Radial part of wave function in respect to spherical harmonic

In summary, the conversation discusses finding the expectation values of L^{2}, L_{z}^{2}, and L_{x}^{2} for a given wavefunction. It is suggested to rewrite the wavefunction in terms of spherical coordinates and consider the radial part when normalizing the wavefunction.
  • #1
Zaknife
12
0

Homework Statement


Consider a Wavefunction:
[tex]\psi(x,y,z)=K(x+y+x^2-y^2)e^{-r/a}[/tex]
Find expectation value of [tex] L^{2} , L_{z}^{2}, L_{x}^{2}[/tex].

Homework Equations


The Attempt at a Solution


The first step would be a rewriting a wavefunction in terms of spherical coordinates:
[tex]\psi=Kr(\cos\phi \sin \theta + 2 \sin \phi \cos \theta +r(\cos^{2} \phi \sin^{2} \theta - \sin^{2} \phi \sin^{2} \theta )) [/tex]

My Question is : is it fair to skip the radial part and just forget about it. Normalize the Wavefunction for just the angular part , and then consider a mean values of Angular Momentum Operators ? Or should i normalize the wavefunction including r ? It bothers me because of the r squared in the equation.
 
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  • #2
You can't neglect the radial functions.
 
  • #3
Just to make it clear - i need to do all next steps with the radial part ?
 
  • #4
It depends what your next steps are. You eventually need to normalize the wave function, so you need to take into account the radial function somewhere along the way.

By the way, you seem to have dropped the exponential factor when you rewrote the function in terms of spherical coordinates.
 
  • #5


It is not fair to skip the radial part and just consider the angular part for calculating the mean values of Angular Momentum Operators. The radial part of the wavefunction is an essential component and cannot be ignored. It is important to normalize the entire wavefunction, including the radial part, before calculating the mean values of the Angular Momentum Operators. This is because the radial part affects the overall shape and magnitude of the wavefunction, which in turn affects the expectation values of the Angular Momentum Operators. Furthermore, the radial part also contributes to the probability density of the wavefunction, which is crucial in calculating the expectation values. Therefore, it is important to include the radial part in the normalization and calculation process.
 

Related to Radial part of wave function in respect to spherical harmonic

What is the radial part of the wave function?

The radial part of the wave function is one of the three components that make up a spherical harmonic wave function. It represents the variation of the wave function with respect to the distance from the origin.

How is the radial part of the wave function related to the spherical harmonic?

The radial part of the wave function is multiplied by the angular part (spherical harmonic) to form a complete wave function. This is because the spherical harmonic only describes the angular variation of the wave function, while the radial part describes the variation in distance from the origin.

What is the significance of the radial part of the wave function?

The radial part of the wave function plays a crucial role in determining the energy and spatial distribution of an electron in a spherical potential. It also helps in understanding the behavior of atoms and molecules.

How is the radial part of the wave function calculated?

The radial part of the wave function is calculated using the radial Schrödinger equation, which takes into account the potential energy of the system. The solution to this equation is a set of radial wave functions, each corresponding to a different energy level.

What are the properties of the radial part of the wave function?

The radial part of the wave function is a continuous and smooth function that goes to zero as the distance from the origin increases. It is also normalized, which means that the total probability of finding an electron at any distance is equal to one.

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