Why is the volume of a gas bigger during a phase change

In summary, the volume of gas produced during a phase change, such as water changing to gas at 1 atm, is significantly greater than the original volume of the liquid being used due to the spreading out of gas molecules to fill the container. This is because, according to the equipartition theorem, the average energy per degree of freedom is the same for gas and liquid at equilibrium. However, liquid water has a higher heat capacity and more degrees of freedom, resulting in more kinetic energy per molecule compared to gaseous water at the same temperature.
  • #1
Richie Smash
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Hello, I would like to know, why is the volume of gas produced during phase change significantly more than the original volume of the liquid being used? Say water changing phase at 1atm.
 
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  • #3
Gas molecules don't necessarily have more kinetic energy than liquid -- it depends on the temperature. If you raise the temperature past the boiling point, it will change to gas. But below the boiling point, you can have gas (called vapor) and liquid in equilibrium at the same temperature.

The volume of a gas is greater since the molecules spread out to fill the container. In a liquid, the molecules are stuck to each other, so they don't fill the whole container (just the bottom, assuming gravity is pulling them down).
 
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Likes russ_watters
  • #4
Khashishi said:
Gas molecules don't necessarily have more kinetic energy than liquid
Is there a way to show that ?
 
  • #5
Ok thank you, both sound correct to me
 
  • #6
BvU said:
Is there a way to show that ?
The equipartition theorem states that the average energy in a mode is ##\frac{1}{2} kT##. So, the energy per degree of freedom is the same for a gas and liquid at equilibrium. But, if you want a complete answer, you need to know how many modes there are.

Wikipedia has a table here
https://en.wikipedia.org/wiki/Heat_capacity
which shows that liquid water has a higher heat capacity than gaseous water at 100C. I think this means the liquid water has more degrees of freedom than gaseous water, and therefore contains more kinetic energy per molecule. Of course, gaseous water has more potential energy than liquid water.
 

Related to Why is the volume of a gas bigger during a phase change

1. Why does the volume of a gas increase during a phase change?

The volume of a gas increases during a phase change because the molecules of the gas are able to move more freely and are less constrained by intermolecular forces. This allows the molecules to spread out and take up more space, resulting in an increase in volume.

2. What causes the volume of a gas to expand during a phase change?

The expansion of a gas during a phase change is caused by an increase in the average kinetic energy of the gas molecules. As the temperature increases, the molecules gain more energy and move faster, leading to an increase in volume.

3. How does the volume of a gas change during a phase transition?

During a phase transition, such as from a liquid to a gas, the volume of the gas increases significantly. This is because the molecules are transitioning from a more compact liquid phase to a more spread out gaseous phase, resulting in an increase in volume.

4. Why does the volume of a gas decrease when it undergoes a phase change from gas to liquid?

When a gas undergoes a phase change to become a liquid, the molecules lose a significant amount of kinetic energy and are forced to come closer together due to intermolecular forces. This results in a decrease in volume as the molecules become more tightly packed.

5. How does pressure affect the volume of a gas during a phase change?

According to Boyle's Law, the volume of a gas is inversely proportional to the pressure exerted on it. During a phase change, there may be a change in pressure due to a change in temperature or external factors, which can also impact the volume of the gas. As pressure increases, the volume of the gas decreases and vice versa.

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