Prove the wave function for dxy orbital

In summary, the dxy orbital can be represented in Cartesian coordinates as xy, which can be converted to spherical coordinates as (r/2)sin^2(θ)sin(2ϕ). However, when attempting to normalize this equation, the integral does not converge, suggesting that there may be a missing term or incorrect manipulation of the equation. Further exploration of trigonometric identities may be necessary to solve this problem.
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chem1309
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Homework Statement



"The angular part of the wave function for the dxy orbital is (√(15/∏)/4)sin^2(θ)sin(2ϕ). Show that this expression corresponds to the dxy orbital"


Homework Equations



conversion of Cartesian to spherical coordinates:
r=√(x^2+y^2+z^2)
cosθ=z/r
tan(ϕ)=y/x

trig identity:
sin(2x)=2sinxcosx

normalization:
N^2∫ψ*ψdτ=1

dτ=r^2sinθdrdθdϕ

0≤r≤∞
0≤θ≤∏
0≤ϕ≤2∏


The Attempt at a Solution



in Cartesian coordinates dxy is represented as simply xy. I converted xy to spherical coordinates and manipulated the equation the relevant equations to get xy=(r/2)sin^2(θ)sin(2ϕ) as follows:

xy=rsincosϕrsinθsinϕ
xy=rsin^2(θ)cosϕsinϕ
xy=rsin^2(θ)sin(2ϕ)/2

Then I tried to normalize the equation, but I ended up with

∫r^3 from 0 to ∞, which goes to ∞/does not converge

and ∫sin2ϕ which equal zero.
 
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  • #2
Do I need to use another identity to make the integral converge, or am I missing something entirely?
 

Related to Prove the wave function for dxy orbital

1. What is the wave function for the dxy orbital?

The wave function for the dxy orbital is represented by the equation Ψ = Axye^(-ρ/2)cos(θ)sin(φ), where Ψ is the wave function, A is a normalization constant, ρ is the distance from the nucleus, θ is the angle between the z-axis and the position vector, and φ is the angle between the x-axis and the position vector.

2. How is the wave function for the dxy orbital derived?

The wave function for the dxy orbital is derived from the Schrödinger equation, which describes the behavior of quantum particles. By solving the equation for the dxy orbital, we can find the corresponding wave function that describes the probability of finding an electron in a particular location in space.

3. What is the significance of the dxy orbital in chemistry?

The dxy orbital is one of the five d orbitals that make up the second energy level in an atom. These orbitals play a crucial role in the bonding and structure of molecules, particularly in transition metal compounds. The dxy orbital specifically has a lobed shape and is involved in bonding with other atoms through its unpaired electrons.

4. How is the wave function for the dxy orbital visualized?

The wave function for the dxy orbital can be visualized using mathematical models and quantum mechanical simulations. It is often represented as a three-dimensional graph, with the x, y, and z axes representing the different variables in the wave function equation. These visualizations help us understand the behavior of electrons in this orbital and their probability distribution in space.

5. Can the wave function for the dxy orbital be experimentally proven?

The wave function for the dxy orbital, like all other wave functions, cannot be directly measured or observed. However, it can be indirectly verified through experiments and calculations. Scientists use spectroscopy and other techniques to observe the electron behavior and properties of atoms and molecules, which provide evidence for the validity of the dxy orbital wave function.

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