Energy levels for mass confined to 1D box

In summary, the conversation discusses calculating the lowest 2 energy levels and characteristic temperature for a nitrogen molecule. The calculations are based on the given mass of the molecule and the length of the box. The final result suggests that the system will most likely be in excited states rather than the ground state at higher temperatures.
  • #1
SalfordPhysics
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Homework Statement


For a nitrogen molecule, calculate the lowest 2 energy levels and the characteristic temperature;
Mass of molecule = 2.33x10-26[kg]
Length of box = 10-9[m]

Homework Equations


E = n2.h2/8mL2 (n=1,2,3,...)

Characteristic Temperature (Tc) -> when thermal energy kBT = energy spacing of lowest 2 levels.

The Attempt at a Solution


[/B]
E1 = h2/(8).(2.33x10-44)
= 2.358x10-24 [J]

E2 = n2.(E1) = 4(E1) = 9.432x10-42

Tc = (E2 - E1)/kB = 7.074x10-24 / kb = 0.512 [Kelvin]

The final answer quite simply does;t seem right to me, but I have checked numerous times my calculations. Can anyone clarify please.
 
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  • #3
Just doesn't seem like 0.5 Kelvins is a reasonable answer. Main problem is that the term characteristic temperature is a new one and not quite sure of its understanding.
 
  • #4
Unless you have some common experience with nanometer size boxes, how can you even expect that you can tell what is a reasonable answer?
Your calculations seem OK. The result means that the system will be in the ground state only at very low temperatures. Otherwise will be very likely in excited states, due to the thermal excitation.
 
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  • #5
Thanks nasu, this makes sense.
 

Related to Energy levels for mass confined to 1D box

1. What is the concept of "energy levels for mass confined to 1D box"?

The concept of "energy levels for mass confined to 1D box" refers to the quantization of energy that occurs when a particle with mass is confined to a one-dimensional box. This means that the particle can only occupy certain energy levels within the box, rather than having a continuous range of energy values.

2. How is the energy level of a particle in a 1D box determined?

The energy level of a particle in a 1D box is determined by the size of the box and the mass of the particle. The energy levels are given by the equation E = (n2h2)/(8mL2), where n is the energy level, h is Planck's constant, m is the mass of the particle, and L is the length of the box.

3. What is the significance of the energy levels in a 1D box?

The energy levels in a 1D box are significant because they demonstrate the quantization of energy, which is a fundamental concept in quantum mechanics. They also provide insight into the behavior of particles at the nanoscale, where confinement effects become significant.

4. How do the energy levels change as the size of the box is altered?

The energy levels in a 1D box become closer together as the size of the box increases. This means that the energy spacing between levels decreases, and the particle has a greater range of energy values it can occupy. As the box becomes larger and approaches infinity, the energy levels become continuous, and the particle behaves more like a classical object.

5. Can the concept of energy levels in a 1D box be applied to other systems?

Yes, the concept of energy levels in a 1D box can be applied to other systems, such as a particle in a 2D or 3D box. It can also be applied to other types of confinement, such as a particle in a potential well or a molecule in a crystal lattice. The principles of quantization and energy level spacing still apply in these systems.

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