Balancing Van der Waals force with a spring

In summary, the problem involves determining the deformation of a cantilever spring, Δx, as it is moved towards another bead of the same radius. This is due to the interaction between the two spheres, which can be calculated using the non-retarded Van der Waals interaction free energy equation. By equating the forces of the cantilever spring and the Van der Waals interaction, a cubic equation can be obtained. By making certain assumptions and approximations, the equation can be simplified and solved for Δx as a function of the distance, z.
  • #1
creemore
2
0

Homework Statement



An AFM tip has a spring constant k, a colloidal bead with radius r is glues onto the cantilever tip. Derive an expression and plot the deformation of the cantilever spring, Δx, as a function of distance the tip of the cantilever is moved towards another bead of the same radius.

Homework Equations



The cantilever tip can be treated as a Hookean spring. So Fspring = -kΔx

The non-retarded Van der Waals interaction free energy between two spheres of the same radius is:

W = -AR/(12D)

where D is the distance between the spheres, R is the radius of the spheres, and A is the Hamaker constant.

The Van der Waals force is simply the derivative of the potential w.r.t. D:

Fvan = AR/(12D2)

The Attempt at a Solution



The question seems fairly straight forward. At equilibrium, Fspring = Fv, so

-kΔx = AR/(12D2)

we can say D is the distance the cantilever tip is manual moved (z), plus the distance the spring is stretched because of VDW interaction.

-kΔx = AR/(12(z+x)2)

For some reason, I can't solve for Δx as a function of z. I feel like I'm missing some trivial step, and would appreciate any help with a solution.

Thanks in advance.
 
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  • #2
creemore said:
-kΔx = AR/(12(z+x)2)
Should that read -kΔx = AR/(12(z+Δx)2)?
If so, can't you just multiply it out to get a cubic? If Δx can be assumed small c.w. z then you can approximate it thus:
-kΔx = AR/(12z2(1+Δx/z)2) ≈ AR/(12z2(1+2Δx/z)) ≈ AR(1-2Δx/z)/(12z2)
That now being linear in Δx, solve in the obvious way.
 

Related to Balancing Van der Waals force with a spring

What is Van der Waals force?

Van der Waals force is a weak attraction between molecules or atoms due to their temporary dipole moments. It is caused by the uneven distribution of electrons in a molecule or atom, creating a temporary dipole that can interact with neighboring molecules or atoms.

How does Van der Waals force affect the behavior of molecules?

Van der Waals force can play a significant role in determining the physical properties and behavior of molecules. It can affect the boiling and melting points, solubility, and viscosity of substances. It also contributes to the cohesion and adhesion of liquids and the stability of molecular structures.

What is the relationship between Van der Waals force and spring?

Van der Waals force and spring force are both interatomic or intermolecular forces. They both involve the interaction between neighboring molecules or atoms. However, while Van der Waals force is a weak, short-range force, the spring force is a strong, long-range force.

Why is it important to balance Van der Waals force with a spring?

In certain materials or systems, the Van der Waals force can become too strong, causing molecules to come too close together and potentially leading to instability or collapse. Balancing it with a spring force can help maintain the proper distance between molecules and prevent these issues.

How can one balance Van der Waals force with a spring?

This can be achieved by adjusting the strength of the spring force, which can be done by changing the properties of the material the spring is made of or altering its geometry. In some cases, external forces may also be applied to counteract the Van der Waals force.

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