Does the Kinetic Energy from Electrolysis Gas Exceed the Energy Required for the Process?

In summary, the conversation discusses the kinetics of electrolysis and the potential for using the kinetic energy from the liberated gas to exceed the energy required for the electrolysis process. The potential for work is compared to a large boulder on a mountain side and it is concluded that the answer is no. The conversation then delves into the laws and formulas involved, including the Kinetics Formula, Chemistry of Electrolysis, Boyle's Law, and Thermodynamics. It is determined that the increase in buoyancy resulting from the change in depth would not be enough to significantly increase the potential for work. The conversation ends with a question about the expected "pull" in pounds of a gas bubble ascending from a depth of 1,000 ft to ten feet
  • #1
brm123
[SOLVED] Kinetics of Electrolysis

Can you help me with this problem?

Assumptions:
1- Electrolysis of seawater at 1,000 ft.
2- Gases are generated having buoyancy, probably chlorine, hydrogen, oxygen
3- Gases are captured as they rise and mechanically converted to electrical energy to power electrolysis

Question:

Does the potential for work provided by the kinetic energy from the liberated gas exceed the energy required to sustain the electrolysis at 1,000... or greater ?

Example: Assume you have a large boulder on a mountain side ready to fall with a small push. The "potential" release of energy is greater than the energy required to start the boulder rolling. I am thinking of the bubble as the boulder and the depth of the ocean as the mountain with electrolysis giving the "push"

As the bubble is "pushed up the mountain" it's velocity will increase, mass will remain basically unchanged or slightly diminished. The amount of energy required to produce the initial "push" is fixed. But the height of the mountain and the "potential" for work can be changed by making the mountain taller or the reaction deeper without the need to increase the push.
 
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  • #2
The answer is no.

- Warren
 
  • #3
Then the next question, of course, is WHY?
 
  • #4
It is not a hard calculation.

- Warren
 
  • #5
It is if you are not a Mathematician/Physicist. I think it involves: Kinetics Formula, Chemistry of Electrolysis and Boyle's Law as well as Thermodynamics. I am neither Mathmetician or Physicist. Just curious.

Can you tell me which law it would violate? Not conservation of energy since that would not include the kinetic potential of the rising gas.
 
  • #6
The _absolute_ largest energy you'd be able to pull would be

∫ (net bouyancy) ds

which is not that much.

Plus, you'd never even come close to pulling 100% out of it.
 
  • #7
I thought it would be more like:

w = 1/2 * m * v2 - 1/2 * m * v02
 
  • #8
What about the increase in bouyancy that results from the change in depth? Would not the change be an increase in boyancy of about 14.7 pounds per square inch for avery 33 feet the bubble ascends? Can't this increase in "displacement" be translated into "work" see previous formula. [?]
 
  • #9
Can anyone answer this?

Say you create, by electrolysis, a gas bubble having 1 pound of "pull" at a depth of 1,000 ft. The "pull" is measured by a spring scale (assume it is unaffected by any force other than the bubble for the time being). What would you expect the "pull" in pounds to be if the bubble ascends to a depth of ten feet?
 

1. What is the definition of electrolysis?

Electrolysis is a chemical reaction that involves the use of electricity to break down a compound into its elements or simpler compounds.

2. How does the rate of electrolysis change with varying current and time?

The rate of electrolysis is directly proportional to the current and time. This means that as the current and time increase, the rate of electrolysis will also increase. However, the rate may eventually reach a maximum as the solution becomes saturated.

3. How does temperature affect the rate of electrolysis?

Increasing the temperature of the solution can increase the rate of electrolysis. This is because higher temperatures provide more energy for the particles to move and react, leading to a faster reaction rate.

4. What factors can affect the efficiency of electrolysis?

The efficiency of electrolysis can be affected by factors such as the concentration of the solution, the type of electrodes used, the current and voltage applied, and the temperature of the solution.

5. What are some practical applications of electrolysis?

Electrolysis has many practical applications, including the production of metals such as aluminum and copper, purification of metals, and production of chlorine and hydrogen gas for industrial use. It is also used in electroplating, electrolytic cells for batteries, and wastewater treatment.

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