Finding Nodal Surfaces in Wave Function of H-Like Atom

In summary, the conversation is about a given wave function for a hydrogen atom and determining the number of nodal surfaces it has. The conversation includes a discussion of coding the wave function in MATLAB and using an applet to check the probability density.
  • #1
ritwik06
580
0

Homework Statement



One wave function of H like atom is [tex]\psi=\frac{\sqrt{2}}{81\sqrt{\pi}a_{0}^{3/2}}(6-\frac{r}{a_{0}})\frac{r}{a_{0}}(e^{\frac{-r}{3a_{0}}})cos \theta[/tex]

How many nodal surfaces are there?
1)1
2)2
3)3
4)none of these

The Attempt at a Solution


Its an objective question which I need to answer in less than a minute. Is it possible to do so?

The next thing that I assume i that the wave function is given in polar coordinate form, isn't it?? [tex]\psi=f(r,\theta, \phi)[/tex]?
phi is absent what does it mean? I guess it means that its the p - orbital. then the anwer must be 2. Am I right?

Last but not the least. I am keen upon seeing the 3D picture this wave function generates. I have MATLAB but I don't know how to code in polar coordinate and all. Will somebody code this wave function for me which is compatible with MATLAB 2008?? Please. I shall be very grateful.
Thanks a lot.
 
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  • #2
Isn't the number of nodal surfaces equal to the quantum number of your wave function?
 
  • #3
buffordboy23 said:
Isn't the number of nodal surfaces equal to the quantum number of your wave function?

Thanks a lot but I know that already. Is it of any help with this particular problem?
And sir, can you please tell me how can I plot equations such as this one and like
x2+y2+z2=1 with MATLAB?
 
  • #4
Your given the wave function. The wave functions for the hydrogen atom are constructed from two separate functions, the spherical harmonic wave functions, [tex] Y^{m}_{l}\left(\theta,\phi\right) [/tex], and the radial wave functions, [tex] R_{nl}\left(r\right) [/tex]:

[tex] \Psi_{nlm}\left(r,\theta,\phi\right) = R_{nl}\left(r\right)Y^{m}_{l}\left(\theta,\phi\right) [/tex]

You really only need to look at the radial wave equation, since by definition it has a term [tex] e^{-r/na} [/tex], where n is the quantum number. So, this is easily determined by your given function.

I am pretty certain that n,l,m = 3,1,0 for your given wave function. Here's an applet to check out the probability density:

http://www.phy.davidson.edu/StuHome/cabell_f/Density.html
 

Related to Finding Nodal Surfaces in Wave Function of H-Like Atom

1. What is the significance of nodal surfaces in the wave function of an H-like atom?

Nodal surfaces are the locations where the wave function of an H-like atom crosses zero. These surfaces play a crucial role in determining the energy levels and properties of the atom.

2. How do you find nodal surfaces in the wave function of an H-like atom?

Nodal surfaces can be found by solving the Schrödinger equation for the H-like atom. This involves using mathematical techniques such as separation of variables and solving for the energy eigenvalues and corresponding wave functions.

3. What factors affect the number and location of nodal surfaces in the wave function of an H-like atom?

The number and location of nodal surfaces are primarily affected by the principal quantum number, n, and the angular momentum quantum number, l. Higher values of n and l result in more nodal surfaces.

4. How do nodal surfaces relate to the probability density of an H-like atom?

The probability density of an H-like atom is directly related to the squared magnitude of the wave function. Nodal surfaces correspond to regions where the probability density is zero, indicating a low likelihood of finding the electron in that location.

5. Can nodal surfaces be observed experimentally?

No, nodal surfaces cannot be directly observed as they are mathematical constructs. However, their effects can be observed through the energy levels and other properties of the atom, which can be measured experimentally.

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