What is Absorption: Definition and 531 Discussions

Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.
Absorption spectroscopy is employed as an analytical chemistry tool to determine the presence of a particular substance in a sample and, in many cases, to quantify the amount of the substance present. Infrared and ultraviolet–visible spectroscopy are particularly common in analytical applications. Absorption spectroscopy is also employed in studies of molecular and atomic physics, astronomical spectroscopy and remote sensing.
There are a wide range of experimental approaches for measuring absorption spectra. The most common arrangement is to direct a generated beam of radiation at a sample and detect the intensity of the radiation that passes through it. The transmitted energy can be used to calculate the absorption. The source, sample arrangement and detection technique vary significantly depending on the frequency range and the purpose of the experiment.
Following are the major types of absorption spectroscopy:

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  1. H

    Indirect absorption and phonons

    In an indirect absorption process that an electron jumps from the top of the valence band to the bottom of the conduction band,why a phonon must be involved to conserve the momentum? At these two points (top of the valence band and bottom of the conduction band) the electron momentum is zero so...
  2. P

    Best material for IR absorption

    Hi all, I am looking for the best material for IR (infra red) absorption, preferably something that I can make it into a thin film; any material that would work from semiconductors, metals to more exotic materials like graphene or... I appreciate your help. Thank you
  3. S

    Thermodynamics: Heat absorption / rejection vs colour

    I am working on an automotive project and am looking to pick up any gains that I can. In doing so, I've been studying the effect that colour has on thermodynamic characteristics. To be specific, I am interested in finding: A) What colour(s) will help retain the most heat i.e. minimize thermal...
  4. J

    Callen & Welton calculation of power of absorption

    In the paper H.B. Callen, T.A. Welton, "Irreversibility and Generalized Noise", Phys. Rev. 83, 34, (1951) the authors arrive at an interesting formula for average power continually absorbed by a quantum system ( = with discrete states of definite energy) under action of a harmonic...
  5. W

    Absorption with UV/VIS spectrometer

    I need to characterize some colloids (extract the concentration of material inside). Why should I dilute the sample before measuring it with spectrometer?
  6. V

    Absorption band and absorption peak?

    The absorption spectra of some materials appear as the absorption bands (for example: TiO2 powder) while the other appear as the absorption peaks (for example: Quantum dots). Please explain why they are different?
  7. S

    Spectral lines and absorption lines

    On PF, to answer why atmosphere is transparent, users explained that atmospheric gases such as oxygen do not have absorption lines in the visible spectrum. On UColorado website, under Spectral Lines, they show that Oxygen has many visible lines in its spectral signature. This confuses me...
  8. M

    Radiant energy, spectral absorption and solid angles

    Hi I'm trying to follow a derivation, I don't think I'm allowed to post the content (copyright) but the paper is here: http://www.sciencedirect.com/science/article/pii/002240739290117M. Does anyone have access to this and know a little bit about integrating over solid angles? I've spend half...
  9. A

    Absorption prob - why my way isn't correct?

    Homework Statement A hydrogen electron is at its ground level when it's radiated in wave length of 94.92 nm. As a result it arrises to level a. then emission occures with frequency of 2.34*10^14 Hz and the electron falls to level b. What's the energy difference between the 2 levelsHomework...
  10. C

    Need help manipulating absorption spectroscopy data please

    Hi guys, So my project partner and I are struggling to solve a problem with our laser spectroscopy data for rubidium isotopes and I thought it may be a good idea to see if you could help us. If you take a look at the attached image you will see that the blue line shows our doppler free...
  11. MikeGomez

    Is photon phase a factor in absorption

    The Hpyerphysics site, while discussing coherent light of lasers, says that… “the emitted photons are "in step" and have a definite phase relation to each other.” So now I wonder about electrons of an atom absorbing photons. Assuming the correct energy level for a given photon, is the...
  12. jaumzaum

    Radiation absorption by an atom

    When we shine light on an atom, it can absorbs this radiation, stimulating its electrons to jump to a more energetic energy level. This lasts too little time, and when the electrons come back to their original (fundamental) energy level, they emit the same energy they had absorbed before. This...
  13. A

    Blackbody and absorption problem

    Well, this question may seem elementary to you but I simply do not have a background for it. Now the question: Sun radiation resembles a blackbody at over 5000°K. A solar cell's temperature is around 300°K. If we neglect loss in the cell, its emission and absorption coefficient are equal...
  14. M

    Markov Chains and absorption probabilites

    Homework Statement Could someone please help me with this question? A single-celled organism contains N particles, some of which are of type A, the others of type B . The cell is said to be in state i , where 0<=i<=N if it contains exactly i particles of type A. Daughter cells are formed...
  15. M

    Markov Chains and absorption probabilites

    Could someone please help me with this question? A single-celled organism contains N particles, some of which are of type A, the others of type B . The cell is said to be in state i where 0<=i<=N if it contains exactly i particles of type A. Daughter cells are formed by cell division, but...
  16. S

    Free carrier absorption in GaSb

    Homework Statement Given the carrier concentrations (1.4x10^16, 3.2x10^16 and 5.3x10^16 /cm^3), verify that the free carrier losses scale linearly. (use λ=10μm) Homework Equations Those concentrations are given by this paper: A. Chandola, R. Pino, and P. S. Dutta, "Below bandgap optical...
  17. I

    Evidence of single photon absorption?

    Hey all, Does anyone know of a paper or experiment that verified that a single photon is absorbed in exchange for electron excitation? Thanks
  18. J

    Understanding molecular absorption of light (UV-Vis spectroscopy)

    Hi all, I'm relatively new to the forum, but excited to be a part of a community discussing physics, as I lack company to really discuss my research at my place of work (university), as I am a physicist working solely amongst chemical engineers. I am using a UV-Vis spectrometer, with the...
  19. W

    How Does Uranium-238 Capture Neutrons and What Happens After?

    can anyone give an example in which a nucleus absorbs a neutron and becomes a stable nucleus? or the combination must break into parts?
  20. L

    Beer-lambert law of absorption.

    An aqueous solution of yeast nucleic acid of length 2.0*10^-2m and concerntrated 2.0mol m-3 has an absorptivity of 25m2 mol-1 at a certain wavelenght. calculate the percentages tranmission at this wavelenght. this is an example that i don't understant, please help me to simplify it and...
  21. H

    Blackbody emission and absorption

    I am trying to understand radiative transport of thermal energy in materials from first (or close to first) principles. I do not understand the systematics/statistics of how photons are emitted and absorbed in a medium. How is it that photons can be emitted at so many wavelengths and atoms can...
  22. F

    Quantum dots:emission versus absorption spectrum

    Hello Forum, how is is possible for quantum dots to offer a wide, broadband absorption spectrum but still have a single distinct emission wavelength? How is that asymmetry possible? For example, I would think that if we can absorb, say, 4 wavelengths, we can also emit those say 4...
  23. R

    Finding Vibrational Spacing from Fluorescence and Absorption Spectre

    Homework Statement The fluorescence spectrum of anthracene vapor in the figure shows peaks with maxima at 440 nm, 410 nm, 390 nm, and 370 nm, whereas the absorption spectrum has peaks at 360 nm, 345 nm, 330 nm, and 305 nm. Assuming that only one vibrational mode contributes to these...
  24. P

    Finding a light source that produces an absorption spectrum?

    This is an observational exercise where I have to find several different light sources and observe their spectra through a diffraction grating, then record my observations. I need two sources of each (i.e. continuous, emission, absorption). Continuous and emission are fairly easy, but for the...
  25. D

    Maximizing heat absorption through Radiation

    Hi All, I am currently investigating a method of absorbing heat from radiation. This is being done to harness heat from skin. I was wondering what was the best method to do this? Is there a particular material that is best suited to do this? I know that having the emissivity value of the...
  26. P

    Absorption and Gain for Lasers

    Homework Statement If a round trip gain in a 56.8 cm long laser is 5.16%, what is the net gain coefficient (g-\alpha). g is the small signal gain coefficient \alpha is the absorption coefficient L-length of cavity Homework Equations The Round Trip Power Gain: Gr= R1*R2*...
  27. A

    Atomic Absorption of Electrons: Mercury

    Homework Statement My class is currently going over electronic energy levels, and the book states that an electron with a kinetic energy of 9.8eV could excited two mercury atoms (first excited state above the ground state of mercury is 4.9) to their first state above the ground state...
  28. R

    How Do You Calculate Total Absorption of a Sample from Its Absorbance Spectrum?

    Hi, does anyone know how to calculate the total absorptin of a sample from its labdam-absorbance spectrum? I found a paper where the author find it as the average of the data, another one numerically integrate the spectrum over the whole lambda range.. but the two methods give different...
  29. B

    Absorption coeffcient of alumina

    I am solving a temperature distribution problem related to laser drilling. In the equation I am encountering a term called ' Absorption or extinction coeffcient' of alumina. Can anybody tell how to find this ?
  30. N

    Photon absorption and momentum recoil

    Hi When talking about atoms absorbing a photon, a classical picture is utilized. The intuitive picture often presented is that when an atom absorbs a photon, a recoil of \hbar k is obtained by the atom. After a time \tau=1/\Gamma the atom emits the photon again. So the force in this picture is...
  31. S

    Mass Absorption -V- Black Hole size

    How much mass would even the smallest of black holes have to absorb (keeping also in mind the radiation lost as it grows) to obtain its size? And considering the largest Black holes discovered so far, how much mass would it have had to gobble up to get to that size? On the average, how much...
  32. F

    Spin statistic terms in absorption cross section

    'Ello, I have a question regarding the results in this paper (and another which I will mention later) http://arxiv.org/abs/hep-ph/0212199 Now, I'm not so concerned about the 'braney' bit, but more their definition of the cross section in Eqn. (46). They have included the usual (2j+1)...
  33. B

    How to Determine Band Gap of Amorphous Materials Using Optical Absorption Edge

    Hello, I am trying to determine the band gap of an amorphous material (a glass sample) and I read that you can do this from the determination of the optical absorption edge. From this kind of measurements you fitt an equation of the type (αhν) = B (hv-Eo) 2. my question are: 1 - is it...
  34. K

    Understanding RF Absorption by Metals in RFID Testing

    Hi everyone. I was wondering how badly aluminum affects RFID waves (860-960MHz)? Do they completely absorb, reflect, combination of the two? I'm having issues with my testing of RFID. I'm getting some dead zones and I think it could be because of the portal frame the antennas are mounted on...
  35. J

    Long vs Short light wavelength absorption

    Hi all I was reading through an astrophysics book{1} and there I came across this sentence: " A dust cloud can either scatter or absorb light that passes through it. Since shorter wavelengths are affected more significantly than longer ones, a star lying behind the cloud appears reddened...
  36. A

    Radio wave attenuation and scattering and absorption

    I am trying to understand why radio waves are not greatly attenuated by the atmosphere due to scattering or absorption? I have tried searching the internet and can't find any satisfactory answers. Please help. Oh and does this property somehow relate to why they are used to transmit information...
  37. K

    The color of an apple (light absorption and emission)

    Emission of light from a solid object From my textbook (explaining why an apple is red): We imagine that the red apple in the picture is illuminated by daylight, IE light which contains all the wavelengths of the visible spectrum. The apple is red because the main part of the light it...
  38. T

    Question about absorption spectra

    Been viewing this site for a while now and very much appreciate all the contributors! I can't seem to find an answer to this anywhere so I think I may be misunderstanding the basic ideas of absorption and emission spectra... An absorption spectrum, say of our Sun, is as I understand it the...
  39. P

    Absorption and Emission Spectrum

    When an element is excited by some method, it emits electromagnetic radiations of definite wavelengths. The arrangement of these wavelengths in order of increasing wavelength is called emission spectrum of the element. (as per my book) But, the definition of absorption spectrum, I don't...
  40. A

    Does Fresnel reflection involves absorption of light?

    When a ray interacts with a solid if the surface is polished reflection occurs. This is true even if the material absorbs at the specific wave lenght? In other words if the material absorbs at the specific λ, can occurs Fresnel reflection ? Or: Fresnel reflection has always all the same λs of...
  41. J

    Glass that has minimum reflection and absorption at 1550nm

    I am building an enclosure for my laser that emits at 1550nm. I need to integrate a window for the laser light to pass through. Anybody have any recommendations on what kind of glass would work best so that the optical losses are kept at a minimum? Ideally, it would be commercially available...
  42. C

    Spectrometer setup to minimize absorption of reflected light

    I'm working on an experiment to measure the quenching of an oxygen-sensitive dye. The excitation light is blue and the light fluoresced is red. When I collect data, there is always a peak for blue and red, which makes it impossible to measure really the quenching in low dye concentrations...
  43. C

    Neutron Absorption of Lead Nuclei compared to Uranium Nuclei

    I have had a question that I cannot get an answer for. I recently had an exam for energy in the nucleus which included a question about why lead nuclei would be inadequate for use as a moderator in a reactor. When I got the answer for the question, it stated that the lead nuclei reflect neutrons...
  44. K

    UV light absorption by transparent sheets – how?

    Ok thanks for the responses to my other question; I think I now have it. I have a follow up question – that is almost on the same topic (but not quite) The complete spectrum (arund 200nm to 380nm) of UV light is absorbed by some plastics?? Elections will be moved to a more energetic orbital...
  45. D

    Colours of objects produced by light due to reflection & absorption

    Colours of objects produced by light due to reflection & absorption! Hi fellow members! We know that colours of our surrounding things is due to the absorption & reflection of particular wavelength of light. But we also see same colours of objects in bulb light aur tube light. Do they also...
  46. A

    Calculating Absorption Coefficient

    I am currently trying to graph the absorption coefficient of Copper tetra-tert butyl phthlocyanine. I have the extinction coefficient vs wavelength graph and refraction vs wavelength graph however I don't know how to use these to graph absorption coefficient. E(eV)=1242.4/λ absorption...
  47. E

    Absorption coefficient of quantum well

    we know that the quantum well absorption coefficient is calculated by summing over the electron-heavy hole and electron-light hole transitions: α_{w}(E) = \sum_{n}α_{e_{n}-hh_{n}}(E) + \sum_{n}α_{e_{n}-lh_{n}}(E) where n is the n^{th} transistion. but when the photon flux is incident...
  48. N

    How Can U-238 Cross Section Be Accurately Modeled in the Resonance Region?

    Hello , I was trying to calculate the effective absorption cross section ( group constant) of U-238 in the resonance region between neutron energies (1 ev - 10 kev) but as you can see from the picture U-238 has a lot of resonance at this region, I was wondering if there is a way I can obtain...
  49. F

    Tabulated absorption cross sections.

    Yo does anyone have a table from like Brookhaven or somewhere of absorption cross sections for just about anything in the 1/v region? And have the precision included in the data. I'm doing a pretty quick statistics assignment.
  50. S

    Mechanism of Bond Energy Absorption

    When scientists analyze proteins (chains of amino acids), often times light spectroscopy is used. Light is passes through a cuvet containing dissolved protein, and the absorption is measured. My question is: How do bonds absorb energy? What is the actual mechanism? I have been told that the...
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