How do the units of polarizability differ between SI and Gaussian systems?

  • Thread starter Steven Hanna
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In summary: UnitsIn summary, polarizability is a ratio of the induced dipole moment to the applied electric field. In SI units, it is represented as C m^2/V, while in Gaussian units it is represented as cm^3. This is due to the difference in the dimensions of dipole moment and electric field in these two systems of units.
  • #1
Steven Hanna
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Can someone explain how it is possible for polarizability to have units of volume?

uinduced = αEapplied

so when i divide u_induced by E_applied I get units of (C*m)/(V/m) = (C*m2)/(J/C) = (C2m2)/J
 
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  • #2
Steven Hanna said:
Can someone explain how it is possible for polarizability to have units of volume?

polarizability can not be visualized as a volume element ...in cgs system of units it may come out as cube of a length but in SI system it has physical more rational units as its a ratio of dipole moment induced by the external field ; one can represent it by the ratio as far as its units are concerned.
one can use C m^2. V^-1 as SI units
 
  • #3
drvrm said:
polarizability can not be visualized as a volume element ...in cgs system of units it may come out as cube of a length but in SI system it has physical more rational units as its a ratio of dipole moment induced by the external field ; one can represent it by the ratio as far as its units are concerned.
one can use C m^2. V^-1 as SI units
can you explain how it is possible for the units to work out to cm^3 in CGS but not to m^3 in SI?
 
  • #4
Steven Hanna said:
can you explain how it is possible for the units to work out to cm^3 in CGS but not to m^3 in SI?

The dipole moment has the dimension of charge times distance, which in SI units is C m (coulomb . meter).

In Gaussian units dipole moment is (stat coulomb .centimeter).

An electric field has dimension voltage divided by distance,

so that in SI units E has dimension V/m and in Gaussian units stat V/cm. Hence the dimension of α is In SI: C m^2 V−1In Gaussian: statC cm^2 .statV−1 = cm^3,

where one can use that in Gaussian units the dimension of V is equal to stat C/cm (as per Coulomb's law).
for discussion one can see
http://en.citizendium.org/wiki/Polarizability
 

Related to How do the units of polarizability differ between SI and Gaussian systems?

1. What is polarizability and why is it important?

Polarizability is a measure of how easily a molecule or atom can be distorted from its original shape by an external electric field. It is important because it helps us understand the behavior of molecules in electric fields and is a fundamental property used in various areas of physics and chemistry, such as in the study of molecular interactions and light-matter interactions.

2. How is polarizability measured?

Polarizability is typically measured experimentally using techniques such as Raman spectroscopy, infrared spectroscopy, and microwave spectroscopy. It can also be calculated theoretically using quantum mechanical methods.

3. What are the units of polarizability?

The units of polarizability depend on the system of measurement being used. In the CGS system, polarizability is measured in cubic centimeters per electrostatic unit (cm^3/esu), while in the SI system, it is measured in cubic meters per volt (m^3/V).

4. How does polarizability vary among different molecules?

The polarizability of a molecule depends on its size, shape, and electronic structure. Generally, larger molecules have higher polarizability, while more symmetric molecules have lower polarizability. Also, molecules with more polarizable bonds, such as those containing double or triple bonds, tend to have higher polarizability.

5. How does polarizability affect the physical properties of a molecule?

Polarizability can affect the physical properties of a molecule such as its boiling point, melting point, and refractive index. It can also influence its response to an electric field, leading to phenomena such as induced dipole-dipole interactions and the ability to interact with polarized light.

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