Pressure affecting the latent heat of vapourization

In summary: This is due to the fact that when pressure is applied, more work must be done against the surroundings, and therefore more energy is required.
  • #1
sgstudent
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Homework Statement


The definition of latent best of vapourization is the amount of thermal energy required to change the state of a liquid to a gas or vice versa. Also, when we increase the pressure of the gas on the liquid there has to be more work done against the surroundings so the latent heat increases. However when they are in the gaseous state will it require less energy for it to reform into a liquid as the pressure around it is greater?


Homework Equations



Q=ml

The Attempt at a Solution


On one hand it makes sense but the definition states that the energy will be the same due to the vice versa. Or is it the same as the gas has more energy than the same gas with a lower pressure surrounding it so when it gives out the energy, there is an excess of it causing more energy to be given out? But still won't the surrounding pressure cause a difference? I'm confused about the two concepts here and it would be great if you guys could sort it out for me.

Thanks for the help! :smile:
 
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  • #2
The latent heat of vaporization is defined as a constant amount of energy required to change the state of a liquid to a gas or vice versa. The pressure around the liquid or gas does not affect the amount of energy required to change the state. However, when pressure is applied to the liquid or gas, it will affect the temperature at which the state change occurs. For example, an increase in pressure will decrease the boiling point, so it will take less energy to cause the state change.
 

Related to Pressure affecting the latent heat of vapourization

1. How does pressure affect the latent heat of vapourization?

As pressure increases, the latent heat of vapourization decreases. This means that it takes less energy to turn a liquid into a gas at higher pressures.

2. Why does pressure affect the latent heat of vapourization?

The relationship between pressure and the latent heat of vapourization is due to the change in the intermolecular forces between molecules. As pressure increases, the molecules are pushed closer together, making it easier for them to break free from the liquid state and enter the gas phase.

3. How does altitude affect the pressure and latent heat of vapourization?

At higher altitudes, the atmospheric pressure decreases, and so does the latent heat of vapourization. This is why water boils at a lower temperature at high altitudes.

4. Is there a limit to how much pressure can affect the latent heat of vapourization?

Yes, there is a limit to how much pressure can affect the latent heat of vapourization. At extremely high pressures, the molecules are compressed so tightly that they no longer have enough space to break free and transition into the gas phase.

5. How does the type of substance affect the relationship between pressure and the latent heat of vapourization?

The type of substance does not affect the relationship between pressure and the latent heat of vapourization. This relationship is based on the intermolecular forces between molecules, which are generally consistent across substances.

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