Dynamics of electron in crystal lattice

In summary, the conversation was about the correct equation for the motion of an electron in a crystal lattice under the influence of magnetic force. The equation for electric force was discussed and modified to incorporate magnetic force. A proof for this modified equation was requested, with a suggestion to look at appendix E of the book "Solid State Physics" by Ashcroft and Mermin. The conversation also touched on the difference between quasimomentum and momentum and the use of Ehrenfest's theorem in deriving the equation.
  • #1
paweld
255
0
I'm not sure what is the correct equation for motion of electron in a crystal
lattice under the influence of magnetic force. On may easily proof that for
electric force the following equation holds (the proof might be found in
http://ajp.aapt.org/resource/1/ajpias/v54/i2/p177_s1" ):
[tex]
\hbar \frac{d}{d t} \langle T \rangle = -e E
[/tex]
(T - lattice translation opertor; its eigenvalues are called usually quasimomentum;
here we have average value). Straightforward modification of above equation
which incorporate magnetic force would be (E(k) means energy):
[tex]
\hbar \frac{d}{d t} \langle T \rangle = -e (\vec{E} + \frac{1}{\hbar}\nabla_{\vec{k}}E(k)\times \vec{B})
[/tex]
And this equation is stated by most textbooks concering solid state physics (however
without proof or with proof which is not rigorous). Does anyone know a good proof
of these equation?
 
Last edited by a moderator:
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  • #2
If you look in appendix E of Ashcroft and Mermin, there is a rigorous proof that the expectation value of the velocity operator is [tex] \nabla_k E(k)[/tex]. Since the equation you wrote is basically the Lorentz force equation, I suspect you could derive it from that and Ehrenfest's theorem.
 
  • #3
Using Ehrenfest theorem one would obtain the following formula
[tex]
\hbar \frac{d}{d t} \langle p\rangle = -e (\vec{E} + \frac{1}{\hbar}\nabla_{\vec{k}}E(k)\times \vec{B})
[/tex]
where p is momentum of electron and it is different from quasimomentum
which is usually denoted by k. Most textbooks gives this formula with k
not p and this is why I'm wondering why it's true.
 
Last edited:
  • #4
Ashcroft and Mermin discuss this topic quite at length and, more importantly, give many links to relevant literature.
 

Related to Dynamics of electron in crystal lattice

1. What is the crystal lattice?

The crystal lattice is the three-dimensional arrangement of atoms, ions, or molecules in a solid material. It is a repeating pattern that extends in all three dimensions and is responsible for the properties of a crystal.

2. How do electrons behave in a crystal lattice?

Electrons in a crystal lattice behave as both particles and waves. They are confined to specific energy levels within the lattice and can move through the lattice in a wave-like manner, resulting in properties such as electrical conductivity and thermal conductivity.

3. What is the role of the crystal lattice in determining the properties of a material?

The crystal lattice plays a crucial role in determining the properties of a material because it affects how electrons move and interact within the material. The size, shape, and orientation of the lattice can greatly influence properties such as electrical conductivity, thermal conductivity, and optical properties.

4. How do defects in the crystal lattice affect electron dynamics?

Defects in the crystal lattice, such as vacancies, dislocations, or impurities, can disrupt the regular arrangement of atoms and ions, leading to changes in the behavior of electrons. For example, defects can scatter electrons, reducing electrical conductivity, or trap electrons, affecting the optical properties of the material.

5. How does temperature affect electron dynamics in a crystal lattice?

At higher temperatures, electrons in a crystal lattice have more thermal energy, allowing them to move more freely and increasing their chances of scattering. This can lead to changes in electrical conductivity and other properties. At very low temperatures, quantum effects come into play, and the behavior of electrons can be drastically different than at room temperature.

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