Absorption Spectrum of Hydrogen

In summary, the conversation discussed why only absorption lines from the Lyman series are observed when passing white radiation through a sample of hydrogen gas. This is due to the corresponding photon energy range for visible light not being enough to cause transitions in the first excited state (n=2) and therefore only allowing for absorption in the Balmer series. It was also mentioned that the minimum energy required to excite an electron from the n=1 shell is 10.2eV, which is not available for photons of visible light. It was concluded that the state of the atom is important in determining which series will be observed, with the Lyman series containing only ultraviolet waves.
  • #1
aim1732
430
2
When white radiation is passed through a sample of hydrogen gas(atoms assumed actually) why are absorption lines observed in Lyman series only?
The corresponding photon energy range for visible light(380-780nm) are 1.59-3.27eV which should cause transitions of electrons in the first excited state(n=2) only.This should give absorption spectrum lines in Balmer series.Am I wrong?
Please,I am studying Bohr's model and any explanation involving quantum physics(except of course the very basics) will not be clear to me.
 
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  • #2
In what energy level should a hydrogen atom in the sample be in order to absorb a photon in the Balmer series? That is, what should the initial value of n be?
 
  • #3
Second,of course(n=2).
But it is not mentioned in the question that the atoms are in ground state hence I assumed a random distribution. Anyways it takes a minimum of 10.2eV to excite an electron from n=1 shell which is clearly not available for photons of visible light.
 
  • #4
aim1732 said:
Second,of course(n=2).
But it is not mentioned in the question that the atoms are in ground state hence I assumed a random distribution. Anyways it takes a minimum of 10.2eV to excite an electron from n=1 shell which is clearly not available for photons of visible light.
Correct. Although the question does not mention it, you are supposed to figure it out and you have. The question also doesn't mention that the sample of hydrogen is bathed in 10.2 eV photons, therefore it is a good assumption that it is not.
 
  • #5
It exactly depends on the state of the atom .For Lyman Series the shortest wave length is 91.2 nm correspond to 13.6 ev and the longest is 121.5 nm correspond to 10.2 ev and all other wavelength in this series are between these 2 limits.So it is clear that this series contains only ultra violate waves.
 

Related to Absorption Spectrum of Hydrogen

1. What is the absorption spectrum of hydrogen?

The absorption spectrum of hydrogen is a series of dark lines in the visible light spectrum that occur when hydrogen gas is exposed to a continuous spectrum of light. These lines represent the wavelengths of light that are absorbed by the hydrogen atoms.

2. How is the absorption spectrum of hydrogen used in scientific research?

The absorption spectrum of hydrogen is used in a variety of scientific research, including astronomy, chemistry, and physics. It can be used to identify the chemical composition of stars and other celestial objects, as well as to study atomic and molecular properties of hydrogen and other elements.

3. What causes the dark lines in the absorption spectrum of hydrogen?

The dark lines in the absorption spectrum of hydrogen are caused by the absorption of specific wavelengths of light by the hydrogen atoms. This occurs because the electrons in the hydrogen atoms can only exist in certain energy levels, and when they absorb a photon of light, they jump to a higher energy level, creating a dark line in the spectrum.

4. How is the absorption spectrum of hydrogen different from the emission spectrum?

The absorption spectrum of hydrogen is created when hydrogen gas absorbs certain wavelengths of light, while the emission spectrum is created when hydrogen gas emits certain wavelengths of light. The emission spectrum is often used to identify the elements present in a sample, while the absorption spectrum can be used to study the properties of the elements themselves.

5. Can the absorption spectrum of hydrogen be used to study other elements?

Yes, the absorption spectrum of hydrogen can be used to study other elements as well. This is because many other elements also have specific energy levels that their electrons can occupy, and therefore, they will also have absorption lines in their spectra. By comparing the absorption spectra of different elements, scientists can learn more about the properties of those elements and their interactions with light.

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