How Does Hydrogen Sulfide Affect pH and Precipitation in a Cu-Zn Solution?

In summary, the problem involves a solution containing Cu+2 and Zn+2 ions at a concentration of 0.1M, which is then bubbled with hydrogen sulphide gas at an initial concentration of 0.1M. The question asks for the pH of the final solution and whether any precipitate will form. The solution involves calculating the dissociation equilibrium of H2S, using the pH value to calculate S2- concentration, and checking for precipitation using Kso values. All necessary equations can be found on the website provided.
  • #1
dragonlady90
3
0

Homework Statement


A sol'n contains Cu+2(aq) and Zn+2 ions each at a con'c of 0.1M. Hydrogen sulphide gas is bubbled up into sol'n and dissociates having an initial con'c of 0.1M. Whats the pH of the final solution? Will any precipate form?
I don't know how to start the problem. Pls help me and reply soon.

Homework Equations





The Attempt at a Solution

 
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  • #2
H2S is a weak diprotic acid. Differences between both dissociation constants are large enough to calculate each dissociation equilibrium separately. You have to check what the pH is (it i will be solely governed by the first dissociation step), use this pH value to calculate S2- concentration, and check if this concetration will be large enough for precipitation (hint: look for Kso values).

For more details see this page on the pH of polyprotic substance calculation.
 
  • #3
thanks for your reply Borek,

can u tell equation of this equilibrium problem so that i can solve it further. THat would be really helpful.
Once again, thanks for your reply.
 
  • #4
All equations that you need to calculate pH of the solution and S2-[/sup concentration are listed on my site.
 
  • #5
Are you still having problems with this question?
 

Related to How Does Hydrogen Sulfide Affect pH and Precipitation in a Cu-Zn Solution?

1. What is chemical equilibrium?

Chemical equilibrium is a state in a chemical reaction where the concentrations of reactants and products remain constant over time. This means that the rate of the forward reaction is equal to the rate of the reverse reaction, resulting in no net change in the amounts of reactants and products.

2. How do you calculate equilibrium constant?

Equilibrium constant (K) is calculated by dividing the concentration of products by the concentration of reactants, each raised to the power of their respective coefficients in the balanced chemical equation. This expression is also known as the law of mass action.

3. What factors affect chemical equilibrium?

Temperature, pressure, and concentration of reactants and products are the main factors that affect chemical equilibrium. Changes in these factors can shift the equilibrium point to favor either the forward or reverse reaction, altering the concentrations of reactants and products.

4. How do you determine if a reaction is at equilibrium?

A reaction is at equilibrium when the concentrations of reactants and products remain constant over time. This can be determined by observing the reaction for a significant amount of time and seeing if there is no net change in the amounts of reactants and products.

5. How do you solve a chemical equilibrium problem?

To solve a chemical equilibrium problem, you must first write a balanced chemical equation and set up an equilibrium expression using the concentrations of reactants and products. Then, use the equilibrium constant (K) and the initial concentrations of reactants and products to solve for the unknown concentration. Finally, check your answer by plugging it back into the equilibrium expression to ensure it satisfies the law of mass action.

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