Quadratic Stark Effect - Perturbation Theory

In summary, the conversation discusses the use of a parity operator to determine the parity of a given operator. It is noted that the operator ##PH_1## and ##H_1P## have opposite parity due to the operator ##H_1## being proportional to the z-direction. The concept of a matrix element between two parity states is also introduced, with the example of ##<n'l'm'p'|PH_1 + H_1P|nlmp>## being discussed. It is mentioned that the diagonal matrix elements for this operator vanish, but the reason for this is unclear. Further clarification is requested for these points.
  • #1
unscientific
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Homework Statement



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Homework Equations


The Attempt at a Solution



With a parity operator, Px = -x implies x has odd parity while Px = x implies x has even parity.

Things that puzzle me

1. Why is ##[H_0,P] = 0## and ##H_1P = -PH_1##? Is it because ##H_1 \propto z## so ##Pz = -z##? Then shouldn't it be ##PH_1 = -H_1##?

2. For any operator R, it is represented by a matrix ##R_{ij} = <i|R|j>##. In this case is the operator in question ##PH_1 + H_1P##? What does 'matrix element between two parity states' mean? From what I see, ##<n'l'm'p'|PH_1 + H_1P|nlmp>## is simply the addition of two matrices, one corresponding to ##PH_1## and another ##H_1P##. Which has odd/even parity and why?

3. Why do all diagonal matrix elements vanish?
 
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bumpp
 
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bumpp
 
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bumppp
 
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bumpp
 
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Would appreciate clarifying doubts on the 3 points above!
 

Related to Quadratic Stark Effect - Perturbation Theory

1. What is the Quadratic Stark Effect?

The Quadratic Stark Effect is a phenomenon that occurs when an external electric field is applied to an atom or molecule. It causes a shift in the energy levels of the atom or molecule, resulting in a splitting of the spectral lines.

2. How does Perturbation Theory explain the Quadratic Stark Effect?

Perturbation Theory is a mathematical approach used to approximate the effects of a small perturbation (such as an external electric field) on a system. In the case of the Quadratic Stark Effect, Perturbation Theory can be used to calculate the shift in energy levels caused by the electric field.

3. What are the factors that affect the magnitude of the Quadratic Stark Effect?

The magnitude of the Quadratic Stark Effect depends on several factors, including the strength of the external electric field, the polarizability of the atom or molecule, and the energy difference between the energy levels involved in the transition.

4. Can the Quadratic Stark Effect be observed in any type of atom or molecule?

Yes, the Quadratic Stark Effect can be observed in any atom or molecule that has an electric dipole moment. This includes most atoms and molecules, as they have a distribution of positive and negative charges that create an electric dipole moment.

5. How is the Quadratic Stark Effect different from the Linear Stark Effect?

The Linear Stark Effect is a first-order effect, meaning it is directly proportional to the strength of the electric field. On the other hand, the Quadratic Stark Effect is a second-order effect, meaning it is proportional to the square of the electric field. This makes the Quadratic Stark Effect stronger and more noticeable than the Linear Stark Effect.

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