In the synthesis of ester, how does conc. aqueos calcium chloride

In summary, conc. aqueous calcium chloride is used in the synthesis of ester to remove excess water from the reaction mixture, which can hinder the reaction and decrease the yield of ester. It does this by absorbing water and forming a solution that can be easily separated from the ester product. While other compounds can be used for this purpose, conc. aqueous calcium chloride is a commonly used and effective option. It is necessary to remove as much water as possible in order to achieve a high yield of ester, as even small amounts can significantly decrease the yield. When handling conc. aqueous calcium chloride, it is important to take safety precautions such as wearing protective gear and working in a well-ventilated area.
  • #1
cyt91
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In the synthesis of ester, how does conc. aqueos calcium chloride remove excess ethanol? I tried google, and found out that a complex is formed. How is this possible? If then what exactly is the complex formed? Thanks. :smile:
 
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  • #2


Obviously some kind of association between the hydroxyl and the calcium ion. I've seen this kind of association with calcium hydroxide as well. Calcium hydroxide is not very soluble in water but sugar greatly enhances its solubility.
 

Related to In the synthesis of ester, how does conc. aqueos calcium chloride

1. What is the purpose of adding conc. aqueous calcium chloride in the synthesis of ester?

Conc. aqueous calcium chloride is added to the reaction mixture in order to remove any excess water. This is important because water can hinder the reaction and decrease the yield of ester.

2. How does conc. aqueous calcium chloride remove excess water?

Conc. aqueous calcium chloride is a hygroscopic compound, meaning it has the ability to absorb water. In the reaction mixture, it will absorb any water present, forming a solution of calcium chloride and water which can be easily separated from the ester product.

3. Can other compounds be used instead of conc. aqueous calcium chloride?

Yes, other compounds such as molecular sieves or anhydrous magnesium sulfate can also be used to remove excess water in the synthesis of ester. However, conc. aqueous calcium chloride is a commonly used and effective option.

4. Is it necessary to completely remove all water from the reaction mixture?

Yes, it is important to remove as much water as possible in order to achieve a high yield of ester. Even small amounts of water can decrease the yield significantly.

5. Are there any safety precautions to consider when handling conc. aqueous calcium chloride?

Yes, conc. aqueous calcium chloride can irritate the skin and eyes, so it is important to wear protective gloves and eyewear when handling it. It is also important to handle it in a well-ventilated area as it can release harmful fumes.

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