chlorophyll

    I have a question. We claim that the wavelength of a photon must exactly match the difference between the states of an atom or molecule. Then why are the peaks in the absorption spectrum of chlorophyll so broad? Shouldn’t they be very sharp?
  50. C

    Total absorption through medium along ray

    I have a 3D graphics book, which gives the formula for absorption of radiance along a ray. I am trying to derive the details and would like to see if my derivation is correct. Let o(p) be the probability density that light is absorbed per unit length at point p. They give the formula as...
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