How Do You Expand a Hydrogen Atom State in an Orthonormal Basis?

In summary, the conversation discusses a hydrogen atom in a specific initial state and the process of expanding that state in terms of a basis of normalized eigenfunctions. The resulting expansion is given as A multiplied by a specific basis state, plus a coefficient multiplied by a combination of three other basis states. The person seeking help expresses their lack of understanding and asks for assistance.
  • #1
carlosbgois
68
0

Homework Statement


[/B]
Consider a hydrogen atom which, in t = 0, is in the state given by

[tex]\psi(\mathbf{r},t>0)=\frac{A}{4\pi}R_{10}(r)+\frac{cos\alpha}{4\pi}\left(\frac{z-\sqrt{2}x}{r}\right)R_{21}(r)[/tex]

Expand ψ in terms of the nlm} basis of normalized eigenfunctions

[tex]\phi_{nlm}(\mathbf{r})=R_{nl}(r)Y_l^m(\theta,\phi)[/tex]

Homework Equations



The result should be

[tex]A\phi_{100}(\mathbf{r})+\frac{cos\alpha}{\sqrt{3}}[\phi_{210}(\mathbf{r})+\phi_{211}(\mathbf{r})-\phi_{21,-1}(\mathbf{r})][/tex]

The Attempt at a Solution



Apart from having the supposed solution, I have no idea where to start.
Any help is appreciated.
 
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  • #2
You are required to show any of your initial effort before others can help you.
 
  • #3
Do you understand the general principle of writing a state as a linear combination of orthonormal basis states? And how, in general, to determine the coefficients?
 

Related to How Do You Expand a Hydrogen Atom State in an Orthonormal Basis?

What is the "Hydrogen atom state expansion"?

The Hydrogen atom state expansion is a mathematical model used to describe the behavior and properties of hydrogen atoms. It is based on the Schrödinger equation and takes into account the energy levels, wave functions, and probabilities of finding the electron in different locations around the nucleus.

What are the energy levels in the Hydrogen atom state expansion?

The energy levels in the Hydrogen atom state expansion are represented by a series of numbers known as quantum numbers. These numbers indicate the different possible energy states that an electron can occupy in the hydrogen atom, with the lowest energy level being the ground state.

How does the Hydrogen atom state expansion explain the behavior of electrons?

The Hydrogen atom state expansion explains the behavior of electrons by using wave functions to describe the probability of finding an electron in a particular location around the nucleus. These wave functions show that electrons do not move in a fixed orbit but rather exist in a cloud of probability around the nucleus.

What is the significance of the Hydrogen atom state expansion in quantum mechanics?

The Hydrogen atom state expansion is significant in quantum mechanics as it was one of the first successful applications of the principles of quantum mechanics. It also provides a foundation for understanding the behavior of more complex systems and has led to the development of many other theories and models in the field of quantum mechanics.

How is the Hydrogen atom state expansion used in practical applications?

The Hydrogen atom state expansion is used in various practical applications, such as in the design of electronic devices and in understanding the behavior of atoms and molecules in chemical reactions. It also plays a crucial role in the study of atomic and molecular spectroscopy, which is used in many fields such as astronomy, medicine, and environmental science.

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