Ionic Strength Calculation: How to Account for All Ions in a Solution?

In summary, the conversation discusses adjusting a solution of acetic acid and NaCl to a specific pH by adding NaOH. The individual also mentions using a correction suggested by Sortwell 2001 to calculate the undissociated concentration of acetic acid, which takes into account the ionic strength of the solution. The question is then posed about how to calculate this ionic strength and whether it includes both NaCl and NaOH. The answer is that all ions present in the solution must be taken into consideration.
  • #1
ionic
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Hi,

I have a solution containing acetic acid and NaCl. The solution is adjusted to a particular pH value by adding NaOH. For the calculation of the undissociated acetic acid concentration, I use the correction suggested by Sortwell 2001 (J. Food Prot. 63(2): 222-230 (2000)), which says that I have to account for the ionic strength in order to calculate pKa properly.

But my question is: how do I calculate this ionic strength? Do I only take NaCl into account? Or do I also account for the presence of NaOH?

Thanks!
 
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  • #2
All ions present in the solution, but I have already answered this question somewhere else :wink:
 
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Related to Ionic Strength Calculation: How to Account for All Ions in a Solution?

1. What is ionic strength and why is it important in chemistry?

Ionic strength is a measure of the total concentration of ions in a solution. It takes into account the charge and size of the ions present. In chemistry, ionic strength is important because it affects the behavior of ions in a solution, including their solubility, reactivity, and ability to form complexes.

2. How is ionic strength calculated?

Ionic strength is calculated by summing the concentration of each individual ion in a solution, multiplied by the square of its charge. This value is then divided by 2 and expressed in units of mol/L or molarity.

3. What is the relationship between ionic strength and conductivity?

There is a direct relationship between ionic strength and conductivity. As the ionic strength of a solution increases, so does its conductivity. This is because a higher concentration of ions in a solution allows for more charge to be carried, resulting in a higher conductivity.

4. How does temperature affect ionic strength?

Temperature can affect ionic strength indirectly by altering the solubility of ions in a solution. As temperature increases, the solubility of most salts also increases, leading to a higher ionic strength. However, temperature can also directly affect the activity coefficients of ions, which can influence ionic strength as well.

5. Why is ionic strength important in biological systems?

Biological systems, such as cells and enzymes, rely on a delicate balance of ions for proper functioning. The ionic strength of a cell's environment can affect the transport of ions across cell membranes, the activity of enzymes, and the stability of proteins. Therefore, understanding and controlling ionic strength is crucial in biological research and applications.

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