Minimum heat removed from gas to restore its state

In summary: Let To be the initial temperature of the gas before the free expansion. Can you find the temperature of the gas at the beginning and end of the final step in terms of To? Hint: What is the temperature at the beginning and end of the isobaric compression?Yes.Yes.
  • #1
hnnhcmmngs
19
0

Homework Statement



After a free expansion to quadruple its volume, a mole of ideal diatomic gas is compressed back to its original volume isobarically and then cooled down to its original temperature. What is the minimum heat removed from the gas in the final step to restoring its state?

Homework Equations



pV = nRT
W = pΔV
ΔEint = Q - W

The Attempt at a Solution



I think ΔEint would be zero since it returns to its original temperature, so
Q = W
However, I don't know where to go from here. Could somebody explain?
 
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  • #2
After the isobaric compression, I think the gas would need to be heated rather than cooled in order to get back to the initial state.

What happens to the temperature of the gas during the free (adiabatic) expansion?
What happens to the temperature of the gas during the isobaric compression?

Based on the answers to these questions, should the gas be heated or cooled after the isobaric compression in order to return to the initial state?
 
  • #3
TSny said:
After the isobaric compression, I think the gas would need to be heated rather than cooled in order to get back to the initial state.

What happens to the temperature of the gas during the free (adiabatic) expansion?
What happens to the temperature of the gas during the isobaric compression?

Based on the answers to these questions, should the gas be heated or cooled after the isobaric compression in order to return to the initial state?
During the adiabatic expansion the temperature remains constant, correct?
And during the isobaric compression the temperature decreases since the pressure remains constant and the volume decreases, correct?
So the gas should be heated?
 
  • #4
hnnhcmmngs said:
During the adiabatic expansion the temperature remains constant, correct?
And during the isobaric compression the temperature decreases since the pressure remains constant and the volume decreases, correct?
So the gas should be heated?
Yes, Yes, and Yes.
 
  • #5
TSny said:
Yes, Yes, and Yes.
Then why does the question say "then cooled down to its original temperature"? How am I supposed to calculate the heat removed from the gas?
 
  • #6
hnnhcmmngs said:
Then why does the question say "then cooled down to its original temperature"?
It appears that whoever wrote the problem was mistaken. The gas is heated in the last step.

How am I supposed to calculate the heat removed from the gas?
You can try to find the heat added during the final step.

Let To be the initial temperature of the gas before the free expansion. Can you find the temperature of the gas at the beginning and end of the final step in terms of To? Hint: What is the temperature at the beginning and end of the isobaric compression?

Knowing the initial and final temperatures for the final step, can you find the heat added during this last step (if you assume the last step takes place at constant volume)?
 
Last edited:

1. What is minimum heat removed from gas?

Minimum heat removed from gas is the smallest amount of heat that needs to be taken away from a gas in order to restore it to its original state.

2. Why is it important to remove minimum heat from gas?

Removing minimum heat from gas is important because it can help prevent the gas from reaching its critical temperature, which can lead to a loss of physical and chemical properties.

3. How is the minimum heat removed from gas determined?

The minimum heat removed from gas is determined by the specific heat capacity of the gas and its initial and final temperatures. It can be calculated using the formula Q = mCΔT, where Q is the heat removed, m is the mass of the gas, C is the specific heat capacity, and ΔT is the change in temperature.

4. What factors can affect the minimum heat removed from gas?

The minimum heat removed from gas can be affected by factors such as the type of gas, its initial and final temperatures, and the amount of gas present. It can also be influenced by external factors such as pressure and volume changes.

5. How is the minimum heat removed from gas used in practical applications?

The concept of minimum heat removed from gas is used in various practical applications, such as refrigeration and air conditioning systems. By removing heat from a gas, these systems can effectively cool and control the temperature of a space or object.

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