What Is the Entropy Change When Ice Melts in a Room at 20 Degrees Celsius?

In summary, the melting of the 15 kg block of ice at 0°C in a room with a temperature of 20°C is an irreversible process. The net entropy change of the system during this process is calculated by using the equations dS = Q/T for constant temperature and Q = m*Lf, where Lf = 3.34 x 10^5 J/kg for water. By only considering the phase change from ice to water, the entropy change is calculated to be 18351 J/K. However, the room also experiences a decrease in entropy as it loses energy to melt the ice, which can be calculated using the first law of thermodynamics and the temperature of the room. The overall entropy change for the system
  • #1
ks23
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Homework Statement


A 15 kg block of ice at 0 celsius degrees melts to liquid water at 0 celsius degrees inside a large room that has temperature 20 celsius degrees. Treat the ice and the room as an isolated system, and assume that the room is large enough for its temperature change to be ignored.
a) Is the melting of the ice reversible or irreversible?
b) Calculate the net entropy change of the system during this process.


Homework Equations


dS = Q/T for constant temperature
Q = m*Lf, where Lf = 3.34 x 10^5 J/kg for water
dS = int(dQ/T) for non-constant temperature


The Attempt at a Solution


I've tried to calculate the phase change from ice to water using dS=Q/T, getting 18351 J/K and then adding the entropy change for the temperature change from 0 to 20 degrees using dS=int(dQ/T)=m*c*ln(T2/T1), getting 4443 J/K. Thats no where near the correct answer, which is supposed to be 1250 J/K.
PLEASE help
 
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  • #2
Hello ks23,

Welcome to Physics Forums!

ks23 said:
I've tried to calculate the phase change from ice to water using dS=Q/T, getting 18351 J/K
So far so good. :approve:
and then adding the entropy change for the temperature change from 0 to 20 degrees using dS=int(dQ/T)=m*c*ln(T2/T1), getting 4443 J/K.
Hold on. The problem statement doesn't say anything about letting the liquid water warm up to 20 degrees. You can stop the calculations the moment the ice completely melts. There's no need in this particular problem to let the water and room reach thermal equilibrium. The problem statement only concerns itself with the ice melting.
Thats no where near the correct answer, which is supposed to be 1250 J/K.
PLEASE help
Don't forget about the entropy decrease of the room (ignoring the ice). The entropy of the ice==>water (ignoring the room) increases as it melts. The entropy of the room (ignoring the ice/water) decreases by some amount too because it is loosing energy that is ultimately transferred into the ice to make it water. How much energy does the room lose? (The 1st law of thermodynamics should help you with this one.) What is the temperature of the room? The overall entropy change is the sum of the ice/water's entropy change with the room's entropy change.
 

Related to What Is the Entropy Change When Ice Melts in a Room at 20 Degrees Celsius?

1. What is entropy change?

Entropy change is a measure of the change in disorder or randomness in a system. It is a thermodynamic property that describes the amount of energy that is unavailable for work in a system.

2. How do you calculate entropy change?

To calculate entropy change, you need to know the initial and final states of a system, and the amount of heat and temperature at each state. The formula for entropy change is ΔS = Q/T, where ΔS is the change in entropy, Q is the heat transferred, and T is the temperature.

3. What units are used to measure entropy change?

The SI unit for entropy change is joules per kelvin (J/K). However, it can also be measured in other units such as calories per degree Celsius (cal/°C) or kilojoules per kelvin (kJ/K).

4. Can entropy change be negative?

Yes, entropy change can be negative. This means that the disorder or randomness in a system has decreased. This can occur when a system becomes more ordered, such as when a gas is compressed or when a liquid freezes into a solid.

5. How is entropy change related to the second law of thermodynamics?

The second law of thermodynamics states that the total entropy of a closed system will always increase over time. Entropy change is a measure of the increase in disorder or randomness in a system, so it is directly related to the second law of thermodynamics.

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