- #1
Telemachus
- 835
- 30
It is easy to show that when you have a quantum system, let's think for example in electrons in a metal, then there appears summation over electron states of the form, e.g. for the energy for a free electron gas at T=0K:
##E=2 \sum_{k\leq k_f} \frac{\hbar^2}{2m}k^2##
Where ##k_f## denotes the Fermi wave vector.
In general one has sums of the form:
##\sum_{k} F(\vec{k})##
Now, for a free electorn gas one has that the volume in k space per allowed k value is ##\Delta \vec{k}=\frac{8\pi^3}{V}## where V is the volume of the solid (I'm following Aschroft and Mermin, solid state physics, page 37). So that in the limit of large V, one has:
##\displaystyle \lim_{V\rightarrow \infty} \frac{1}{V} \sum_{k} F(\vec{k}) \Delta k= \int \frac{d^3k}{8\pi^3} F(k).##
For the energy at non zero temperature one has
##E=2 \sum_k \epsilon(k) f(\epsilon_k)##
With:
##\epsilon_k=\frac{\hbar^2}{2m}k^2##
In general one has a dependence on energy ##\epsilon## per electron on the wave vector k, and f denotes the Fermi-Dirac distribution.
In the limit of large V, one then has:
##\lim \frac{E}{V}=u=\frac{1}{4\pi} \int \epsilon(k)f(\epsilon(k))d^3k##
Now, for the arbitrary function ##F(k)##, one can solve the integral in spherical coordinates:
##\int \frac{d^3k}{8\pi^3} F(k)=\frac{1}{\pi^2}\int dk k^2 F(\epsilon_k)##
So, that's ok, now the next step the book does is the one that is not clear to me how to get. In this step, this integral is taken to the one that is commonly used to evaluate the internal energy, or the number of electrons, etc. its the integral which I call as the "Sommerfeld type" because is that Sommerfeld used to make the "Sommerfeld expansion"
In this step, it is introduced the density of states
##\frac{1}{\pi^2}\int dk k^2 f(\epsilon_k)=\int_{-\infty}^{\infty} d\epsilon g(\epsilon) F(\epsilon)##
Where is used the fact that the integrand depends on ##\vec k## only through the electronic energy ##\epsilon =\frac{\hbar^2}{2m}k^2##
I hoped to derive this result just by calculation of the differentials, to get something like ##d\epsilon g(\epsilon)=\frac{k^2 dk}{\pi^2}##
The density of states is defined as ##g(\epsilon)=\frac{dn}{d\epsilon}##
Where ##n=\frac{N}{V}## is the number of electrons per unit volume, the electronic density.
##E=2 \sum_{k\leq k_f} \frac{\hbar^2}{2m}k^2##
Where ##k_f## denotes the Fermi wave vector.
In general one has sums of the form:
##\sum_{k} F(\vec{k})##
Now, for a free electorn gas one has that the volume in k space per allowed k value is ##\Delta \vec{k}=\frac{8\pi^3}{V}## where V is the volume of the solid (I'm following Aschroft and Mermin, solid state physics, page 37). So that in the limit of large V, one has:
##\displaystyle \lim_{V\rightarrow \infty} \frac{1}{V} \sum_{k} F(\vec{k}) \Delta k= \int \frac{d^3k}{8\pi^3} F(k).##
For the energy at non zero temperature one has
##E=2 \sum_k \epsilon(k) f(\epsilon_k)##
With:
##\epsilon_k=\frac{\hbar^2}{2m}k^2##
In general one has a dependence on energy ##\epsilon## per electron on the wave vector k, and f denotes the Fermi-Dirac distribution.
In the limit of large V, one then has:
##\lim \frac{E}{V}=u=\frac{1}{4\pi} \int \epsilon(k)f(\epsilon(k))d^3k##
Now, for the arbitrary function ##F(k)##, one can solve the integral in spherical coordinates:
##\int \frac{d^3k}{8\pi^3} F(k)=\frac{1}{\pi^2}\int dk k^2 F(\epsilon_k)##
So, that's ok, now the next step the book does is the one that is not clear to me how to get. In this step, this integral is taken to the one that is commonly used to evaluate the internal energy, or the number of electrons, etc. its the integral which I call as the "Sommerfeld type" because is that Sommerfeld used to make the "Sommerfeld expansion"
In this step, it is introduced the density of states
##\frac{1}{\pi^2}\int dk k^2 f(\epsilon_k)=\int_{-\infty}^{\infty} d\epsilon g(\epsilon) F(\epsilon)##
Where is used the fact that the integrand depends on ##\vec k## only through the electronic energy ##\epsilon =\frac{\hbar^2}{2m}k^2##
I hoped to derive this result just by calculation of the differentials, to get something like ##d\epsilon g(\epsilon)=\frac{k^2 dk}{\pi^2}##
The density of states is defined as ##g(\epsilon)=\frac{dn}{d\epsilon}##
Where ##n=\frac{N}{V}## is the number of electrons per unit volume, the electronic density.