How can we explain continuous absorption / emission?

In summary, the conversation discusses the difference between atomic absorption and emission line spectra, which occur at specific frequencies, and the absorption, reflection, and emission of electromagnetic radiation by everyday objects, which appears to occur continuously over a wide range of frequencies. The speaker questions how this continuous absorption occurs, specifically wondering if it is the absorption of numerous, closely spaced discrete frequencies. They also mention that the collective behavior of atoms and molecules in a material, known as the lattice, plays a role in this absorption process.
  • #1
DomPhillips
8
1
I am familiar with the explanations for atomic absorption and emission line spectra and how the existence of discrete, fixed energy levels can give rise to the absorption/emission lines that are seen at only very particular frequencies of EM radiation.
However, I have no intuitive understanding as to why the vast majority of objects that we see in the everyday world seem to absorb/reflect/transmit/emit EM radiation over a wide continuous frequency range. How can a black object absorb all wavelengths of visible EM radiation simultaneously? How can a white object reflect all wavelengths of visible light simultaneously? Is it actually a true continuous absorption or is it the absorption of innumerable different discrete frequencies which are very close together? What physical/atomic properties of a material govern which frequency ranges it absorbs in?Note:
I am familiar with how systems of delocalised electrons can give rise to absorption in the visible spectrum and how the absorption of IR can cause bonds to vibrate, but I am still none the wiser as to why these adsorptions always seem to be continuous (at least to an extent) and never perfectly discrete (as seems to be the case with line spectra).
 
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  • #2
This is because bulk medium consists of bonding of atoms/molecules, and the interaction with EM fields is governed by the collective behavior of those arrays of atoms/molecules called lattice instead of the individual atoms.
DomPhillips said:
is it the absorption of innumerable different discrete frequencies which are very close together?
Yes it is and for which in crystalline materials, those very closely separated levels form the so called energy bands.
 

Related to How can we explain continuous absorption / emission?

1. How does continuous absorption and emission occur?

Continuous absorption and emission occurs when a material absorbs or emits electromagnetic radiation continuously over a broad range of frequencies. This can happen when the material is heated to high temperatures, causing its atoms or molecules to become excited and release energy in the form of photons.

2. What is the difference between continuous absorption and emission and line absorption and emission?

The main difference between continuous absorption and emission and line absorption and emission is the range of frequencies involved. In continuous absorption and emission, a broad range of frequencies is absorbed or emitted, while in line absorption and emission, only specific frequencies are absorbed or emitted by the material.

3. How can we observe continuous absorption and emission?

Continuous absorption and emission can be observed using spectroscopy techniques, such as absorption spectroscopy or emission spectroscopy. These methods involve shining a beam of light through a sample and measuring the amount of light absorbed or emitted at different frequencies.

4. What are the applications of continuous absorption and emission?

Continuous absorption and emission have various applications in different fields. In astronomy, it is used to study the composition of stars and other celestial bodies. In chemistry, it is used to identify and analyze chemical compounds. It also has applications in medical imaging, environmental monitoring, and industrial processes.

5. Can continuous absorption and emission be explained by the quantum theory?

Yes, continuous absorption and emission can be explained by the quantum theory. According to this theory, energy is not emitted or absorbed continuously but in discrete packets called photons. These photons have a specific energy that corresponds to a specific frequency, and the absorption and emission of these photons can explain the continuous absorption and emission phenomenon.

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