Redox Reactions: Loss and Gain of Electrons

In summary, a redox reaction is defined as a reaction involving both reduction and oxidation, which are the gain and loss of electrons. However, not all reactions involve the movement of electrons, as some involve the sharing of electrons or changes in oxidation numbers. While Wikipedia may classify some reactions as redox based on changes in oxidation numbers, this is not always an accurate representation as these numbers are simply an accounting device and not a true measurement. Thus, not all reactions can be classified as redox reactions.
  • #1
joeyjo100
23
1
Not particually a paradox, just liked the word play. Anyway...

The definition of a redox reaction is a reaction with both reduction and oxidation. As we know, oxidation is loss, reduction is gain of electrons. So redox is a reaction with both loss and gain of reaction.

Does it follow that every single reaction in the universe is a redox reaction, since a reaction is the transfer of electrons?

Are there any reactions that don't involve the movement of electrons?
 
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  • #2
Every reaction means electrons are moving, no doubt about it. However, it is not always clear to which atom they belong in a molecule (it is safer to think about them being shared), so it is not always easy to say "this atom lost an electron", "this atom gained an electron".
 
  • #3
Does it follow that every single reaction in the universe is a redox reaction, since a reaction is the transfer of electrons?

but there are many reactions that are classed as "redox" even though no electron transfer occurs (such as those involving covalent bonds) -Wikipedia

http://en.wikipedia.org/wiki/Redox"
 
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  • #4
This is one of these cases when wiki fails to explain things properly.

Wiki combines redox processes with change in oxidation number. That's where the problem starts. Oxidation numbers are not combined with any existing property of the matter, you can't measure oxidation number. You can only calculate it, using set of rules. And the problem here is that these rules were designed for a "charge accounting". They do give correct results when you trace the charges, but the underlying principle is charge conservation, not oxidation numbers which are just an accounting device.

When all you have is a hammer everything looks like a nail. When you use oxidation numbers every reaction looks like a redox.
 
  • #5


While it is true that redox reactions involve both the loss and gain of electrons, not all reactions in the universe can be classified as redox reactions. There are certain reactions, such as acid-base reactions, that do not involve the transfer of electrons. In these reactions, protons (H+) are transferred instead. Additionally, some reactions may involve the transfer of other particles, such as ions or molecules, rather than electrons.

Furthermore, even within redox reactions, not all species involved necessarily undergo a change in oxidation state (the number of electrons gained or lost). Some species may act as catalysts or intermediates, facilitating the transfer of electrons between other species without undergoing a change in their own oxidation state.

In conclusion, while redox reactions are an important type of reaction in chemistry, not all reactions in the universe can be classified as redox reactions. It is important to consider the specific nature of the reaction and the species involved in order to accurately classify it as a redox reaction or not.
 

Related to Redox Reactions: Loss and Gain of Electrons

1. What is a redox reaction?

A redox reaction, also known as an oxidation-reduction reaction, is a chemical reaction in which electrons are transferred between reactants. One reactant loses electrons (oxidation) while the other gains electrons (reduction).

2. What is meant by "loss" and "gain" of electrons in a redox reaction?

In a redox reaction, one reactant loses electrons and is therefore oxidized, while the other reactant gains electrons and is reduced. This transfer of electrons is what allows the reaction to occur and results in a change in the oxidation states of the reactants.

3. How do you determine which reactant is oxidized and which is reduced in a redox reaction?

The reactant that loses electrons is oxidized, and the reactant that gains electrons is reduced. This can also be determined by looking at the change in oxidation states of each reactant. The reactant with a decrease in oxidation state is oxidized, and the reactant with an increase in oxidation state is reduced.

4. What is the role of electrons in a redox reaction?

Electrons play a crucial role in redox reactions as they are transferred between reactants, allowing for the reaction to occur. The transfer of electrons results in a change in the oxidation states of the reactants and is what drives the reaction forward.

5. Can you give an example of a redox reaction in everyday life?

A common example of a redox reaction is the rusting of iron. In this reaction, iron (Fe) loses electrons (oxidation) to oxygen (O2), forming iron oxide (Fe2O3), while oxygen gains electrons (reduction). This process is an example of a natural redox reaction that occurs due to the transfer of electrons.

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