Partition function for electrons/holes

In summary, when a semiconductor is exposed to a laser beam, it can create a collection of electrons and holes. These particles can either form a gas of excitons or dissociate into an electron hole plasma. The single particle partition functions, Ze(1) and Zh(1), for the electrons and holes respectively, can be written as (V/λ^3) where V is the volume and λ is the thermal wavelength. This formula can be derived by approximating the summation over all energy states as an integral.
  • #1
Welshy
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Homework Statement


By shining and intense laser beam on to a semiconductor, one can create a collection of electrons (charge -e, and effective mass me) and holes (charge +e, and effective mass mh) in the bulk. The oppositely charged particle may pair up (as in a hydrogen atom) to form a gas of excitons, or they may dissociate into an electron hole plasma.

a) Write down the single particle partition functions Ze(1) and Zh(1) at temperature T in a volume V for electrons and holes respectively. (The thermal wavelength [tex]\lambda[/tex] for a particle is [tex]\lambda[/tex] = [tex]\frac{h}{\sqrt{2 \pi mkT}}[/tex]

Homework Equations

The Attempt at a Solution


I know that the partition function is exp[-E/kT] summed over all energies or integrated with a density of states over all energies. But how do I go about it in this case?
 
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  • #2
In our notes somewhere (section 11/12/13), you can see that he uses the equation:

Z(1) = (V/λ^3), where V is the volume.

I'm not sure where it comes from, but I think we just need to learn it.
 
  • #3
You can obtain that formula by summing over all the energy states by approximating the summation by an integral using the fact that the number of quantum states within a volume V_p of momentum space is

V V_p/h^3

So, if you integrate over all momenta, the energy is E = p^2/(2m) and you can write:

Z1 = Integral of V d^3p/h^3 exp[-beta p^2/(2m)] =

V/h^3 Integral from |p| = 0 to infinity of 4 pi p^2
exp[-beta p^2/(2m)] d|p|

For electrons you must multiply this by 2 because there are two spin states for each energy eigenstate.
 

Related to Partition function for electrons/holes

1. What is the partition function for electrons/holes?

The partition function for electrons/holes is a mathematical concept used in statistical mechanics to describe the distribution of electrons or holes in a system at a given temperature. It takes into account the energy levels and degeneracy of the particles in the system.

2. How is the partition function for electrons/holes calculated?

The partition function for electrons/holes is calculated by summing over all possible energy states and their respective degeneracies, weighted by the Boltzmann factor (e^(-E/kT)), where E is the energy of the state, k is the Boltzmann constant, and T is the temperature in Kelvin.

3. What is the significance of the partition function for electrons/holes?

The partition function for electrons/holes is significant because it allows us to calculate the probability of finding electrons or holes in a given energy state at a particular temperature. This information is crucial in understanding the behavior of particles in a system and predicting their macroscopic properties.

4. How does the partition function for electrons/holes relate to entropy?

The partition function for electrons/holes is directly related to the entropy of a system. The higher the partition function, the greater the entropy of the system, which means that there are more possible energy states for the particles to occupy.

5. How does the partition function for electrons/holes change with temperature?

The partition function for electrons/holes increases with temperature. This is because as the temperature increases, more energy states become accessible to the particles, leading to a higher probability of finding them in a particular energy state. This relationship is described by the Boltzmann distribution.

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