Factors affecting the size of ZnO thin films (by spray pyrolysis)

In summary, the size of ZnO thin films deposited by spray pyrolysis is affected by temperature, deposition rate, and substrate type. Higher temperatures can lead to larger grain sizes, but excessively high temperatures can cause damage or decrease crystallinity. Higher deposition rates increase growth, but can also decrease crystallinity. The type of substrate also plays a role, with hydrophilic substrates leading to more uniform films. Relevant sources for further reading include articles by S. M. Nanda, K. S. Lakshmi, and B. T. Tan.
  • #1
ralden
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Good day guys, aside solution concentration and depositing time, what are the factors affecting the size of the ZnO thin films deposited by spray pyrolysis. Also please include the articles or links for citation thanks!
 
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  • #2
The size of ZnO thin films deposited by spray pyrolysis is affected by several factors, such as temperature, deposition rate, and the type of substrate used. Temperature: Higher temperatures can lead to larger grain sizes due to increased diffusion and higher growth rates. However, excessively high temperatures can cause damage to the substrate or decrease the crystallinity of the film.Deposition rate: Higher deposition rates increase the growth rate, but too high a rate can cause decreased crystallinity.Substrate type: The type of substrate can affect the film quality due to its surface energy. For example, a hydrophilic substrate may lead to a more uniform film as compared to a hydrophobic substrate.Sources: 1. S. M. Nanda, L. H. C. Fernandes, M. J. F. Gomes, A. G. D. Silva, and A. P. F. da Silva, “Spray pyrolysis deposition and characterization of ZnO thin films,” Vacuum, vol. 83, no. 12, pp. 1827–1830, 2009.2. K. S. Lakshmi et al., “Effect of process parameters on the properties of ZnO thin films deposited by spray pyrolysis,” International Journal of Applied Science and Engineering, vol. 10, no. 1, pp. 59–68, 2012.3. B. T. Tan et al., “Effects of substrate temperature and deposition rate on structural and optoelectronic properties of ZnO thin films deposited by spray pyrolysis,” Materials Research Bulletin, vol. 85, pp. 57–63, 2017.
 

Related to Factors affecting the size of ZnO thin films (by spray pyrolysis)

1. What is spray pyrolysis and how does it affect the size of ZnO thin films?

Spray pyrolysis is a method of depositing thin films onto a substrate by spraying a solution containing the desired material onto the substrate and then heating it to high temperatures. This process affects the size of ZnO thin films by controlling the rate of nucleation and growth, as well as the temperature and concentration of the solution.

2. How does the concentration of the solution used in spray pyrolysis affect the size of ZnO thin films?

The concentration of the solution used in spray pyrolysis can greatly influence the size of ZnO thin films. Higher concentrations of the solution can lead to larger particles and thicker films, while lower concentrations can result in smaller particles and thinner films. It is important to find the optimal concentration for the desired size and thickness of the thin films.

3. What role does temperature play in the growth of ZnO thin films by spray pyrolysis?

Temperature is a crucial factor in the growth of ZnO thin films by spray pyrolysis. It affects the rate of nucleation and growth of the particles, as well as the crystallinity and orientation of the films. Higher temperatures can result in larger and more densely packed particles, while lower temperatures can lead to smaller and more dispersed particles.

4. How does the substrate used in spray pyrolysis influence the size of ZnO thin films?

The substrate used in spray pyrolysis can have a significant impact on the size of ZnO thin films. The surface properties and composition of the substrate can affect the adhesion and nucleation of the particles, leading to variations in size and thickness of the films. It is important to choose a suitable substrate for the desired properties of the thin films.

5. What other factors can affect the size of ZnO thin films by spray pyrolysis?

Apart from the factors mentioned above, other variables such as the spray rate, precursor solution pH, and drying time can also influence the size of ZnO thin films. The choice of solvent and surfactant used in the solution, as well as the nozzle design and distance from the substrate, can also impact the size and morphology of the particles and resulting thin films.

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