What are two molecular states ?

In summary, there are two molecular states in molecular orbital theory: one with an apostrophe and one without. However, there is no specific notation system that uses the prime symbol for atomic or molecular orbitals. It is possible that in some contexts, the prime symbol is used to denote a specific atom's 1s orbital. Writing \sigma_g1s does not make sense on its own as it combines an MO (\sigma_g) and an atomic orbital (1s). \sigma_g represents the even (gerade) symmetry and is equivalent to the bonding sigma orbital.
  • #1
xylai
60
0
In molecular orbital theory, there are two molecular states. (see below)

I don't know the differences between these two states?
 

Attachments

  • 未命名.JPG
    未命名.JPG
    5 KB · Views: 611
Physics news on Phys.org
  • #2
The difference is one of them has an apostrophe.

Seriously though, to my knowledge there's no system of notation for atomic or molecular orbitals which uses the prime symbol for anything in particular. I'm guessing in the context they're denoting a particular atom's 1s orbital with a prime and another's without.

Writing [tex]\sigma_g1s[/tex] doesn't quite make sense by itself either - sigma is an MO, 1s is an atomic orbital, and you need at least two of those to get an MO.

[tex]\sigma_g[/tex] signifies the even (gerade) symmetry, it's the same as the bonding sigma orbital.
 
  • #3


The two molecular states refer to the bonding and anti-bonding states in molecular orbital theory. These states represent the distribution of electrons in a molecule and are determined by the combination and interaction of atomic orbitals. In the bonding state, the electrons are shared between the atoms, resulting in a stable and lower energy state. In the anti-bonding state, the electrons are pushed away from each other, leading to an unstable and higher energy state. The main difference between these two states is the distribution of electron density and energy levels. Understanding and analyzing these states is crucial for predicting the properties and behavior of molecules in chemical reactions.
 

Related to What are two molecular states ?

1. What are the two molecular states?

The two molecular states refer to the two possible energy levels that a molecule can exist in: the ground state and the excited state. The ground state is the lowest energy level that a molecule can have, while the excited state is a higher energy level that a molecule can transition to under certain conditions.

2. How do molecules transition between the two states?

Molecules can transition between the ground state and excited state through various processes, such as absorbing or emitting energy through electromagnetic radiation, collisions with other molecules, or chemical reactions.

3. What is the significance of the two molecular states?

The two molecular states play an important role in understanding the behavior and properties of molecules. The ground state is the most stable state for a molecule and is where it spends most of its time. The excited state, on the other hand, allows for the absorption and emission of energy, which is essential for many biological and chemical processes.

4. Are all molecules capable of existing in both states?

No, not all molecules are capable of existing in both the ground state and excited state. Some molecules, particularly simpler ones, may only have a ground state and cannot transition to an excited state. However, more complex molecules may have multiple excited states that they can transition between.

5. How are the two molecular states related to chemical reactions?

Chemical reactions involve the breaking and forming of chemical bonds, which often requires molecules to transition between the ground state and excited state. The energy absorbed or released during these transitions can determine the outcome and rate of a chemical reaction.

Similar threads

  • Atomic and Condensed Matter
Replies
0
Views
478
  • Atomic and Condensed Matter
Replies
9
Views
4K
  • Atomic and Condensed Matter
Replies
15
Views
2K
  • Atomic and Condensed Matter
Replies
3
Views
994
  • Atomic and Condensed Matter
Replies
1
Views
936
  • Atomic and Condensed Matter
Replies
1
Views
1K
  • Atomic and Condensed Matter
Replies
1
Views
1K
  • Atomic and Condensed Matter
Replies
4
Views
1K
  • Atomic and Condensed Matter
Replies
1
Views
2K
  • Atomic and Condensed Matter
Replies
1
Views
1K
Back
Top