How to use extra term in radial equation

In summary, the conversation discusses the modification of inner-shell electrons in a multi-electron system and its effect on the outer shell electron. The effective electrostatic potential and its equation are given, and the problem of finding the energy eigenvalues and wavefunctions of the outer shell electron is presented. The conversation also mentions the comparison to the hydrogen atom and suggests the possibility of rescaling the r-axis to solve the problem.
  • #1
valtorEN
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0

Homework Statement



Due to the modification of inner-shell electrons of a multi-electron system,

the outer shell electron can feel an effective electrostatic potential as

V(r)=-e^2/(4*π*eo*R)-lambda*(e^2/(4*π*eo*R^2)) ; 0<lambda≤1

Find the energy eigenvalues and wavefunctions of the outer shell electron

and compare to those of the hydrogen atom

Homework Equations



Radial equation

-hbar^2/2*m(d^2u/dr^2)+[(V(r)+(hbar^2/2*m)*l(l+1)/R^2]

Eigenenergies for hydrogen atom

En=-[(m/2*hbar^2)*(e^2/4*π*e0)^2]*(1/n^2)=E1/n^2



The Attempt at a Solution



i plugged the effective potential into the radial equation, divided by E

(E=-hbar^2*k^2/(2*m)) where k=sqrt(2mE)/hbar

and get an equation with the same general solutions as in my book

u(rho)=(rho^(l+1))*(e^(-rho))*(v(rho))

still, how does this term effect the energy compared to that with hydrogen's

eigenenergies? i assume a const term with lambda in it finds it way into the

eigenenergies, but how to solve this is beyond me!


how do i calculate the new energy eigenvalues and wave functions?

how do they compare to that of hydrogen?

cheers
nate
 
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  • #2
My feeling is that you could rescale the r-axis to get this problem solved.
The additional term in the potential is similar to the angular momentum term.
Therefore, the effect should be equivalent to the same problem with r rescaled and V(r) rescaled correspondingly.
But that is only my guess ...
Hope it helps.
 

Related to How to use extra term in radial equation

1. How do I add an extra term to the radial equation?

To add an extra term to the radial equation, you can simply include it as an additional variable in the equation. For example, if you are adding a term for potential energy, you would include it as "V(r)" in the equation.

2. What is the purpose of adding an extra term to the radial equation?

The purpose of adding an extra term to the radial equation is to account for any additional factors that may affect the system being studied. This could include factors such as external forces or interactions with other particles.

3. How does the extra term affect the solution of the radial equation?

The extra term can have a significant impact on the solution of the radial equation. It may change the shape of the solution curve or introduce new critical points. Therefore, it is important to carefully consider and analyze the effects of the extra term on the solution.

4. Are there any specific guidelines for choosing the extra term in the radial equation?

There are no set guidelines for choosing the extra term in the radial equation, as it depends on the specific system and factors being studied. However, it is important to select a term that accurately reflects the physical properties and interactions of the system.

5. Can the extra term be removed from the radial equation?

Yes, the extra term can be removed from the radial equation if it is not relevant or necessary for the specific study. However, it is important to thoroughly analyze the consequences of removing the term and ensure that it does not significantly affect the overall results.

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