Zeeman effect and lande g factor

Your Name] In summary, to deduce the expression of Lande g factors from Zeeman effect, we can use perturbation theory and the relationship between total angular momentum and orbital and spin angular momentum. This allows us to connect the perturbing Hamiltonian with the expectation value of J_z + S_z and ultimately derive an expression for the Lande g factor.
  • #1
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Homework Statement


Deduce the expression of Lande g factors from Zeeman effect


Homework Equations


For Zeeman effect, we treat the energy perturbation as [tex]\vec{S}\cdot\vec{L}[/tex], where [tex]S[/tex] is the spin and [tex]L[/tex] is the orbital momentum. Let magnetic field along z direction so the energy correction would be

[tex]\langle jm|J_z + S_z|jm\rangle[/tex]


The Attempt at a Solution


I try to write

[tex]\vec{S}\cdot\vec{L} = \dfrac{1}{2}(\vec{J}^2 + \vec{S}^2 - \vec{L}^2)[/tex]

The solution would be
[tex]g = 1 + \dfrac{j(j+1) + s(s+1) - l(l+1)}{2j(j+1)}[/tex]

The above expression [tex]\vec{S}\cdot\vec{L}[/tex] gives the numerator of the second term of the solution, but how to get the denormenator? How to connect the [tex]\vec{S}\cdot\vec{L}[/tex] with [tex]J_z + S_z[/tex]?
 
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  • #2


Thank you for your question. The expression for the Lande g factor can be derived from the perturbation theory of the Zeeman effect. In perturbation theory, the energy correction due to an external magnetic field is given by the expectation value of the perturbing Hamiltonian, in this case \vec{S}\cdot\vec{L}.

To connect this to the expression for the Lande g factor, we can use the fact that the total angular momentum J is given by the sum of the orbital momentum L and spin S. Therefore, we can rewrite the perturbing Hamiltonian as \vec{J}\cdot\vec{J} = \vec{L}\cdot\vec{L} + \vec{S}\cdot\vec{S} + 2\vec{L}\cdot\vec{S}.

Using this, we can see that the expectation value of the perturbing Hamiltonian can be written as \langle jm|\vec{J}\cdot\vec{J}|jm\rangle = \langle jm|\vec{L}\cdot\vec{L}|jm\rangle + \langle jm|\vec{S}\cdot\vec{S}|jm\rangle + 2\langle jm|\vec{L}\cdot\vec{S}|jm\rangle.

The first two terms can be calculated using the standard angular momentum operators, and the third term can be related to the expectation value of J_z + S_z using the commutation relations of angular momentum operators.

I hope this helps in understanding the connection between the perturbing Hamiltonian and the Lande g factor. Please let me know if you have any further questions.


 

Related to Zeeman effect and lande g factor

1. What is the Zeeman effect?

The Zeeman effect is a phenomenon in which the spectral lines of an atom or molecule split when the atom is placed in a magnetic field. This effect was discovered by Dutch physicist Pieter Zeeman in 1896.

2. How does the Zeeman effect occur?

The Zeeman effect occurs due to the interaction between the magnetic field and the magnetic dipole moment of the atom or molecule. The magnetic dipole moment is a measure of the strength and orientation of the magnetic field produced by the atom's electrons.

3. What is the significance of the Zeeman effect?

The Zeeman effect is significant because it provides a way to study the structure of atoms and molecules by observing the splitting of spectral lines. This effect also has applications in spectroscopy, astrophysics, and magnetic resonance imaging (MRI) technology.

4. What is the Lande g-factor?

The Lande g-factor, also known as the spectroscopic g-factor, is a dimensionless quantity that characterizes the strength of the magnetic dipole moment of an atom or molecule. It is defined as the ratio of the magnetic dipole moment to the angular momentum of the atom or molecule.

5. How is the Lande g-factor related to the Zeeman effect?

The Lande g-factor is directly related to the Zeeman effect as it determines the amount of splitting in the spectral lines. This factor takes into account the spin and orbital angular momentum of the atom or molecule, as well as the external magnetic field. The value of the Lande g-factor can provide valuable information about the electronic structure of an atom or molecule.

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