How to Write Chemical Formulas Systematically?

In summary, there are systematic ways to write chemical formulas and balance chemical equations. The general rule is to write the cation first and then the anion, but there are exceptions. Balancing equations can be done through trial and error or using systematic methods such as half reactions. LaTeX can also be helpful in writing chemical equations.
  • #1
courtrigrad
1,236
2
Hello

Is there any systematic way to write chemical formulas? Any help would be greatly appreciated
 
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  • #2
Hello, first cation and then anion is written; this is a very general rule.
 
  • #3
Maltun is right. First read the positive ion (cation), and then the second. But you will need some information about how special cations and anions are read, for example, [itex]NO_{3}^{-}[/itex] is read as nitrate.

Let me give some examples on this:
[tex]Sodium~chloride=NaCl[/tex]
[tex]Silver~nitrate=AgNO_3[/tex]
[tex]Calcium~phosphate=Ca_3(PO_4)_2[/tex]
In the last example, remember that calcium ion has 2+ charge while phosphate is a 3- charged ion; so the smallest common number of these is 6.
There are some exceptions where we don't obey the rule "cation first, anion second", as in acetate compounds. Potassium acetate is written as [itex]CH_3COOK[/itex] but we may rewrite this as [itex]KOOCCH_3[/itex], which is not a familiar style.

I may go on if you need some more examples.
 
  • #4
I am sorry. I meant is there any systematic way to balance chemical equations. Right now we are learning how to do that.

Any help would be appreciated!

Thanks
 
  • #5
Mostly it's a kind of trial and error approach. Depending on the equation, there may be a best way to gp about balancing it. If there is a certain radical that is present in only one species on either side of the equation, it's a good idea to start with that radical and balance it first. From there, the rest will fall into place relatively easily.

If you show us with some examples, how you would balance certain specific equations, we might be able to tell you if you're doing it okay, or if there's a better way.
 
  • #6
Fe(OH)3 (s) + H2SO4(aq) ----------> MgSO4(aq) + (NH4)2S
 
  • #7
Are you sure your reaction is correct? Or you've found some nuclear technique :smile:

Iron(III)hydroxide is a base, and reacts with sulfuric acid to give its sulfate with water:

[tex]2Fe(OH)_3+3H_2SO_4\longrightarrow Fe_2(SO_4)_3+6H_2O[/tex]
 
  • #8
Gokul43201 said:
Mostly it's a kind of trial and error approach...

True...and it's usually pretty easy. However, if it's a re-dox reaction, trial and error can be really time consuming. For those, you use "half reactions." That technique is quite systematic. Here's a simple example:

To balance KClO4 + Al -> KCl + Al2O3, start by writing equations for the transfer of electrons that occurs with the elements that change in oxidation state:

Cl(+7) + 8e -> Cl(-1)
Al - 3e -> Al(+3)

Now, find coefficients to multiply each equation by, so the total number of electrons going one way is equal to the total number going the other:

3Cl(+7) + 24e -> 3Cl(-1)
8Al -24e -> 8Al(+3)

Put those numbers in the original equation:

3KClO4 + 8Al -> 3KCl + 4Al2O3

It gets a little messier when the reaction occurs in acidic or basic solution, but the general method is still the same.
 
  • #9
A good explanation, congrats. It can be better if you learn and use LaTeX, but it is still okay now.
 

Related to How to Write Chemical Formulas Systematically?

What is a chemical formula?

A chemical formula is a way to represent the types and numbers of atoms present in a molecule of a compound. It uses symbols and subscripts to indicate the elements and their ratios in a compound.

How do you write a chemical formula?

A chemical formula is written by first identifying the elements present in a compound. The elements are then written in a specific order, with the most metallic element first. Next, subscripts are added to indicate the number of each type of atom present. The subscripts are written after the element symbol and are written in a smaller font size.

What is the difference between empirical and molecular formulas?

An empirical formula is the simplest whole number ratio of elements present in a compound. A molecular formula, on the other hand, is the actual number of atoms of each element present in a molecule of the compound. Empirical formulas are often used for simple compounds, while molecular formulas are more specific and used for more complex compounds.

Why are chemical formulas important?

Chemical formulas are important because they provide a standardized way to represent and communicate the composition of a compound. They allow scientists to easily identify and differentiate between different compounds and also help in predicting the chemical and physical properties of a substance.

What are some common mistakes to avoid when writing chemical formulas?

Some common mistakes to avoid when writing chemical formulas include not reducing subscripts to their simplest form, forgetting to include a subscript for elements that are present in a compound, and incorrectly ordering the elements in a compound. It is also important to use the correct symbols for elements and to accurately count the number of atoms present in a molecule.

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