What is Entropy: Definition and 1000 Discussions

Entropy is a scientific concept, as well as a measurable physical property that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change, and information systems including the transmission of information in telecommunication.The thermodynamic concept was referred to by Scottish scientist and engineer Macquorn Rankine in 1850 with the names thermodynamic function and heat-potential. In 1865, German physicist Rudolph Clausius, one of the leading founders of the field of thermodynamics, defined it as the quotient of an infinitesimal amount of heat to the instantaneous temperature. He initially described it as transformation-content, in German Verwandlungsinhalt, and later coined the term entropy from a Greek word for transformation. Referring to microscopic constitution and structure, in 1862, Clausius interpreted the concept as meaning disgregation.A consequence of entropy is that certain processes are irreversible or impossible, aside from the requirement of not violating the conservation of energy, the latter being expressed in the first law of thermodynamics. Entropy is central to the second law of thermodynamics, which states that the entropy of isolated systems left to spontaneous evolution cannot decrease with time, as they always arrive at a state of thermodynamic equilibrium, where the entropy is highest.
Austrian physicist Ludwig Boltzmann explained entropy as the measure of the number of possible microscopic arrangements or states of individual atoms and molecules of a system that comply with the macroscopic condition of the system. He thereby introduced the concept of statistical disorder and probability distributions into a new field of thermodynamics, called statistical mechanics, and found the link between the microscopic interactions, which fluctuate about an average configuration, to the macroscopically observable behavior, in form of a simple logarithmic law, with a proportionality constant, the Boltzmann constant, that has become one of the defining universal constants for the modern International System of Units (SI).
In 1948, Bell Labs scientist Claude Shannon developed similar statistical concepts of measuring microscopic uncertainty and multiplicity to the problem of random losses of information in telecommunication signals. Upon John von Neumann's suggestion, Shannon named this entity of missing information in analogous manner to its use in statistical mechanics as entropy, and gave birth to the field of information theory. This description has been proposed as a universal definition of the concept of entropy.

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  1. Art_Vandelay

    Entropy & Gasoline HW: Answer & Explanation

    Homework Statement Premium gasoline produces 1.23×108 J of heat per gallon when it is burned at a temperature of approximately 400ºC (although the amount can vary with the fuel mixture). If the car's engine is 25.0% efficient, three-fourths of that heat is expelled into the air, typically at...
  2. H

    Why total entropy change must be positive?

    Im not satisfied with the answer: that's just what it is... Because it kinda doesn't explain anything. Please help me, anyone?
  3. N

    Entropy change with elevation

    I have seen in a number of thermodynamics lectures that the entropy change of a system as it falls approximately isothermally from some height h to the ground is: ΔS = mgh/T (The proof basically has you conceive of a reversible process between the same two states where some upwards force acts...
  4. T

    Prove the 3 definitions of entropy are equivalent (stat. mechanics)

    Homework Statement S(E,V) = kln(\Gamma(E) )\\ S(E,V) = kln(\omega(E) )\\ S(E,V) = kln(\Sigma(E) )\\ S entropy, k Boltzmann's constant. Prove these 3 are equivalent up to an additive constant. Homework Equations \Gamma(E) = \int_{E<H<E+\Delta}^{'}dpdq\\...
  5. kelvin490

    Entropy: Problem Combining 1st & 2nd Law of Thermodynamics

    Combining first and second law of thermodynamics we can get the following equation TdS=dU-PextdV First question: Is this equation available for irreversible process that dS≠dQ/T? Second question:If the system temperature Tsys is smaller than the surrounding temperature Tsur, which...
  6. kelvin490

    Is entropy a state property in thermodynamics?

    The usual "proof" entropy is a state property is like that: "Consider a system which undergoes a reversible process from state 1 to state 2 along path A, and let cycle be completed along path B, which is also reversible. Since the cycle is reversible we can write: ∫1-2 δQ / T + ∫2-1 δQ / T...
  7. P

    Passing of time in Bolzmann's entropy curve. Is it all wrong?

    Hello guys, I was watching video about physical basis for arrow of time.. ..as well as several other videos and articles about physics of time. I am puzzled with this picture here (seen in 35:07 in video above)...
  8. T

    Entropy: Understanding the Cycle | Thermodynamics

    I'm having trouble getting my head around entropy. In an isolated system, entropy can only remain the same or increase. Is this the same for a thermodynamics cycle? What I mean is, if I drew a cycle on a PV diagram, would the entropy keep increasing? I can't see how that would work, that would...
  9. W

    What could happen after maximum entropy is reached if

    When: - Vacuum had an absolute mass, relatively limiting expension of all universal matter - Newton's second law could be overridden or negated - [Anything else I couldn't think of]
  10. D

    Standard entropy of a liquid at melting temperature

    I am presented a review of data which gives: vapour pressures of a liquid have been measured and fit to the following equation: Log10 (mmHg) = -3571/T + 8.999 The melting point has been determined to be 392.7 K. A Cp value given for the liquid is 250 J/mol K and the ΔSvap is 117 J/mol K...
  11. C

    The change in entropy of the gas vs thermal reservoir

    Homework Statement Homework Equations The Attempt at a Solution I don't know what is the difference between the change in entropy of the gas vs the thermal reservoir??
  12. R

    Entropy and Enthelpy for adiabatic process

    1) What is the reason why dH!=0 for an adiabatic(q=0) reversible process? The mathematical argument is irrefutable and it is clear that it has to do with the process not being isobaric: ΔH=ΔU+PΔV+VΔP , ΔU=work=−PΔV Therefore, ΔH=VΔP and this is not 0. However, I do not understand it...
  13. 2

    Deriving the formula for the change in entropy

    Hello. I was reading Hyperphysics website and could not get one particular part. I am providing a picture of the equation I am having trouble with: http://i.snag.gy/W3CC3.jpg The particular part that puzzles me is the relation around the third equation sign. From the formula there one can think...
  14. ChrisVer

    Solving Entropy Expression Homework Statement

    Homework Statement From the 2nd TD law: TdS= d(\rho V) + P dV - \mu d(nV) find that: S= \frac{V}{T} (\rho+P- \mu n) Homework Equations \frac{dP}{dT}= \frac{P+\rho - \mu n}{T} The Attempt at a Solution TdS= d(\rho V) + P dV - \mu d(nV) TdS= d[(\rho+ P- \mu n) V] -...
  15. D

    Standard Entropy of a liquid at melting point with no S(298.15) given

    Homework Statement Vapour pressures of a liquid have been measured and fit to the following equation: Log10 P (mmHg) = -3571/T + 8.999 The melting point has been determined to be 392.7 K. A Cp value given for the liquid is 250 J/mol K and the ΔSvap is 117.20 J/mol K Homework Equations...
  16. A

    Entropy in Information theory vs thermodynamic

    We Now From Information Theory That Entropy Of Functions Of A Random Variable X Is Less Than Or Equal To The Entropy Of X. Does It Break The Second Law Of Thermodynamic?
  17. D

    How Do You Calculate Standard Entropy at the Melting Point?

    Homework Statement vapour pressures of a liquid have been measured and fit to the following equation: Log10 (mmHg) = -3571/T + 6.124 The melting point has been determined to be 392.7 K. A Cp value given for the liquid is 250 J/mol K and theΔSvap is 117 J/mol K Homework Equations...
  18. D

    Standard Entropy for Liquid at Melting Point

    Homework Statement The vapour pressures of a liquid have been measured and fit to the following equation: Log10 (mmHg) = -3571/T + 6.124 The melting point has been determined to be 392.7 K. Calculate the standard entropy of the liquid at the melting point. Homework Equations...
  19. N

    Why is entropy zero in an adiabatic process?

    No heat exchange is facilitated during an adiabatic process. Change is heat is zero. How does this relates to the entropy being zero? ∫dQ/T? But this could really just mean that the integral is of any constant.
  20. PsychonautQQ

    Thermal: Entropy of Ideal Gas (Sackur-Tetrode equation)

    okay so I suck at La-Tex so I'm not going to put the actual equation, but it's not important for my question. In the equation the entropy is dependent on the natural log with mass in the numerator of the argument. Why is mass involved when talking about entropy at all? I mean I think of...
  21. B

    Entropy of canonical ensemble - invariant wrt energy shift?

    I have a short question which I have been discussing with a fellow student and a professor. The question (which is not a homework question!), is as follows: If you shift all the energies E_i \to E_i + E_0 (thus also shifting the mean energy U \to U + E_0), does the entropy of the system remain...
  22. C

    Problem on entropy change and specific heat capacity

    Calculate the change in entropy of the Universe as a result of the following operations: (a) A copper block of mass 0.4kg and thermal capacity 150JK-1 at 100◦C is placed in a lake at 10◦C. dS=dQ/T dQ=mCdT Tried simply combining these equations and integrating to find change of entropy of...
  23. K

    Explanation of entropy for a beginner please

    Hello, I am looking for some clarity on the second law of thermodynamics. I am an amateur physics student and only just beginning and so my understanding is currently very basic! I have watched Brian Cox's Wonders of the Universe, where he talks about the second law of thermodynamics being...
  24. C

    Calculating Entropy of Adsorbed Atoms on a Surface

    Homework Statement Suppose we put N atoms of argon into a container of volume V at temperature T. Of these N atoms, Nad stick to the surface, while the remainder Ngas = N - Nad form an ideal gas inside the container. Assume that the atoms on the surface are not able to move and have an...
  25. M

    Erik Verlinde's paper on Emergent Entropy

    There is one paragraph that says: " Our starting assumption is directly motivated by Bekenstein's original thought experiment from which he obtained is famous entropy formula. He considered a particle with mass m attached to a ctitious "string" that is lowered towards a black hole. Just...
  26. D

    Entropy of a Fermi dirac ideal gas

    Hello Homework Statement From the expression of the partition function of a fermi dirac ideal gas ln(Z)=αN + ∑ ln(1+exp(-α-βEr)) show that S= k ∑ [ <nr>ln(<nr>)+(1-<nr>)ln(1-<nr>) Homework Equations S=k( lnZ+β<E>) <nr>=-1/β ∂ln(Z)/∂Er <E>=-∂ln(Z)/∂β The Attempt at a Solution I...
  27. M

    Calculating Entropy Change for N2O4 Equilibrium in Constant Pressure Vessel

    1.0 mol of N2O4 placed in a constant pressure vessel at P = 1bar and T = 298 K. The system is allowed to slowly (reversibly) come to equilibrium. Given gibbs energy of formation, enthalpy of formation and entropy (the values are below) calculate the entropy change to the surroundings. N2O4...
  28. C

    Change in Entropy of an expanding gas

    Homework Statement Four moles of an ideal gas expands at constant temperature until its pressure is reduced to half of its initial value. What is the change in entropy of the gas? Homework Equations ΔS=Q/T (For constant T) pinitial=p pfinal=.5p Q=W W=pdv nrTln(vf/vi) The Attempt...
  29. A

    Entropy of Reeh-Schlieder correlations

    Any state analytic in energy (which includes most physical states since they have bounded energy) contains non-local correlations described by the Reeh-Schlieder theorem in AQFT. It is further shown that decreasing the distance between wedges will increase the entanglement as measured by a...
  30. C

    Entropy and Carnot refrigerators

    Homework Statement a)A stone at 400K with heat capacity ##c_p## is placed in a very large lake at 300K. The stone cools rapidly to 300K. Calculate the entropy change, due to this process, of the stone and lake. b)An insulated cool-box of a Carnot refrigerator at temperature T loses heat...
  31. F

    [Statistical Physics] Microstates in a large system/Boltzmann entropy

    Homework Statement For a box containing 1m^{3} of nitrogen at S.T.P., estimate the number of microstates which make up the equilibrium macrostate. Homework Equations S = Nk_{b}(ln\frac{V}{N} + \frac{5}{2} + \frac{3}{2}ln\frac{2πmk_{b}T}{h^{2}}) where the entropy of a volume, V ...
  32. N

    Entropy of a mole of a crystalline solid as a function of temperature

    Homework Statement 5. The nuclei of atoms in a certain crystalline solid have spin one. Each nucleus can be in anyone of three quantum states labeled by the quantum number m, where m = −1,0,1. This quant number measures the projection of the nuclear spin along a crystal axis of the solid. Due...
  33. Y

    Decomposition of N2O5 Entropy Equilibrium

    Please see attached picture. I need verification of my answers. I unfortunately found these problems on an old book with no answer. I would really appreciate it. (a) Ok. For this one, I am really not sure. PLEASE help. I get a very complicated formula. (1+x)(x^4)/(1-x)^2=Kp. Now, this...
  34. naima

    How to compute Von Neumann entropy?

    I know how to get Von Neumann entropy from a density matrix. I want to get a real number from measurements that give real numbers as outcomes. (there are complex numbers in a density matrix). So suppose Charlie sends 1000 pairs of particles in the same state to Bob and Alice. They agree to...
  35. N

    Change in Entropy for Irreversible Processes

    I was following along in my Thermodynamic textbook and began playing with some definitions. In the following formulation, I somehow managed to prove (obviously incorrectly) that dq = TdS for even irreversible processes. I was hoping someone could point out where in the proof I'm going wrong...
  36. P

    Calculating the change in entropy, did I calculate correctly?

    Homework Statement A 3.5 kg block of cobber at 100 degrees celsius (373 K) is put in 0.8 kg water at 0 degrees celsius (273 K). The equilibrium temperature is 30 degrees celsius (303 K). Calculate the change of entropy for the system of cobber and water. Homework Equations ΔS=\frac{Q}{T}...
  37. S

    Entropy: Destruction or Transformation?

    Ok so entropy cannot be destroyed, right? So let's say you have a reaction that decreases entropy (s<0) but it also is exothermic (h<0) and that overpowers the entropy decrease so it is spontaneous (ie h-ts=g<0). If that happens, where does the entropy go?
  38. U

    Standard change in entropy and change in entropy

    In the Gibbs free energy equation, does the standard change in entropy equal q(sys)/T(system)? Or in math terms: T(surr) * q(sys)/T(sys) = T(surr) * dS(standard) Thus dS(standard) = q(sys)/T(sys) (surr) = surroundings (sys) = systems (standard) = at standard conditions
  39. U

    Does entropy increase in this process

    Homework Statement Is boiling of egg accompanied by an increase in entropy? The Attempt at a Solution I guess entropy decreases because as the egg boils, the stuff inside it gets hardened and changes into a solid mass. So the disorderliness decreases and the entropy should decrease. But...
  40. Feodalherren

    Entropy Change from Sun to Earth: 1000 J Radiation Transfer Calculation

    Homework Statement The temperature at the surface of the Sun is approximately 5 700 K, and the temperature at the surface of the Earth is approximately 290 K. What entropy change occurs when 1 000 J of energy is transferred by radiation from the Sun to the Earth? Homework Equations...
  41. D

    Solving the Paramagnet Entropy Equation

    Homework Statement As a model of a paramagnet, consider a system of N fixed particles with spin 1/2 in a magnetic fiels H along z axis. Each particle has an energy e=μH (spin up) or e=-μH Using S=kln(Ω), show that S=k [ (N-E/e)/2 ln( 2N/(N-E/e) ) + (N+E/e)/2 ln( 2N/(N+E/e) ) ]...
  42. B

    Dumping Entropy: Exploring Why Systems Expel Excess Entropy

    "Dumping" Entropy Hello everyone, I am reading Daniel Schroeder's Thermal Physics book. One phrase he uses that I find particular confusing is that a system has to "dump" entropy. As one example, in chapter 5 he briefly discusses how a fuel cell functions, stating, "In the process of...
  43. C

    [Thermal] Is it possible that increases of moles decrease entropy?

    From Statsitical And Thermal Physics (Reif. international edition 1985) 160 page. (5.4.4) S(T,V;√) = √[∫{cv(T`)/T`}dT` + Rln(V) - Rln(√) + constant] (integral is from T0 to T , cv is specific heat) This is a entropy of system for temperature 'T' , Volume 'V' , Moles '√' <--...
  44. K

    Entropy Generation in a Rod: Heat Transfer Considerations

    Hi.. Consider a rod which is insulated on its lateral surface, now this rod is brought in contact with a source at temperature T1 and sink at temperature T2 now a temperature gradient sets up in the rod after steady state is reached temperature at some distance X from the source end is given as...
  45. K

    What is the Meaning of Entropy Change for a Reservoir?

    hi to everybody out there, entropy as i know of now is associated with heat which is basically energy in transit(for a rev. process it is indicative of unavailable part of energy) having said that what is meant by entropy change for a system as heat flows into or out of it(for instance consider...
  46. T

    Deriving entropy change equation from Boltzmann's principle

    Homework Statement Show using Boltzmann's principle (S=k.lnW), show that with respect to changes in V and T: dS=k.N.\frac{dV}V{}+\frac{C.dT}V{T} Where W=T^{\frac{C}k{}}V^{N}The Attempt at a Solution S=k.lnT^{\frac{C}k{}}V^{N}=k.lnT^{\frac{C}k{}}+klnV^{N} S=C.lnT+N.lnV Now I know that the...
  47. D

    Entropy of a system water-reservoir

    Hello, I'm studying for my exam for tomorrow and we solved an exercise in class , but a question was not answered and I don't know how to solve it. Homework Statement 1 Kg of water is heated at 0 degree C is brought into contact with a large heat reservoir at 100 degrees C. When the water...
  48. C

    Entropy change in a irreversible adiabatic process

    One mole of an ideal monatomic gas initially at 298 k expands from 1.0 L to 10.0 L. Assume the expansion is irreversible, adiabatic, and no work is done. Calculate delta S of the gas and delta S of the surroundings. I know that delta dS = dq/T but q = 0 in adiabatic processes right? So does dS...
  49. P

    Does eating decrease the entropy of my body?

    Hello, Do living beings use food to decrease the entropy of his body? If so, could anyone explain the process of how we do it? (or at least name a couple of keywords that I can search) Thank you very much.
  50. gfd43tg

    Entropy change of water mixing

    I don't know how to relate the entropies, S1 and S2, to the temperatures in my entropy balance
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