Understanding No Energy Degeneracy in Sakurai's Quantum Mechanics

In summary, the conversation discusses a statement in Sakurai Modern Quantum Mechanics about energy degeneracies in the free particle in an infinite spherical well. The text explains that for a given ##l## value, there are no energy degeneracies except for any accidental equality between zeros of spherical Bessel functions of different order. However, in the case of the isotropic harmonic oscillator, there are degenerate energy eigenvalues in the ##l## quantum number. This degeneracy is due to additional symmetries, such as SO(4) for the non-relativistic Coulomb problem and SU(3) for the 3D harmonic symmetric oscillator.
  • #1
euphoricrhino
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Hello, I'm hoping someone can help me understand a statement in Sakurai Modern Quantum Mechanics (3rd edition).
In particular, in the section that describes free particle in infinite spherical well (page 198, section 3.7.2), after the text has shown that for a given ##l## value, the energy eigenvalues correspond to the nodes of spherical Bessel functions, the last paragraph went on and said

"It should be noted that this series of energy levels shows no degeneracies in ##l##. Indeed, such degenerate energy levels are impossible, except for any accidental equality between zeros of spherical Bessel functions of different order."

How can there be no energy degeneracy for a given ##l##? Don't all the ##m## state for the same ##l## count as degeneracies?

If I understand this statement as specifically referring to the radial part of the wave function (hence ##m## degeneracies are not in scope), the next few pages (pp201) discussed degeneracies of isotropic oscillator, where the text stated

"Quite unlike the square well, the three-dimensional isotropic harmonic oscillator has degenerate energy eigenvalues in the ##l## quantum number. There are three states (all ##l=1##) for ##N=1##. For ##N=2## there are five states with ##l=2##, plus one state with ##q=1## and ##l=0##..."
where clearly the ##m## states are counted as degeneracies here.

Any insightful explanations are greatly appreciated!
 
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  • #2
After some thoughts, I think I misunderstood the statement. Degeneracy in ##l## means two different ##l## values ending up at the same energy eigenvalue. So the two cases are indeed what the text claims to be :)
 
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  • #3
I think the latter is what Sakurai means. The degeneracy wrt. the "magnetic quantum number" ##m## is valid for all radially symmetric potentials due to rotation invariance of the problem. Degeneracy wrt. to the angular-momentum quantum number ##\ell## is special and indicates additional symmetries. E.g., for the non-relativistic Coulomb problem (hydrogen atom) it's an SO(4) symmetry. For the 3D harmonic symmetric oscillator it's SU(3).
 
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1. What is energy degeneracy in Sakurai's Quantum Mechanics?

Energy degeneracy refers to the phenomenon where multiple quantum states have the same energy value. In other words, there are different quantum states that have the same energy level, making it impossible to distinguish between them based on energy alone.

2. Why is it important to understand the concept of no energy degeneracy in quantum mechanics?

Understanding no energy degeneracy allows us to accurately predict the behavior of quantum systems and make precise calculations. It also helps us understand the principles of quantum mechanics and how particles behave at the atomic and subatomic level.

3. How does Sakurai's Quantum Mechanics explain the absence of energy degeneracy?

Sakurai's Quantum Mechanics incorporates the concept of spin, which is an intrinsic property of particles that affects their energy levels. By taking into account the spin of particles, Sakurai's theory can explain why energy degeneracy does not occur in certain quantum systems.

4. What are some real-life applications of understanding no energy degeneracy in Sakurai's Quantum Mechanics?

Understanding no energy degeneracy is crucial in various fields such as quantum computing, materials science, and particle physics. It allows scientists to accurately model and manipulate quantum systems, leading to advancements in technology and our understanding of the universe.

5. Are there any exceptions to the absence of energy degeneracy in quantum mechanics?

Yes, there are certain scenarios where energy degeneracy can occur in quantum systems. For example, in certain symmetrical systems, multiple quantum states can have the same energy level. However, these exceptions are well understood and can be accounted for in calculations using Sakurai's Quantum Mechanics.

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