Does Atmospheric Pressure or Temperature Determine the State of CO2?

In summary, the partial pressure of CO2 is what determines whether it is in a liquid or gas state, not the total atmosphere. At 0F, the vapor pressure of CO2 is about 20 bars, but the partial pressure in the given gas mixture is only 1 bar, so it remains in a gas state. If the temperature were -40 F, CO2 would be in a liquid state at the total atmosphere, but would still be a gas at its partial pressure. This understanding is important in order to reason out and determine the state of CO2 in various scenarios.
  • #1
willstaruss22
108
1
Let's say you have a 20 bar atmosphere of 95% nitrogen, 3% oxygen, 1% argon and 1% Co2 cooled to 0 F. Would Co2 be liquid or gas?
 
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  • #2
Get yourself a CO2 phase diagram and see.
 
  • #3
The partial pressure is 0.2 bar so it would be gas. However with the whole atmosphere is would be liquid.
 
  • #4
The vapor pressure of CO2 at 0F is about 20 bars, and the partial pressure of the CO2 in your gas mixture is about 1 bar. So it won't condense.

Chet
 
  • #5
Here's where I'm confused is it the partial pressure of Co2 that determines which state its in or the total atmosphere? Because if in this scenario the temperature were -40 F Co2 would be liquid with the total atmosphere but it would be gas at partial pressure.
 
  • #6
willstaruss22 said:
Here's where I'm confused is it the partial pressure of Co2 that determines which state its in or the total atmosphere? Because if in this scenario the temperature were -40 F Co2 would be liquid with the total atmosphere but it would be gas at partial pressure.
It's the partial pressure that matters, not the total pressure.

Chet
 
  • #7
willstaruss22 said:
Here's where I'm confused is it the partial pressure of Co2 that determines which state its in or the total atmosphere? Because if in this scenario the temperature were -40 F Co2 would be liquid with the total atmosphere but it would be gas at partial pressure.

Which would you think it should be? It is nice to be told a confirmation, but it is not that much help to you really if you can't or don't reason it out mechanistically.
 

Related to Does Atmospheric Pressure or Temperature Determine the State of CO2?

1. Would CO2 be a liquid or gas at room temperature?

At room temperature, CO2 exists as a gas. It has a boiling point of -78.5 degrees Celsius and a melting point of -56.6 degrees Celsius, which are both well below room temperature. Therefore, it would need to be under high pressure to exist as a liquid at room temperature.

2. What conditions are needed for CO2 to become a liquid?

In order for CO2 to become a liquid, it needs to be at a temperature below its critical point of 31.1 degrees Celsius and at a pressure of at least 73.8 atmospheres. At this point, the gas and liquid phases of CO2 are in equilibrium, and it can exist as a liquid.

3. Can CO2 exist as both a liquid and a gas?

Yes, CO2 can exist as both a liquid and a gas depending on the temperature and pressure conditions. At normal atmospheric pressure and temperatures above -56.6 degrees Celsius, CO2 is a gas. However, at lower temperatures and/or higher pressures, it can exist as a liquid.

4. How does the phase of CO2 affect its properties?

The phase of CO2 can significantly affect its properties. As a gas, CO2 is less dense and more compressible than as a liquid. It also has different thermal conductivity and diffusion rates in each phase. Additionally, the liquid phase of CO2 is highly soluble, making it a useful solvent in industrial applications.

5. Can CO2 transition directly from a gas to a solid?

Yes, CO2 can transition directly from a gas to a solid phase through a process called sublimation. This occurs at temperatures below -78.5 degrees Celsius and at atmospheric pressure. Dry ice, which is solid CO2, is commonly used for refrigeration and special effects due to its ability to sublimate into a gas at room temperature.

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