Linear equations and superposition of wavefunctions

In summary, the Schrodinger equation is a linear equation, meaning that the sum of two solutions is also a solution. This is the same definition of linearity used for differential equations. As the Schrodinger equation is also an eigenvalue equation for the Hamiltonian, the condition for a superposition of wavefunctions to also solve the eigenvalue equation is that it is both linear and the wavefunctions have the same eigenvalues. This is similar to the concept of superposition in linear ordinary differential equations. However, for eigenvalue problems, the superposition only holds if the eigenvalues are the same. In the case of the Schrodinger equation, operators act on function spaces instead of vectors, but the concept of linearity and super
  • #1
dyn
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61
Hi. I have read many times that the Schrodinger equation is a linear equation and so if Ψ1 and Ψ2 are both solutions to the equation then so is Ψ1 + Ψ2. Is this use of the word linear the same as generally used for differential equations ? As the Schrodinger equation is also an eigenvalue equation for the Hamiltonian.

My main confusion is why a superposition of wavefunctions such as eikx + e-ikx is not a solution to the momentum eigenvalue equation as this also looks like a linear equation ?
Thanks
 
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  • #2
dyn said:
Is this use of the word linear the same as generally used for differential equations ?
Yes.
dyn said:
My main confusion is why a superposition of wavefunctions such as eikx + e-ikx is not a solution to the momentum eigenvalue equation as this also looks like a linear equation ?
Because the summands correspond to different eigenvalues.
 
  • #3
Thanks. So the condition that the superposition of wavefunctions also solves the eigenvalue equation is that it is both linear and the wavefunctions also have the same eigenvalues ?
 
  • #4
dyn said:
Thanks. So the condition that the superposition of wavefunctions also solves the eigenvalue equation is that it is both linear and the wavefunctions also have the same eigenvalues ?
Yes. (Eigenvalue equations are usually linear, by the way. There does exist something called a "nonlinear eigenvalue problem", but that is not relevant here.)

The SE is a partial differential equation, but for your understanding perhaps consider the setting of a linear ordinary differential equation. In the simplest case (constant coefficients, homogeneous) a linear ODE can be written as
$$
\frac{dx}{dt}(t) = Ax(t) \qquad (\ast)
$$
(Think, for example, about the simple harmonic oscillator.) If ##x_1## and ##x_2## are both solutions, then their sum is also a solution and hence satisfies ##(\ast)##. This is superposition.

Regarding the corresponding eigenvalue problem, if ##\lambda## and ##\mu## are distinct eigenvalues of ##A## with eigenvectors ##u## and ##v##, then ##u + v## is not an eigenvector of ##A##. (Try it out.) In contrast, if ##\lambda = \mu## then it is true that
$$
A(u + v) = \lambda(u + v)
$$
In case of the SE similar remarks hold, but the matrices are replaced by (unbounded) operators that act on function spaces instead of ##\mathbb{R}^n## or ##\mathbb{C}^n##. Does this clarify matters a bit?
 
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  • #5
Yes. Thanks for your help.
 

Related to Linear equations and superposition of wavefunctions

1. What is a linear equation?

A linear equation is an algebraic equation in which the variables are raised to the first power and the equation can be graphed as a straight line. It can be written in the form of y = mx + b, where m represents the slope and b represents the y-intercept.

2. What is superposition of wavefunctions?

Superposition of wavefunctions is a principle in quantum mechanics where the total wavefunction of a system is a combination of the individual wavefunctions of its components. This allows us to describe the behavior of a system in terms of the behavior of its individual parts.

3. How do you solve a system of linear equations?

A system of linear equations can be solved by using elimination, substitution, or graphing methods. Elimination involves adding or subtracting equations to eliminate a variable, substitution involves replacing a variable with an equivalent expression, and graphing involves plotting the equations on a graph and finding the point of intersection.

4. What is the significance of slope in a linear equation?

The slope of a linear equation represents the rate of change between two variables. It can tell us how much the dependent variable changes for every one unit change in the independent variable. It also determines the steepness of the line on a graph.

5. How are linear equations and wavefunctions related?

Linear equations and wavefunctions are related in that they both involve the concept of superposition. In linear equations, we can combine multiple equations to find a solution, while in wavefunctions, we can combine multiple individual wavefunctions to describe the behavior of a system. Both use the principle of superposition to solve complex problems and understand the behavior of a system.

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