Solving Flexible Balloon H2S Gas Problem: Q, ΔU, W & V

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In summary, a flexible balloon contains 0.375 mol of hydrogen sulfide gas H2S with a volume of 6750 cm^3 and a temperature of 29.0 C. The H2S expands isobarically until the volume doubles, then expands adiabatically until the temperature returns to its initial value. The total heat supplied to the gas is 3290J, and the total change in internal energy is 0. The total work done is equal to the heat supplied, and the final volume is yet to be determined. This can be found by using the equation P V^{\frac {C_p}{C_v}} = constant for adiabatic expansion.
  • #1
gmarc
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Homework Statement



A flexible balloon contains 0.375 mol of hydrogen sulfide gas H2S. Initially the balloon of H2S has a volume of 6750 cm^3 and a temperature of 29.0 C. The H2S first expands isobarically until the volume doubles. Then it expands adiabatically until the temperature returns to its initial value. Assume that the H2S may be treated as an ideal gas with C_p = 34.60 J/mol*K and gamma = 4/3.

a) What is the total heat Q supplied to the H2S gas in the process?

b) What is the total change in the internal energy Delta U of the H2S gas?

c) What is the total work W done by the H2S gas?

d) What is the final volume V?



The Attempt at a Solution



For part A, I found Q = 3290J, which is the right answer.
For part B, I know that Delta U = nCv*Delta T, but I can't come out with the right answer. I'm sure once I find part B, the others will be much easier.
 
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  • #2
they ask for the total change in the internal energy. For an ideal gas the internal energy only depends on the temperature.
 
  • #3
So if the change in temperature is 302K, that's the change in internal energy?
 
  • #4
gmarc said:
So if the change in temperature is 302K, that's the change in internal energy?
In the second phase the temperature returns to its initial value.
 
  • #5
Ok, so the change in internal energy is equal to zero, and the total work done is just equal Q, the heat supplied. Now I just can't find the final volume in m^3
 
  • #6
you know that [tex] P V^{\frac {C_p}{C_v}} = constant [/tex] for adiabatic expansion?
 

Related to Solving Flexible Balloon H2S Gas Problem: Q, ΔU, W & V

1. What is the flexible balloon H2S gas problem?

The flexible balloon H2S gas problem is a common challenge in chemistry where a flexible balloon is filled with hydrogen sulfide (H2S) gas, and the volume, pressure, and temperature of the gas change due to external factors. The problem requires the use of the ideal gas law to calculate the changes in the gas's properties.

2. What is the ideal gas law and how is it used to solve the flexible balloon H2S gas problem?

The ideal gas law is a mathematical equation that relates the pressure, volume, temperature, and amount of a gas. It is represented as PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature. In the flexible balloon H2S gas problem, the ideal gas law is used to calculate the changes in pressure, volume, and temperature of the gas as it expands or contracts.

3. What is the significance of Q, ΔU, W, and V in solving the flexible balloon H2S gas problem?

Q, ΔU, W, and V are all variables used in the ideal gas law to represent different properties of the gas. Q represents the heat added or removed from the gas, ΔU represents the change in internal energy, W represents the work done by or on the gas, and V represents the volume of the gas. These variables are used to calculate the changes in the gas's properties in the flexible balloon H2S gas problem.

4. What is the difference between Q and ΔU in the flexible balloon H2S gas problem?

Q and ΔU both represent different forms of energy in the ideal gas law. Q represents heat, which is a form of energy transferred due to a temperature difference, while ΔU represents the change in internal energy, which is the sum of all forms of energy within the gas system. In the flexible balloon H2S gas problem, Q and ΔU are used to calculate the heat added or removed and the change in internal energy of the gas, respectively.

5. How do you determine if work is being done in the flexible balloon H2S gas problem?

In the flexible balloon H2S gas problem, work is considered to be done if there is a change in the volume of the gas. If the gas expands, work is done by the gas, and if the gas contracts, work is done on the gas. The work done is calculated using the equation W = -PΔV, where W is the work, P is the pressure, and ΔV is the change in volume. If the value of W is positive, work is being done by the gas, and if it is negative, work is being done on the gas.

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