Terms Allowed in Spectroscopic Structure of Calcium

In summary, the conversation discusses the concept of having a 4s^2 3S1 calcium configuration and why it is not possible. The idea of spins and degeneracy is also brought up. The solution is then provided, stating that two electrons in the same orbital would result in an opposite spin, leading to a S = 0 value. The conversation concludes with the mention of PEP (Pauli Exclusion Principle) as the reason behind this concept.
  • #1
jeffbarrington
24
1

Homework Statement


Why can't we have 4s^2 3S1 calcium? I've looked up a table of terms and this is never given, so I guess we can't have it. Why can't the spins of each of the outer electrons add to give S = 1, J = 1, and a degeneracy of 3? I guess the answer must be pretty basic since nobody has asked about this that I can find, so what's going on?

Homework Equations

The Attempt at a Solution

 
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  • #2
I think this one is simple: Two electrons in the same orbital implies S=0 because the spins must be opposite.
 
  • #3
Charles Link said:
I think this one is simple: Two electrons in the same orbital implies S=0 because the spins must be opposite.
Oh yeah, completely forgot about the PEP! Thanks for taking your time to answer my dumb question!
 
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Likes Charles Link

Related to Terms Allowed in Spectroscopic Structure of Calcium

What is spectroscopic structure?

Spectroscopic structure refers to the arrangement of particles, atoms, or molecules within a physical system, as observed through spectroscopic techniques such as absorption, emission, or scattering of electromagnetic radiation.

What is calcium?

Calcium is a chemical element with the symbol Ca and atomic number 20. It is a soft, silvery-white alkaline earth metal that is essential for living organisms, as it is involved in many biological processes such as bone formation, muscle contraction, and nerve function.

What terms are allowed in the spectroscopic structure of calcium?

The terms allowed in the spectroscopic structure of calcium include electron transitions between different energy levels, spin-orbit coupling, and nuclear spin states. These terms are responsible for the spectral lines observed in calcium's emission or absorption spectra.

How does spectroscopy help in understanding the structure of calcium?

Spectroscopy allows scientists to study the energy levels and transitions within the atoms of calcium, providing information about its electronic and nuclear structure. By analyzing the spectral lines, researchers can determine the number of electrons, their arrangement in energy levels, and the presence of any unpaired electrons, which can help in understanding the chemical and physical properties of calcium.

Why is understanding the spectroscopic structure of calcium important?

Understanding the spectroscopic structure of calcium is crucial for various fields such as chemistry, biology, and materials science. It can help in identifying and characterizing calcium-containing compounds, studying their reactivity and bonding, and even predicting their behavior in different environments. Additionally, knowledge of calcium's spectroscopic structure is essential for the development of new technologies and applications, such as calcium-based medical treatments and high-performance materials.

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