Fick's Second Law: Laplace Transform to solve PDE in Spherical Coords

In summary, Fick's second law can be written in general form as \frac{\partial C}{\partial t} = D\nabla^2 C and in spherical form as \frac{\partial C}{\partial t} = D\frac{1}{r^2}\frac{\partial}{\partial r}\left( r^2\frac{\partial C}{\partial r} \right). When we laplace transform the equation, the left hand side becomes p\bar{C} and the right hand side simplifies to Dpr^2\frac{\partial \bar{C}}{\partial r}.
  • #1
johndoe3344
29
0
Fick's second law in general form:
[tex]\frac{\partial C}{\partial t} = D\nabla^2 C[/tex]

In spherical form:
[tex]\frac{\partial C}{\partial t} = D\frac{1}{r^2}\frac{\partial}{\partial r}\left( r^2\frac{\partial C}{\partial r} \right)[/tex]

(Assume all changes in phi and theta to be zero, so we are only concerned with the r component here.)

Let's say that C(t=0) = 0

If we laplace transform:
LHS becomes: [tex]p\bar{C}[/tex]

Where C bar is the laplace transform of C, and C(t=0) = 0.

I'm stuck on the right hand side. The textbook just skips the math and gives the solution. Any help would be appreciated.

Thanks.
 
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  • #2
The right hand side of the equation can be simplified as follows:RHS = D\frac{1}{r^2}\frac{\partial}{\partial r}\left( r^2\frac{\partial \bar{C}}{\partial r} \right)RHS = D\frac{1}{r^2}\frac{\partial}{\partial r}\left( r^2p\bar{C} \right)RHS = Dp\frac{\partial}{\partial r}\left( r^2\bar{C} \right)RHS = Dp\frac{\partial}{\partial r}\left( r^2 \right)\bar{C} + Dpr^2\frac{\partial \bar{C}}{\partial r}RHS = Dpr^2\frac{\partial \bar{C}}{\partial r}Finally, we can write the Laplace transformed Fick's second law as:p\bar{C} = Dpr^2\frac{\partial \bar{C}}{\partial r}
 

Related to Fick's Second Law: Laplace Transform to solve PDE in Spherical Coords

What is Fick's Second Law?

Fick's Second Law is a mathematical equation used to describe the diffusion of particles in a medium. It states that the rate of change of concentration of particles is proportional to the second derivative of concentration with respect to position.

How is the Laplace Transform used to solve PDE in Spherical Coordinates?

The Laplace Transform is a mathematical tool used to solve differential equations. In the case of Fick's Second Law in Spherical Coordinates, the Laplace Transform can be used to convert the partial differential equation into an algebraic equation, which can then be solved using standard techniques.

What are Spherical Coordinates?

Spherical Coordinates are a system of coordinates used to describe the position of a point in three-dimensional space. In this system, a point is described using three coordinates: radius, inclination, and azimuth. This system is particularly useful in solving problems involving diffusion in spherical objects.

What is the significance of solving Fick's Second Law in Spherical Coordinates?

Solving Fick's Second Law in Spherical Coordinates allows us to understand and predict the diffusion of particles in spherical objects, such as cells or spherical containers. This is important in many scientific fields, including biology, chemistry, and engineering.

Are there any limitations to using Fick's Second Law in Spherical Coordinates?

While Fick's Second Law in Spherical Coordinates is a useful tool, it is based on several assumptions, such as constant diffusion coefficients and no external forces acting on the particles. These assumptions may not be valid in certain situations, and thus, the results obtained from using this equation may not accurately reflect reality.

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