Degenerate Perturbation Theory

In summary: The basic idea of degenerate perturbation theory is to take a system of equations and solve for the energy eigenvalues of the system. When you solve for the energy eigenvalues, you are diagonalizing a matrix. This matrix represents how the energy is affected by the states of the system. You are solving for the energy eigenvalues in a basis that is chosen based on the energy eigenvalues of the system.
  • #1
TeddyYeo
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Homework Statement


We have spin-1 particle in zero magnetic field.
Eigenstates and eigenvalue of operator [itex] \hat S_z [/itex] is [itex] - \hbar |-1> [/itex], [itex] 0 |0> [/itex]
and [itex] \hbar |+1> [/itex].

Calculate the first order of splitting which results from the application of a weak magnetic field in the x direction.

Homework Equations


Hamiltonian is perturbed by [itex] H' = \gamma B \hat S_x = - ( \gamma B/2) (\hat S_+ + \hat S_-)[/itex]

The Attempt at a Solution


[/B]
We have to solve it using degenerate perturbation theory in the basis mentioned, and check it which the basis of eigenvectors of [itex] \hat S_x [/itex].

I am really confused with quantum mechanics, thus would like to know how do we start the question.
Is there anyone that can help us by going through step by step how should we go about it and explain it as well?
 
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  • #2
No, we don't supply solutions here. You need to show some effort in trying to figure out the problem yourself.

You already know how to start the question. As you said, you need to apply degenerate perturbation theory. This topic is surely covered in your textbook.
 
  • #3
How do we apply the theory?
Do I need to assume anything?

For unperturbed,
[itex] |-1> => E^0_{-1} =-\hbar [/itex]
[itex] |0> => E^0_{0} = 0
[itex] |+1> => E^0_{+1} =+\hbar [/itex]

Correct?
How do we create the new basis for the H' then?
 
  • #4
No, that's not correct. If the unperturbed energies are different, you don't need degenerate perturbation theory, do you?

Can you describe the general idea behind degenerate perturbation theory?
 
  • #5
Is it that when we affect the system by a little, then we are to find out the how much the system changes?
And by degenerate, it means that energy eigenvalues are the same for all states it act on?
 
  • #6
Yes, that's what degenerate perturbation theory is, but I want you to describe the basic idea of what you're doing when you apply the theory to a situation. In other words, what's the math problem you are solving? Are you diagonalizing a matrix? If so, what matrix? What does it represent and in what basis?
 
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Related to Degenerate Perturbation Theory

1. What is degenerate perturbation theory?

Degenerate perturbation theory is a mathematical tool used in quantum mechanics to calculate the energy levels of a system that experiences a perturbation, or small disturbance, to its original Hamiltonian. It is specifically used for systems that have degenerate energy levels, meaning they have the same energy but different quantum states.

2. How does degenerate perturbation theory work?

In degenerate perturbation theory, the Hamiltonian of the original system is first diagonalized to find the unperturbed energy levels and corresponding eigenstates. Then, the perturbation is introduced and the Hamiltonian is re-diagonalized to determine the corrections to the energy levels and eigenstates. These corrections are then added to the unperturbed energy levels to obtain the final, perturbed energy levels.

3. What are the advantages of using degenerate perturbation theory?

Degenerate perturbation theory allows for the accurate calculation of energy levels in systems with degenerate states, which cannot be done using non-degenerate perturbation theory. It also provides a systematic way to calculate the corrections to the energy levels, making it easier to handle complex systems.

4. What are the limitations of degenerate perturbation theory?

Degenerate perturbation theory assumes that the perturbation is small enough that it doesn't significantly alter the original system. If the perturbation is too large, the theory may not accurately predict the energy levels. Additionally, it only applies to systems with degenerate states, so it cannot be used for systems with non-degenerate states.

5. How is degenerate perturbation theory used in real-world applications?

Degenerate perturbation theory is used in a variety of fields, including physics, chemistry, and materials science. It has been used to study the energy levels of atoms and molecules, as well as the electronic properties of materials. It is also used in quantum computing to calculate the energy levels of quantum systems.

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