Ionizing a covalently-bonded molecule?

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  • Thread starter bigplanet401
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In summary, when a high energy electron or photon collides with a water molecule, it can cause ionization which leads to the formation of ions such as H^+ and OH^- as well as free radicals. This can result in the breaking of bonds within the molecule, leading to the formation of new compounds. The process is complex and can have various outcomes, but it is possible for a hydroxide cation to be formed as well as other products. The effects of cosmic rays on covalently-bonded molecules, like water, can also lead to the formation of radicals and other compounds. Further research is needed to fully understand the mechanisms involved.
  • #1
bigplanet401
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Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?

Homework Equations


The Attempt at a Solution



My knowledge of chemistry is very limited, and my guess is that it would be ionized:

[tex]
e + H_2 O \rightarrow H^+ + OH + 2e
[/tex]

Here, a high energy electron hits the molecule and releases 1 electron from the H atom, making it a cation. Two electrons appear in the products: 1 from the H along with the original electron.

If something like this were possible, then could a "hydroxide cation" be formed?

[tex]
e + H_2 O \rightarrow H + OH^+ + 2e
[/tex]

And if a photon strikes the molecule, how about

[tex]
\gamma + H_2 O \rightarrow H_2 + O
[/tex]

(Can water absorb photons?)

I am trying to understand how a covalently-bonded molecule "breaks up" when bombarded with cosmic rays, and would like to know if any of these examples (which contain such a molecule) are plausible. Thanks for your help!
 
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  • #2
You are reducing water, so the reaction is simply [tex]H_2O+e^- \rightarrow \frac{1}{2}H_2+OH^-[/tex]
You just can't go and cleave bonds that easily. And for the cosmic rays, I think that everybody can form radical, as many species does in UV light. (Cosmic rays are too powerful I suppose)
 
  • #3
bigplanet401 said:

Homework Statement


What happens to a water molecule if it is hit by a high energy electron or photon?

Also known as ionizing radiation. There is a lot of information on the web regarding ionizing radiation and it's effects on the water molecule.
 

Related to Ionizing a covalently-bonded molecule?

1. What is ionization of a covalently-bonded molecule?

Ionization of a covalently-bonded molecule is the process of removing one or more electrons from the molecule, resulting in the formation of ions. This can be achieved by exposing the molecule to high-energy radiation or by chemical reactions.

2. How does ionization affect the stability of a covalently-bonded molecule?

Ionization can significantly impact the stability of a covalently-bonded molecule. The removal of electrons can disrupt the balance of charges within the molecule, leading to changes in its chemical properties and reactivity. Additionally, the formation of ions can result in the formation of new chemical bonds, altering the overall structure and stability of the molecule.

3. What factors influence the ease of ionization for a covalently-bonded molecule?

The ease of ionization for a covalently-bonded molecule is influenced by several factors, including the strength of the covalent bond, the energy of the ionizing radiation, and the presence of any electron-donating or withdrawing groups in the molecule. Generally, molecules with weaker covalent bonds and electron-donating groups are more easily ionized.

4. Can ionization of a covalently-bonded molecule result in the formation of free radicals?

Yes, ionization of a covalently-bonded molecule can lead to the formation of free radicals. Free radicals are highly reactive species that have an unpaired electron, which is formed when a molecule loses an electron during ionization. These free radicals can then participate in various chemical reactions, potentially leading to the formation of new compounds.

5. What applications does ionization of covalently-bonded molecules have in scientific research?

Ionization of covalently-bonded molecules has numerous applications in scientific research, particularly in the field of mass spectrometry. By ionizing molecules and separating the resulting ions based on their mass-to-charge ratio, scientists can identify and analyze the chemical composition of complex mixtures. This technique is widely used in areas such as proteomics, metabolomics, and drug discovery.

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