Express volume expansivity in terms of density

In summary, to express volume expansivity (B) in terms of density (ρ) and its partial derivatives, we can substitute V=m/ρ into the expansivity equation to find that β= (ρ/m)*(d/dT(m/ρ)). Then, taking the derivative of 1/ρ with respect to temperature, we get β=-m/(ρ^2)*(dρ/dT). Mass is constant and does not change with temperature, so we can cancel out a ρ and the m term to get β=(-1/ρ)(dρ/dT).
  • #1
matthewsyq1995
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0

Homework Statement


Express volume expansivity (B) in terms of density (ρ) and its partial derivatives

Homework Equations


B = (1/V) (dV/dT)
V = m/ρ

The Attempt at a Solution


I have only managed to substitute m/ρ into the expansivity equation.
Don't really understand how to manipulate the differential equation into (-1/ρ)(dρ/dT)

Especially the part where d[(m/ρ)]/(m/ρ) equals (-1/ρ)dρ
 
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  • #2
What are the properties of "m?"
 
  • #3
Given the equations you provided, we substitute V=m/ρ to find that β= (ρ/m)*(d/dT(m/ρ)). Then, take the derivative of 1/ρ with respect to temperature, so we don't just end up with -m/(ρ^2), we end up with -m/(ρ^2)*(dρ/dT). Mass is of course constant, and does not (noticeably) change with temperature. (Think back to implicit differentiation where we differentiate y^2 with respect to x to get 2y*y'). Now, we have β= (ρ/m)*(-m/[ρ][/2]*(dρ/dT)) which, when we cancel out a ρ and the m term, gives us β=(-1/ρ)(dρ/dT).
 
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Related to Express volume expansivity in terms of density

1. What is the definition of volume expansivity?

Volume expansivity, also known as thermal expansivity, is a measure of how much a substance's volume changes with temperature. It is typically denoted by the symbol β and is defined as the fractional change in volume per degree change in temperature.

2. How is volume expansivity related to density?

Volume expansivity is inversely proportional to density. This means that as the density of a substance increases, its volume expansivity decreases. This relationship is described by the equation β = α/ρ, where α is the coefficient of linear thermal expansion and ρ is the density.

3. Can volume expansivity be negative?

Yes, volume expansivity can be negative. This occurs when a substance contracts instead of expanding with an increase in temperature. An example of this is water between 0 °C and 4 °C, where the volume decreases as the temperature increases.

4. How is volume expansivity typically measured?

Volume expansivity is usually measured experimentally by measuring the change in volume of a substance as it is heated or cooled. The initial volume and temperature are recorded, and then the substance is heated or cooled to a different temperature. The final volume and temperature are then measured and used to calculate the volume expansivity.

5. What is the SI unit for volume expansivity?

The SI unit for volume expansivity is 1/K (kelvin) or 1/°C (degree Celsius). This unit represents the fractional change in volume per degree change in temperature. In other words, if the temperature changes by 1 K or 1 °C, the volume will change by the value of the volume expansivity.

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