Symmetry of the Bloch Ground State

In summary, on page 3 of Hasan & Kane's review on topological insulators, it is stated that the Bloch ground state is U(N) invariant. This means that any Hartree or Hartree Fock wavefunction is invariant under separate unitary transformations of the occupied and unoccupied orbitals. The Bloch functions are unique as they diagonalize the Hartree Fock effective single particle operators. These functions can be transformed into localized Brillouin functions, also known as Wannier functions. The details of this can be found in any book on solid state theory, such as Roy McWeeny's "Methods of Molecular Quantum Mechanics" from 1989. This concept of invariance is also discussed in depth in
  • #1
Jan Paniev
9
0
I was reading Hasan & Kane's review on topological insulators and right in the beginning, page 3, they say that the Bloch ground state is U(N) invariant. I do not see that. Would anyone be able to show it or point to a reference?

Thanks,
Jan.
 
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  • #2
Any Hartree or Hartree Fock wavefunction is invariant with respect to a separate unitary U(N) and U(M) transformation of the N occupied and M unoccupied orbitals, respectively, among each other. The Blochfunctions are special insofar as they diagonalize the Hartree Fock effective single particle operators which have no fundamental significance, however.
A popular unitary transformation transforms the Bloch functions to the so called localized Brillouin functions (I hope, I remember the name correctly).
 
  • #3
Thanks a lot for the answer. Would you know in which book I would be able to find the details?

Jan.
 
  • #4
Sorry, the name is not Brillouin function but Wannier function.
They should be named in any book on solid state theory.
The invariance of many particle wavefunctions in quantum chemistry is discussed in depth in
Roy McWeeny, Methods of Molecular Quantum Mechanics, 1989.
Basically it is nothing more than the invariance of the determinant under unitary transformations as prooved in elementary linear algebra.
 

Related to Symmetry of the Bloch Ground State

1. What is the Bloch ground state?

The Bloch ground state refers to the lowest energy state of a quantum system that exhibits translational symmetry. This means that the system has the same properties and behavior at every point in space. It is named after physicist Felix Bloch who first described this state in 1928.

2. How is the symmetry of the Bloch ground state determined?

The symmetry of the Bloch ground state is determined by the periodicity of the system. If the system has a repeating structure, such as a crystal lattice, the Bloch ground state will exhibit the same symmetry as the lattice. This can be described mathematically using group theory.

3. What are the implications of the symmetry of the Bloch ground state?

The symmetry of the Bloch ground state has important implications for the properties and behavior of the system. For example, it can affect the electronic and magnetic properties of materials, as well as the transport of particles through the system. Understanding the symmetry of the Bloch ground state is crucial for studying and manipulating quantum systems.

4. Can the symmetry of the Bloch ground state be broken?

Yes, the symmetry of the Bloch ground state can be broken in certain conditions. For example, if the system is subjected to an external force or perturbation, it may no longer exhibit the same symmetry. This can lead to interesting phenomena such as phase transitions and the emergence of new properties in the system.

5. How is the symmetry of the Bloch ground state relevant in modern research?

The symmetry of the Bloch ground state is a fundamental concept in modern research in various fields, including condensed matter physics, materials science, and quantum computing. By understanding and manipulating the symmetry of the Bloch ground state, researchers can develop new materials and technologies with unique and desirable properties.

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