Interpretation of the polarizability

In summary, when using the Lindhard formula to calculate the static polarizability of an electron gas, the function remains constant until a certain point (q=2k_F). After this point, the function decays, indicating that short wavelengths are not screened effectively. For values of k < 2k_F, this can be understood through Thomas-Fermi theory where the external potential modifies the local Fermi energy and orbital filling. However, for higher values of k > 2k_F, the electronic wavefunctions must be bent, causing a greater energy cost.
  • #1
daudaudaudau
302
0
Hello!

If one uses the Lindhard formula to calculate the static polarizability of an electron gas, [itex]\chi(q)[/itex], you get a function which is pretty much a constant until [itex]q=2k_F[/itex] with [itex]k_F[/itex] being the Fermi wave vector. After this it decays(it's on page 335 of Ashcroft and Mermin). But what is the interpretation of this? Somehow short wavelengths are not screened very well?
 
Physics news on Phys.org
  • #2
bump :)=
 
  • #3
For k<2k_K, you can understand static screening in therms of Thomas-Fermi theory, i.e. the external potential modifies the local Fermi Energy and the filling of the orbitals, in terms of perturbation theory, you work with zeroth order wavefunctions and change only occupation, due to the degeneracy of the electron gas, this costs little energy. For higher values of k >2k_F, you really have to bend the electronic wavefunctions which costs more energy (I would guess of the order of min(k-2k_F)*k_F/m=min(k-2k_F)*v_F).
 

Related to Interpretation of the polarizability

1. What is polarizability and why is it important in science?

Polarizability is a measure of the ability of a molecule to be distorted by an external electric field. It is important in science because it helps us understand the behavior of molecules in different environments, such as in a solution or in the presence of other molecules.

2. How is polarizability measured?

Polarizability is typically measured using spectroscopic techniques, such as Raman spectroscopy or infrared spectroscopy. These techniques involve shining a light on a sample and measuring the changes in the light as it interacts with the molecules.

3. What factors affect the polarizability of a molecule?

The polarizability of a molecule is influenced by factors such as its size, shape, and electronic structure. Larger molecules tend to have higher polarizability, while molecules with more delocalized electrons are more easily polarized.

4. How does polarizability relate to intermolecular interactions?

Polarizability plays a crucial role in intermolecular interactions, as it determines how molecules can interact with each other. For example, molecules with higher polarizability may have stronger dipole-dipole interactions, which can affect properties such as boiling point and solubility.

5. Can polarizability be manipulated?

Yes, polarizability can be manipulated by changing the electronic structure of a molecule. This can be done through chemical modifications or by changing the conditions of the environment, such as temperature or pressure. Understanding and controlling polarizability is important in various fields, such as materials science and drug design.

Similar threads

  • Atomic and Condensed Matter
Replies
0
Views
646
  • Quantum Interpretations and Foundations
Replies
21
Views
2K
  • Quantum Interpretations and Foundations
Replies
7
Views
2K
Replies
1
Views
4K
  • Quantum Physics
5
Replies
143
Views
6K
  • Advanced Physics Homework Help
Replies
6
Views
2K
  • Quantum Interpretations and Foundations
Replies
28
Views
7K
  • Electromagnetism
Replies
28
Views
2K
  • Other Physics Topics
Replies
0
Views
780
Back
Top