E-field Perturbation of 2D rotor. Show Y_10 couples ground state?

In summary, the conversation discusses the Hamiltonian of a molecule in an external electric field and the field-induced contribution to the ground-state energy. The action of the perturbation operator on the ground-state wave function is also explored, specifically showing that only one state, with angular momentum quantum number l = 1 and magnetic quantum number m = 0, is coupled to the ground state. The mathematical meaning of this coupling is also questioned.
  • #1
fandango92
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Homework Statement



Consider a molecule with an electric dipole moment d. The Hamiltonian of a molecule in the external electric field E is: [itex]\hat{H} = \frac{\hat{L^2}}{2I} - dE \cos{\theta}[/itex], where the polar angle [itex]\theta[/itex] characterises the orientation of the molecule. (We have chosen the field direction as the angular momentum quantisation axis.) Let us find field-induced contribution to the ground-state energy.

Consider the action of the perturbation operator [itex]\hat{V} = −dE \cos{\theta}[/itex] on the ground-state wave function [itex]Y_{00}[/itex]. How does the function [itex]Y_{00}[/itex] depend on angles? Use this to show that there is only one state which is coupled to the ground state by [itex]\hat{V}[/itex], the state with [itex]\ell = 1[/itex] and [itex]m = 0[/itex].

Homework Equations




The Attempt at a Solution



I have stated that [itex]Y_{00}[/itex] does not depend on angles, but have no idea how to show that [itex]Y_{10}[/itex] is the only state that couples with the ground state.
 
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  • #2
What does it mean mathematically to say that a state ##Y_{l,m}## is coupled to the ground state ##Y_{0,0}## by ##\hat{V}##?
 

Related to E-field Perturbation of 2D rotor. Show Y_10 couples ground state?

1. What is an E-field perturbation?

An E-field perturbation is a change or disturbance in the electric field of a system. It can be caused by external factors such as applied voltages or by changes in the system itself.

2. How does a 2D rotor respond to an E-field perturbation?

A 2D rotor, also known as a two-dimensional rigid rotor, is a model used to study the behavior of molecules in a gas phase. When an E-field perturbation is applied, the rotor will experience a change in its orientation and rotational energy levels.

3. What is the significance of Y_10 in the perturbation of a 2D rotor?

Y_10, also known as a spherical harmonic, represents the orientation of the electric field with respect to the rotor. It is a crucial factor in determining the response of the rotor to the perturbation.

4. How does the ground state of a 2D rotor couple with Y_10 in an E-field perturbation?

The ground state of a 2D rotor is the lowest energy state. When coupled with Y_10, it determines the overall orientation of the rotor in response to the E-field perturbation.

5. What are the practical applications of studying E-field perturbation of 2D rotors?

Understanding the behavior of 2D rotors in response to E-field perturbations is essential in fields such as molecular spectroscopy and quantum mechanics. It allows for the analysis and prediction of molecular properties and behaviors, which has implications in various industries, including pharmaceuticals and material science.

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