Quantum harmonics oscillator at high temperature

In summary: It just means that as T gets larger and larger, U approaches kT. Again, we have to talk about limits because infinity is not a real number.
  • #1
alejandrito29
150
0
Hello

The energy of harmonics oscillator, started of [tex]U=-\frac{\partial}{\partial \beta} \ln Z[/tex] is equal to [tex]\frac{\hbar \omega}{2} + \frac{\hbar \omega}{exp(\beta \hbar \omega)-1}[/tex].

At high temperature, i could say that [tex]exp (\beta \hbar \omega ) \approx 1 + (\beta \hbar \omega )[/tex], and then [tex]U=\frac{\hbar \omega}{2} + kT[/tex], therefore at high temperature [tex]\frac{\hbar \omega}{2}[/tex] is negligible compared to [tex]kT[/tex], and then [tex]U \approx k T [/tex].

I need find arguments about why is incorrect say that [tex]\frac{\hbar \omega}{2} + \frac{\hbar \omega}{exp(\beta \hbar \omega)-1}[/tex] at [tex]\beta \to 0[/tex] (high temperature) is equal to [tex]\infty[/tex]. This motivated by the fact that [tex]k T = k \cdot \infty = \infty[/tex]. I understand that at high temperature the energy has a asyntote equal to kT (http://www.av8n.com/physics/oscillator.htm#sec-e-vs-t ), but still need argumens.

Also ¿why the harmonics oscillators need a specific heat at high temperature?. In this case the specific heat is equal to k. But if the energy us infinity, then the specific heat would be zero.
 
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  • #2
alejandrito29 said:
I need find arguments about why is incorrect say that [tex]\frac{\hbar \omega}{2} + \frac{\hbar \omega}{exp(\beta \hbar \omega)-1}[/tex] at [tex]\beta \to 0[/tex] (high temperature) is equal to [tex]\infty[/tex].

The precise statement would be that ##\frac{\hbar \omega}{2} + \frac{\hbar \omega}{exp(\beta \hbar \omega)-1} \to \infty## as ##\beta \to 0##. We always have to speak of limits when discussing infinity. Nothing ever equals infinity.

alejandrito29 said:
Also ¿why the harmonics oscillators need a specific heat at high temperature?. In this case the specific heat is equal to k. But if the energy us infinity, then the specific heat would be zero.

The energy is never infinity. For any finite temperature, no matter how large, the energy is finite. So you can always evaluate the specific heat ##d U / d T## and it is always nonzero, for any ##T > 0##.
 
  • #3
The_Duck said:
The energy is never infinity. For any finite temperature, no matter how large, the energy is finite. So you can always evaluate the specific heat ##d U / d T## and it is always nonzero, for any ##T > 0##.

¿why The energy is never infinity?

The_Duck said:
For any finite temperature, no matter how large, the energy is finite.

but the literature says that at [tex] T \to \infty[/tex] , then [tex]U \to k T[/tex]

sorry, but still i don´t understand
 
  • #4
alejandrito29 said:
¿why The energy is never infinity?

Because nothign is ever infinite. This is why we have to talk about limits. This is as true here as in in every other case in math and physics.

but the literature says that at [tex] T \to \infty[/tex] , then [tex]U \to k T[/tex]

Which is correct, but does not mean that T ever EQUALS infinity.
 

Related to Quantum harmonics oscillator at high temperature

1. What is a quantum harmonic oscillator?

A quantum harmonic oscillator is a physical system that follows the laws of quantum mechanics and exhibits a periodic motion, similar to a classical harmonic oscillator. It is often used as a model to study the behavior of atoms, molecules, and other particles.

2. How does a quantum harmonic oscillator behave at high temperatures?

At high temperatures, the energy levels of a quantum harmonic oscillator become highly populated, leading to a decrease in the oscillation amplitude and an increase in the average energy of the system. This behavior is known as thermal broadening.

3. What is the relationship between temperature and the average energy of a quantum harmonic oscillator?

The average energy of a quantum harmonic oscillator at high temperature is directly proportional to the temperature. This means that as the temperature increases, so does the average energy of the oscillator.

4. How does the behavior of a quantum harmonic oscillator at high temperature differ from that at low temperature?

At low temperatures, the energy levels of a quantum harmonic oscillator are not highly populated, and the oscillator behaves more like a classical system. However, at high temperatures, the quantum nature becomes more apparent, and thermal effects such as thermal broadening become significant.

5. What are the practical applications of studying quantum harmonic oscillators at high temperature?

The study of quantum harmonic oscillators at high temperatures has applications in various fields, including quantum computing, materials science, and statistical mechanics. It can also help improve our understanding of fundamental quantum mechanics principles and their applications in real-world systems.

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