- #1
maistral
- 240
- 17
I am quite unsure where to post this, as I am a chemical engineer and that I am working with phase equilibrium. My issue however is regarding statistical mechanics, thus me posting my problem here.
I keep on encountering that the second virial coefficient of a mixture must be quadratically composition-dependent, and that it is stipulated in statistical mechanics that it must be so.
May I know what, why, or where did this 'stipulation from statistical mechanics' come from?
I keep on encountering that the second virial coefficient of a mixture must be quadratically composition-dependent, and that it is stipulated in statistical mechanics that it must be so.
May I know what, why, or where did this 'stipulation from statistical mechanics' come from?