Can there be multiple ground states?

In summary, the article discusses the concept of ground state in quantum mechanics, which is the lowest-energy state of a system. It also explains the idea of degeneracy, where multiple ground states can exist with the same energy. This can occur in various systems, such as when there are two electrons in an orbital or in a crystal lattice with defects.
  • #1
marc32123
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I am reading an article on wikipedia about ground state and it says -


The ground state of a quantum mechanical system is its lowest-energy state; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. The ground state of a quantum field theory is usually called the vacuum state or the vacuum.

If more than one ground state exists, they are said to be degenerate. Many systems have degenerate ground states. Degeneracy occurs whenever there exists a unitary operator which acts non-trivially on a ground state and commutes with the Hamiltonian of the system.

I am confused about what it says there at the beginning of the second paragraph, that "If more than one ground state exists, they are said to be degenerate". It says in the paragraph before that the ground state of a quantum mechanical system is its lowest-energy state; the energy of the ground state is known as the zero point energy of the system. How could there possibly be two ground states?
 
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  • #2
Take two electrons in an orbital. One must be spin up, one must be spin down.
Use lower case for down, upper case for UP. call the electrons a and b. aB and Ab are two degenerate configurations of equivalent energy. There are dozens of other simple examples of degeneracy I can think of off the top of my head, but this should do. Another is picture a crystal lattice. Say you have a mole of atoms in the crystal. Now, at a given temperature there will be a certain number of defects present (where one atom is "off lattice"). Say this is the "ground state". How many different possibilities are there for a 6E23 atoms in a lattice with just one off lattice? How many with 2? With 3, 4, ...100, 1000000,...
 

1. What are ground states?

Ground states are the lowest energy states that a physical system can exist in. They are characterized by the most stable and lowest energy configuration of the system.

2. Can there be more than one ground state?

Yes, it is possible for a physical system to have multiple ground states. This can occur when there are different configurations of the same energy level that are equally stable.

3. What factors determine the number of ground states?

The number of ground states is determined by the properties and interactions of the system's components. Factors such as temperature, pressure, and external fields can also affect the number of ground states.

4. How does the concept of ground states relate to phase transitions?

Ground states are closely related to phase transitions, which is the process of a physical system changing from one state to another. At a phase transition, the ground state changes and the system moves to a new, lower energy state.

5. Can multiple ground states exist in all physical systems?

No, not all physical systems have the potential for multiple ground states. This is dependent on the properties and interactions of the system's components. For example, simple systems such as a single particle do not have multiple ground states, while more complex systems like solids and liquids can have multiple ground states.

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