Trichloroacetic acid: electron density and stability

In summary: The electronegativity of the chlorine atoms draws the electrons, to a small extent, as pointed out above, towards themselves. This 'slight' (?) delocalization of the electrons lowers the overall energy of the molecule; whereas, without the chlorine atoms, the electrons would generally reside in a much smaller area (around the oxygen atoms), and therefore the overall energy of the molecule would be higher, and therefore the molecule would be less stable. Resonance is used here to describe the mechanism behind the decreased stability of the molecule.
  • #1
nobahar
497
2
"The rather strong acidity of trichloroacetic acid is usually ascribed to the inductive effect of the three chlorine atoms attached to the end of the molecle opposite the acidic proton. Electron density is withdrawn away from the carboxylate group so that the trichloroacetate anion that is formed when the acid dissociates is stabilized." (Skoog, West, Holler & Crouch, 2003)

Isn't oxygen more electronegative than chlorine? So why does the electron density shift in favour of the chlorine atoms? Is it because they outnumber the oxygen atoms, or is it a consequence of the structure (shape) of the molecule?
Also, what is the meaning of the term "stabilized" as used here?
Any input appreciated. I will also continue to search elsewhere; so far it's been to no avail.
 
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  • #2
The chlorine atoms are replacing hydrogen atoms and chlorine is certainly more electronegative than hydrogen. So, while the chlorine atoms are not going to pull all or most of the electron density away from the oxygen, they will pull some electron density away and the oxygen atom will have less electron density than if the chlorines had not been present.
 
  • #3
Stabilization most likely refers to the carboxylic group.

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methods
 
  • #4
Thanks Yggdrasil and Borek. For some reason I took it to mean a change after the proton had departed, but as your explanation makes clear its disucussing the molecule as it stands.

Borek said:
Stabilization most likely refers to the carboxylic group.
What does it mean by stable in this usage? If it was unstable, or less stable, what would this mean?
 
  • #5
Think resonance.

--
methods
 
  • #6
Thanks Borek.
I think I understand:
The electronegativity of the chlorine atoms draws the electrons, to a small extent, as pointed out above, towards themselves. This 'slight' (?) delocalization of the electrons lowers the overall energy of the molecule; whereas, without the chlorine atoms, the electrons would generally reside in a much smaller area (around the oxygen atoms), and therefore the overall energy of the molecule would be higher, and therefore the molecule would be less stable.
Have I understood resonance correctly? And if so, have I understood it's application here?
Thanks!
 

Related to Trichloroacetic acid: electron density and stability

1. What is the electron density of trichloroacetic acid?

The electron density of trichloroacetic acid is the measure of the distribution of electrons within the molecule. It is determined by the number and arrangement of atoms and their bonds in the molecule.

2. How does the electron density of trichloroacetic acid affect its stability?

The electron density of trichloroacetic acid plays a crucial role in its stability. Higher electron density can make the molecule more prone to reactions and less stable, while lower electron density can make the molecule more stable and less reactive.

3. What factors influence the electron density of trichloroacetic acid?

The electron density of trichloroacetic acid can be influenced by several factors, including the electronegativity of the atoms involved, the size of the molecule, and the presence of any functional groups that may attract or donate electrons.

4. How does the electron density of trichloroacetic acid change in different environments?

The electron density of trichloroacetic acid may change in different environments due to the presence of other molecules or solvents. For example, in a polar environment, the electron density may be affected by the attraction or repulsion of other polar molecules.

5. Can the electron density of trichloroacetic acid be measured experimentally?

Yes, the electron density of trichloroacetic acid can be measured experimentally using techniques such as X-ray crystallography or nuclear magnetic resonance (NMR) spectroscopy. These methods allow scientists to visualize the distribution of electrons within the molecule and determine its electron density.

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